Search Results - "Flock, Michaela"

The Role of 2,6-Diaminopyridine Ligands in the Isolation of an Unprecedented, Low-Valent Tin Complex by Flock, Johanna, Suljanovic, Amra, Torvisco, Ana, Schoefberger, Wolfgang, Gerke, Birgit, Pöttgen, Rainer, Fischer, Roland C., Flock, Michaela

“…Stabilization of the central atom in an oxidation state of zero through coordination of neutral ligands is a common bonding motif in transition‐metal…”
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Influence of Ligand Modifications on Structural and Spectroscopic Properties in Terphenyl Based Heavier Group 14 Carbene Homologues by Wilfling, Petra, Schittelkopf, Kathrin, Flock, Michaela, Herber, Rolfe H, Power, Philip P, Fischer, Roland C

“…The synthesis and characterization of a series of heavier group 14 element (Ge, Sn, and Pb) carbene homologues based on the electronically modified,…”
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Nano-Indentation to Determine Mechanical Properties of Intraocular Lenses: Evaluating Penetration Depth, Material Stiffness, and Elastic Moduli by Borkenstein, Andreas F., Borkenstein, Eva-Maria, Mühlbacher, Inge, Flock, Michaela

“…Introduction Intraocular lenses (IOL) should remain in the eye for life after implantation into the capsular bag during cataract surgery. The material must…”
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Structure based descriptors for the estimation of colloidal interactions and protein aggregation propensities by Brunsteiner, Michael, Flock, Michaela, Nidetzky, Bernd

“…The control of protein aggregation is an important requirement in the development of bio-pharmaceutical formulations. Here a simple protein model is proposed…”
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Formation of Formal Disilene Fluoride Adducts by Zirngast, Michaela, Flock, Michaela, Baumgartner, Judith, Marschner, Christoph

“…Reactions of trisilylated silylfluorides with potassium tert-butoxide were found to give disilylated fluorosilylenoids. The latter undergo a self-condensation…”
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Theoretical Study of the Interconversion of O2-Binding Dicopper Complexes by Flock, Michaela, Pierloot, Kristine

“…The structures and interconversion pathway between the [Cu2(μ-η2:η2-O2)]2+ and [Cu2(μ-O)2]2+ isomers of model systems with three ammonia ligands per copper…”
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Lithium Oligophosphanediides in the Li/PhPCl2 System by Stein, Daniel, Dransfeld, Alk, Flock, Michaela, Rüegger, Heinz, Grützmacher, Hansjörg

“…Optimized conditions for the selective synthesis of [Li2(PnPhn)(tmeda)x] (n = 2, 3, 4) have been developed. X‐ray diffraction with single crystals show…”
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Hypersilylphosphanylidene: A Facile Low-Temperature Generation and Formation of Bis(hypersilyl)diphosphene and the Bis(hypersilyl)triphosphaallyl Anion by Cappello, Vittorio, Baumgartner, Judith, Dransfeld, Alk, Flock, Michaela, Hassler, Karl

“…The reaction of hypersilyl(trimethylsilyl)chlorophosphane (SiMe3)3SiP(SiMe3)Cl (1) with tBuOK in THF at –60 °C proceeds by Si–P bond cleavage of the…”
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Ge6Me12 and Ge6H12 Cyclohexagermanes: Conformer Equilibria Studied by Raman Spectroscopy and Quantum Chemical Calculations by Hölbling, Margit, Flock, Michaela, Baumgartner, Judith, Hassler, Karl

“…In the first experimental study of rotational isomerism of a compound possessing a fourth row element backbone, the totally symmetric Ge–Ge stretching mode of…”
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The Solution Structure of (Me3Si)3CSiBr-An Ab Initio/NMR Study by Flock, Michaela, Dransfeld, Alk

“…The first halosilylene stable in solution was investigated by ab initio/NMR calculations (IGLO SOS‐DFPT PW91/B2//B3LYP/6‐31+G(d)). The δ 29Sicalc of…”
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Synthesis and Unusual Reactivity of Acyl-Substituted 1,4-Disilacyclohexa-2,5-dienes by Schuh, Lukas, Torvisco, Ana, Flock, Michaela, Grogger, Christa, Stueger, Harald

“…In continuation of our recent studies on group 14 rings with exocyclic silicon–carbon double bonds, we report here on the synthesis and reactivity of…”
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Synthesis and Photochemistry of Tris(trimethoxysilyl)acyl-silanes and 1,4-Tetrakis(silyl)-1,4-bisacylsilanes by Lainer, Thomas, Pueschmann, Sabrina D., Torvisco, Ana, Fischer, Roland C., Flock, Michaela, Haas, Michael

“…In this contribution, we present the synthesis of two groups of novel acylsilanes 1–6. Compounds 1 and 2 represent tris­(trimethoxysilyl)­acylsilanes, and…”
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An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4 by Steller, Beate G., Roller, Clara A., Flock, Michaela, Fischer, Roland C.

“…Controlled insertion into a single P−P bond of white phosphorus (P4) was achieved by employing a diaryl stabilized stannylene, Ar*2Sn…”
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Synthesis and Properties of Backbone Silylated Imidazol‐2‐thiones by Grogger, Christa, Flock, Michaela, Heurix, Madeleine, Torvisco, Ana, Kyri, Andreas W., Stueger, Harald

“…Imidazole‐2‐thiones have attracted considerable interest in the past as materials for potential applications in the pharmaceutical and chemical industries…”
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An Air-Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P 4 by Steller, Beate G, Roller, Clara A, Flock, Michaela, Fischer, Roland C

“…Controlled insertion into a single P-P bond of white phosphorus (P ) was achieved by employing a diaryl stabilized stannylene, Ar* Sn…”
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Aryltin chlorides and hydrides: Preparation, detailed NMR studies and DFT calculations by Zeppek, Cathrin, Pichler, Johann, Torvisco, Ana, Flock, Michaela, Uhlig, Frank

“…A series of novel tin chlorides RnSnCl4−n and respective hydrides RnSnH4−n were synthesized displaying a range of substituted phenyl residues, as well as…”
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Selective synthesis of tetraarylgermanes and triarylgermanium halides by Wolf, Melanie, Falk, Astrid, Flock, Michaela, Torvisco, Ana, Uhlig, Frank

“…A series of novel and previously published tetraarylgermanes aryl4Ge (aryl = m-tolyl, 3,4-xylyl, 3,5-xylyl, 2-naphthyl) and triarylgermanium halides aryl3GeX…”
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Synthesis and Theoretical Investigation of Diphosphastannylenes by Schwarz, Elisabeth, Mueller, Stefan K, Weinberger, Gernot, Torvisco, Ana, Flock, Michaela

“…The factors affecting the stabilization of diphosphastannylenes, such as substituent size, steric demand, and type of substituent (aryl, alkyl, silyl) were…”
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Phenylene‐Bridged Perylene Monoimides as Acceptors for Organic Solar Cells: A Study on the Structure–Property Relationship by Schweda, Bettina, Reinfelds, Matiss, Hofinger, Jakob, Bäumel, Georg, Rath, Thomas, Kaschnitz, Petra, Fischer, Roland C., Flock, Michaela, Amenitsch, Heinz, Scharber, Markus Clark, Trimmel, Gregor

“…A series of non‐fullerene acceptors based on perylene monoimides coupled in the peri position through phenylene linkers were synthesized via Suzuki‐coupling…”
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Exploration of Novel α,ω‐Substituted Diphosphatrisilanes by Combining Experimental Methods and DFT Calculations by Weinberger, Gernot P., Sommer, Florian, Torvisco, Ana, Fischer, Roland C., Flock, Michaela

“…The novel diphosphatrisilanes {(R2P‐Si(SiMe3)2‐)2‐SiMe2} [R = Ph, H] and the cyclophosphatrisilabutanes {R–PSi3} [R = H, SiMe3] have been prepared via salt…”
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