Search Results - "Forbes, Malcolm D E"

Alkyne-Bridged Multi[Copper(II) Porphyrin] Structures: Nuances of Orbital Symmetry in Long-Range, Through-Bond Mediated, Isotropic Spin Exchange Interactions by Wang, Ruobing, Brugh, Alexander M, Rawson, Jeff, Therien, Michael J, Forbes, Malcolm D. E

“…Spin and conformational dynamics in symmetric alkyne-bridged multi­[copper­(II) porphyrin] structures have been studied in toluene solution at variable…”
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Photoinduced Charge Shifts and Electron Transfer in Viologen–Tetraphenylborate Complexes: Push–Pull Character of the Exciplex by Santos, Willy G, Budkina, Darya S, Deflon, Victor M, Tarnovsky, Alexander N, Cardoso, Daniel R, Forbes, Malcolm D. E

“…Viologen–tetraarylborate ion-pair complexes were prepared and investigated by steady-state and time-resolved spectroscopic techniques such as fluorescence and…”
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Excited-State Quenching by Proton-Coupled Electron Transfer by Concepcion, Javier J, Brennaman, M. Kyle, Deyton, Jeremy R, Lebedeva, Natalia V, Forbes, Malcolm D. E, Papanikolas, John M, Meyer, Thomas J

“…The emitting metal-to-ligand charge transfer (MLCT) excited state of [Ru(bpy)2(bpz)]2+ (bpy is 2,2‘-bipyridine; bpz is 2,2‘-bipyrazine) is reductively quenched…”
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Spinning Molecules, Spinning Spins: Modulation of an Electron Spin Exchange Interaction in a Highly Anisotropic Hyperfine Field by Brugh, Alexander M, Wang, Ruobing, Therien, Michael J, Forbes, Malcolm D. E

“…An investigation of spin and conformational dynamics in a series of symmetric Cu–Cu porphyrin dimer solutions is presented using electron paramagnetic…”
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What We Talk About When We Talk About Light by Forbes, Malcolm D. E

“…UNESCO (the United Nations Educational, Scientific, and Cultural Organization) has declared 2015 the “International Year of Light and Light-Based…”
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Photochemical [2+4]‐Dimerization Reaction from the Excited State by Ahuja, Sapna, Baburaj, Sruthy, Valloli, Lakshmy Kannadi, Rakhimov, Sarvar Aminovich, Manal, Kavyasree, Kushwaha, Aakrati, Jockusch, Steffen, Forbes, Malcolm D. E., Sivaguru, Jayaraman

“…Aryl‐maleimides undergo a novel [2+4]‐photodimerization instead of the expected [2+2]‐photodimerization under both direct irradiation with visible light and…”
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The Missing Link Between Molecular Triplets and Spin-Polarized Free Radicals: Room Temperature Triplet States of Nanocrystalline Radical Pairs by Lebedeva, Natalia V, Tarasov, Valery F, Resendiz, Marino J. E, Garcia-Garibay, Miguel A, White, Ryan C, Forbes, Malcolm D. E

“…Photochemical reactions of organic molecules in the solid state have an excellent potential in green chemistry technologies as they often proceed in high…”
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Guest Inclusion Modulates Concentration and Persistence of Photogenerated Radicals in Assembled Triphenylamine Macrocycles by Sindt, Ammon J., DeHaven, Baillie A., Goodlett, Rachel L., Hartel, Johannes O., Ayare, Pooja J., Du, Yong, Smith, Mark D., Mehta, Anil K., Brugh, Alexander M., Forbes, Malcolm D. E., Bowers, Clifford R., Vannucci, Aaron K., Shimizu, Linda S.

“…Substituted triphenylamine (TPA) radical cations show great potential as oxidants and as spin-containing units in polymer magnets. Their properties can be…”
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Concerted electron-proton transfer in the optical excitation of hydrogen-bonded dyes by Westlake, Brittany C, Brennaman, M. Kyle, Concepcion, Javier J, Paul, Jared J, Bettis, Stephanie E, Hampton, Shaun D, Miller, Stephen A, Lebedeva, Natalia V, Forbes, Malcolm D.E, Moran, Andrew M, Meyer, Thomas J, Papanikolas, John M

“…The simultaneous, concerted transfer of electrons and protons--electron-proton transfer (EPT)--is an important mechanism utilized in chemistry and biology to…”
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AB569, a nontoxic chemical tandem that kills major human pathogenic bacteria by McDaniel, Cameron T., Panmanee, Warunya, Winsor, Geoffrey L., Gill, Erin, Bertelli, Claire, Schurr, Michael J., Dongare, Prateek, Paul, Andrew T., Ko, Seung-Hyun B., Lau, Gee W., Dasgupta, Nupur, Bogue, Amy L., Miller, William E., Mortensen, Joel E., Haslam, David B., Dexheimer, Phillip, Muruve, Daniel A., Aronow, Bruce J., Forbes, Malcolm D. E., Danilczuk, Marek, Brinkman, Fiona S. L., Hancock, Robert E. W., Meyer, Thomas J., Hassett, Daniel J.

“…Antibiotic-resistant superbug bacteria represent a global health problem with no imminent solutions. Here we demonstrate that the combination (termed AB569) of…”
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Structural and pH Dependence of Excited State PCET Reactions Involving Reductive Quenching of the MLCT Excited State of [RuII(bpy)2(bpz)]2+ by Hydroquinones by Lebedeva, Natalia V, Schmidt, Robert D, Concepcion, Javier J, Brennaman, M. Kyle, Stanton, Ian N, Therien, Michael J, Meyer, Thomas J, Forbes, Malcolm D. E

“…The proton-coupled electron transfer (PCET) reaction between the bpz-based photoexcited 3MLCT state of [RuII(bpy)2(bpz)]2+ (bpy = 2,2′-bipyridine, bpz =…”
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Fluorophore Assisted Photolysis of Thiolato-Cob(III)alamins by Rodgers, Zachary L, Shell, Thomas A, Brugh, Alexander M, Nowotarski, Hannah L, Forbes, Malcolm D. E, Lawrence, David S

“…Cobalamins are known to react with thiols to yield stable β-axial CoIII–S bonded thiolato-cobalamin complexes. However, in stark contrast to the Co–C bond in…”
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Radical–Triplet Pair Interactions as Probes of Long-Range Polymer Motion in Solution by Sim, Sooyeon, Forbes, Malcolm D. E

“…Radical–triplet pair interactions are used to investigate the dynamics of acrylic polymers in dilute solution. Methyl methacrylate was randomly copolymerized…”
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Molecular Dynamics Simulation of Sodium Dodecyl Sulfate Micelle in Water:  Micellar Structural Characteristics and Counterion Distribution by Bruce, Chrystal D, Berkowitz, Max L, Perera, Lalith, Forbes, Malcolm D. E

“…An all-atom 5 nanosecond molecular dynamics simulation of a water-solvated micelle containing 60 sodium dodecyl sulfate monomers was performed. Structural…”
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Molecular Dynamics Simulations of Sodium Dodecyl Sulfate Micelle in Water:  The Behavior of Water by Bruce, Chrystal D, Senapati, Sanjib, Berkowitz, Max L, Perera, Lalith, Forbes, Malcolm D. E

“…Using a 5 ns explicit atom molecular dynamics simulation of a 60 monomer sodium dodecyl sulfate micellar system containing 7579 TIP3P water molecules, the…”
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Kinetic analysis of nitroxide radical formation under oxygenated photolysis: toward quantitative singlet oxygen topology by Zigler, David F, Ding, Eva Chuheng, Jarocha, Lauren E, Khatmullin, Renat R, DiPasquale, Vanessa M, Sykes, R Brendan, Tarasov, Valery F, Forbes, Malcolm D E

“…Reaction kinetics for two sterically hindered secondary amines with singlet oxygen have been studied in detail. A water soluble porphyrin sensitizer,…”
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Supramolecular Photochemistry in β-Cyclodextrin Hosts: A TREPR, NMR, and CIDNP Investigation by Krumkacheva, Olesya A, Gorelik, Vitaly R, Bagryanskaya, Elena G, Lebedeva, Natalia V, Forbes, Malcolm D. E

“…A systematic investigation of the photochemistry and ensuing radical chemistry of three guest ketones encapsulated in randomly methylated β-cyclodextrin (β-CD)…”
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Gateway Reactions to Diverse, Polyfunctional Monolayer-Protected Gold Clusters by Templeton, Allen C, Hostetler, Michael J, Warmoth, Emily K, Chen, Shaowei, Hartshorn, Chris M, Krishnamurthy, Vijay M, Forbes, Malcolm D. E, Murray, Royce W

“…Amide and ester coupling reactions of ω-functionalized monolayer-protected gold cluster molecules (MPCs) are an exceptionally efficient avenue to a diverse…”
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Exploiting chemistry and molecular systems for quantum information science by Wasielewski, Michael R., Forbes, Malcolm D. E., Frank, Natia L., Kowalski, Karol, Scholes, Gregory D., Yuen-Zhou, Joel, Baldo, Marc A., Freedman, Danna E., Goldsmith, Randall H., Goodson, Theodore, Kirk, Martin L., McCusker, James K., Ogilvie, Jennifer P., Shultz, David A., Stoll, Stefan, Whaley, K. Birgitta

“…The power of chemistry to prepare new molecules and materials has driven the quest for new approaches to solve problems having global societal impact, such as…”
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Radical Reactions with Double Memory of Chirality (2MOC) for the Enantiospecific Synthesis of Adjacent Stereogenic Quaternary Centers in Solution: Cleavage and Bonding Faster than Radical Rotation by Resendiz, Marino J. E, Family, Farnosh, Fuller, Kerrian, Campos, Luis M, Khan, Saeed I, Lebedeva, Natalia V, Forbes, Malcolm D. E, Garcia-Garibay, Miguel A

“…The solution photochemistry of bis(phenylpyrrolidinonyl)ketones (R,R)-1b and (S,S)-1b exhibited a remarkably high memory of chirality. Stereospecific…”
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