Search Results - "Fouassier, J. P."
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High Performance Near-Infrared (NIR) Photoinitiating Systems Operating under Low Light Intensity and in the Presence of Oxygen
Published in Macromolecules (27-02-2018)“…Photopolymerization under near-infrared (NIR) light is challenging due to the low energy of the absorbed photon but, if successful, presents significant…”
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Photoinduced Thermal Polymerization Reactions
Published in Macromolecules (13-11-2018)“…The combination of thermally induced and photoinduced free radical polymerization of (meth)acrylic monomers has only been scarcely presented in the…”
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3
Copper (Photo)redox Catalyst for Radical Photopolymerization in Shadowed Areas and Access to Thick and Filled Samples
Published in Macromolecules (23-05-2017)“…The free radical polymerization of low viscosity methacrylate blends upon a LED irradiation at 405 nm under air is carried out using Cu(I)/iodonium…”
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Simultaneous initiation of radical and cationic polymerization reactions using the “G1” copper complex as photoredox catalyst: Applications of free radical/cationic hybrid photopolymerization in the composites and 3D printing fields
Published in Progress in organic coatings (01-07-2019)“…[Display omitted] This investigation presents the use of a photoredox catalyst "G1" as a photoinitiating system for free radical/cationic hybrid polymerization…”
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New functionalized aromatic ketones as photoinitiating systems for near visible and visible light induced polymerizations
Published in Polymer (Guilford) (01-05-2013)“…Novel functionalized ketones (K_PY) incorporating one/two pyrene moieties or a pyridinium chromophore for radical and/or cationic polymerization under soft…”
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Silanes as New Highly Efficient Co-initiators for Radical Polymerization in Aerated Media
Published in Macromolecules (25-03-2008)“…A large series of silanes are proposed as new co-initiators for radical photopolymerization. Silanes in the presence of benzophenone, isopropylthioxanthone,…”
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Aminoalkyl Radicals: Direct Observation and Reactivity toward Oxygen, 2,2,6,6-Tetramethylpiperidine-N-oxyl, and Methyl Acrylate
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-08-2007)“…The reactivity of 11 aminoalkyl radicals toward different additives [oxygen, 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), and methyl acrylate (MA)] has been…”
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New Photoinitiators Based on the Silyl Radical Chemistry: Polymerization Ability, ESR Spin Trapping, and Laser Flash Photolysis Investigation
Published in Macromolecules (24-06-2008)“…New highly efficient photoinitiators (PI) based on silyl radicals chemistry are proposed. The ability of these structures to initiate both free radical…”
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9
Photopolymerization reactions under visible lights: principle, mechanisms and examples of applications
Published in Progress in organic coatings (01-07-2003)“…A general overview of visible light photoinduced polymerization reactions is presented. Reaction mechanisms as well as practical efficiency in industrial…”
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10
Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems
Published in Polymer (Guilford) (01-06-2003)“…The activity of six newly designed three-component systems (containing a dye, an amine and a triazine derivative) for the initiation of the photopolymerization…”
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11
Camphorquinone–amines photoinitating systems for the initiation of free radical polymerization
Published in Polymer (Guilford) (01-08-2003)“…Results of the camphorquinone/hindered piperidines, visible-light photoinduced polymerization of triethyleneglycol dimethacrylate are presented. The…”
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12
Boryl Radicals as a New Photoinitiating Species: A Way to Reduce the Oxygen Inhibition
Published in Macromolecules (09-12-2008)“…Amine- and phosphine-ligand-containing borane complexes (BoC) are proposed as new, highly efficient coinitiators for acrylate photopolymerization. In the…”
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13
A Photodissociation Reaction: Experimental and Computational Study of 2-Hydroxy-2,2-dimethylacetophenone
Published in Photochemistry and photobiology (01-01-2006)“…The photophysical parameters controlling the cleavage process of 2-hydroxy-2,2-dimethylacetophenone (HDMA) were investigated in detail. Time-resolved…”
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14
New Photoiniferters: Respective Role of the Initiating and Persistent Radicals
Published in Macromolecules (08-04-2008)“…Three new structures (S-benzoyl O-ethyl xanthate, benzoyl diethyldithiocarbamate, and benzyl 9H-carbazole-9-carbodithioate) are proposed as photoiniferters for…”
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15
Reactivity and efficiency of difunctional radical photoinitiators
Published in Journal of applied polymer science (05-01-2008)“…Three difunctional cleavable photoinitiators based on the α-hydroxyketone structure were tested in photopolymerization reactions with Fourier transform…”
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On-Demand Visible Light Activated Amine/Benzoyl Peroxide Redox Initiating Systems: A Unique Tool To Overcome the Shadow Areas in Photopolymerization Processes
Published in Macromolecules (27-12-2016)“…A novel way to counterbalance the drawbacks and advantages of photopolymerization and redox polymerization is proposed. Photoinitiating systems based on charge…”
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Respective Contributions of Polar vs Enthalpy Effects in the Addition/Fragmentation of Mercaptobenzoxazole-Derived Thiyl Radicals and Analogues to Double Bonds
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (19-10-2006)“…The formation and the reactivity of three selected sulfur-centered radicals formed from mercaptobenzoxazole, mercaptobenzimidazole, and mercaptobenzothiazole…”
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18
Pyrromethene derivatives in three-component photoinitiating systems for free radical photopolymerization
Published in Journal of polymer science. Part A, Polymer chemistry (15-06-2010)“…1,3,5,7,8-pentamethyl pyrromethene difluoroborate complex (HMP) and 2,6-diethyl-8-phenyl-1,3,5,7-tetramethylpyrromethene difluoroborate complex (EPP) were used…”
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A New Highly Efficient Amine-Free and Peroxide-Free Redox System for Free Radical Polymerization under Air with Possible Light Activation
Published in Macromolecules (13-09-2016)“…Efficient redox initiating systems for radical polymerizations under air usually show some severe drawbacks such as handling and toxicity of the oxidizing…”
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Investigation of Barton esters as radical photoinitiators
Published in Journal of applied polymer science (15-07-2008)“…Different photoinitiators based on Barton thiohydroxamic esters, O-acyl-N-hydroxy-pyridine-2(1H)-thione and O-acyl-N-hydroxy-thiazole-2(3H)-thione derivatives,…”
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