Search Results - "Fonticelli, Mariano"
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The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model
Published in Accounts of chemical research (21-08-2012)“…Over the last three decades, self-assembled molecular films on solid surfaces have attracted widespread interest as an intellectual and technological challenge…”
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Radiation Damage Mechanisms of Monolayer-Protected Nanoparticles via TEM Analysis
Published in Journal of physical chemistry. C (22-11-2017)“…In this work, it is shown that thiol-protected Au nanoparticles (AuNPs@SR) of approximately 3.4 nm size suffered unexpectedly high radiation damage under…”
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Unraveling the Radiation Damage of n‑Dodecanethiol Self-Assembled Monolayers on Au(100) and Au(111): A Prerequisite to Understand the Oriented Attachment of Au Nanoparticles
Published in Journal of physical chemistry. C (16-12-2021)“…We present a quantitative X-ray photoelectron spectroscopy study on the electron-induced degradation of self-assembled monolayers of n-dodecanethiol on Au(100)…”
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Atomic Sulfur Formation Mechanism on 3‑Mercaptopropanoic Acid Derivative Self-Assembled Monolayers: Understanding the C–S Bond Cleavage
Published in Journal of physical chemistry. C (03-10-2019)“…Self-assembled monolayers (SAMs) of ω-carboxylic acid thiols are very important in the surface modification of metals, especially on gold surfaces. Indeed, the…”
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Understanding the Surface Chemistry of Thiolate-Protected Metallic Nanoparticles
Published in The journal of physical chemistry letters (19-09-2013)“…Metallic nanoparticles (NPs) appear as promising materials to be used in biomedicine, as efficient catalysts and electrocatalysts, and as active elements in…”
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Mechanistic Framework for the Formation of Different Sulfur Species by Electron Irradiation of n‑Dodecanethiol Self-Assembled Monolayers on Au(111) and Au(100)
Published in Journal of physical chemistry. C (15-10-2020)“…The electron-induced damage in self-assembled monolayers (SAMs) of n-dodecanethiolate on Au(111) and Au(100) single-crystalline surfaces is investigated in…”
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New Insights into the Chemistry of Thiolate-Protected Palladium Nanoparticles
Published in Journal of physical chemistry. C (03-05-2012)“…This paper establishes the chemical nature of Pd nanoparticles protected by alkanethiolates that were prepared through a ligand place-exchange approach and the…”
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Silica-coated magnetic particles for efficient RNA extraction for SARS-CoV-2 detection
Published in Heliyon (15-02-2024)“…Molecular diagnostic methods to detect and quantify viral RNA in clinical samples rely on the purification of the genetic material prior to reverse…”
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Influence of Capping on the Atomistic Arrangement in Palladium Nanoparticles at Room Temperature
Published in Journal of physical chemistry. C (23-10-2014)“…The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the…”
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Synthesis and Characterization of Gold@Gold(I)−Thiomalate Core@Shell Nanoparticles
Published in ACS nano (22-06-2010)“…In this paper, the synthesis of gold@gold(I)−thiolate core@shell nanoparticles is described for the first time. The chemical nature and structure of these…”
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A Surface Effect Allows HNO/NO Discrimination by a Cobalt Porphyrin Bound to Gold
Published in Inorganic chemistry (02-08-2010)“…Nitroxyl (HNO) is a small short-lived molecule for which it has been suggested that it could be produced, under certain cofactors conditions, by nitric oxide…”
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Electrochemical and X-ray Photoelectron Spectroscopy Characterization of Alkanethiols Adsorbed on Palladium Surfaces
Published in Journal of physical chemistry. C (23-04-2009)“…The self-assembly of alkanethiolate monolayers on palladium substrates and their stability in aqueous solutions have been studied by electrochemical techniques…”
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The Complex Thiol−Palladium Interface: A Theoretical and Experimental Study
Published in Langmuir (21-09-2010)“…This paper presents a theoretical study of the surface structures and thermodynamic stability of different thiol and sulfide structures present on the…”
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Surface Chemistry of Thiomalic Acid Adsorption on Planar Gold and Gold Nanoparticles
Published in Langmuir (25-02-2014)“…The self-assembly of thiomalic acid (TMA) on Au(111) and on preformed Au nanoparticles (AuNPs) protected by weak ligands has been studied by X-ray…”
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Two-Site Adsorption Model for the (√3 × √3)-R30° Dodecanethiolate Lattice on Au(111) Surfaces
Published in The journal of physical chemistry. B (23-03-2006)“…The surface structure of dodecanethiolate self-assembled monolayers (SAMs) on Au(111) surfaces, formed from the liquid phase, have been studied by grazing…”
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Electrochemical Desorption of Thiolates and Sulfur from Nanoparticle and Planar Platinum Surfaces
Published in Journal of physical chemistry. C (18-04-2013)“…Thiolate-protected platinum nanoparticles have become promising for applications in heterogeneous catalysis and the fabrication of new materials for hydrogen…”
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Electrochemical Deposition onto Self-Assembled Monolayers: New Insights into Micro- and Nanofabrication
Published in Chemistry : a European journal (16-12-2005)“…Pattern transfer with high resolution is a frontier topic in the emerging field of nanotechnologies. Electrochemical molding is a possible route for…”
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Preparation of Ultrathin Thiolate-Covered Bimetallic Systems: From Extended Planar to Nanoparticle Surfaces
Published in Journal of physical chemistry. C (05-07-2007)“…A simple method entirely based on solution chemistry to deposit metals on foreign substrates at underpotential conditions is described. The method allows…”
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Electrochemical stability of metal nanoparticles: The role of size-distribution broadness
Published in Electrochimica acta (20-01-2024)“…In this article, we develop a thermodynamic and an electrochemical kinetic model to study the stability of metal nanoparticles (MNPs) supported on an inert…”
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