Search Results - "Fletcher, Philip J."
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Understanding Transient Ionic Diode Currents and Impedance Responses for Aquivion-Coated Microholes
Published in ACS applied materials & interfaces (23-08-2023)“…Ionic diode based devices or circuits can be applied, for example, in electroosmotic pumps or in desalination processes. Aquivion ionomer coated asymmetrically…”
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Photoelectrochemistry of immobilised Pt@g-C3N4 mediated by hydrogen and enhanced by a polymer of intrinsic microporosity PIM-1
Published in Electrochemistry communications (01-06-2019)“…Graphitic carbon nitride with photo-attached platinum nanoparticles of typically 2.5 nm diameter, Pt@g-C3N4, is known for photo-generation of hydrogen in…”
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Paired Electrosynthesis at Interdigitated Microband Electrodes: Exploring Diffusion and Reaction Zones in the Absence of a Supporting Electrolyte
Published in ACS measurement science au (19-06-2024)“…Electrosynthesis traditionally requires dedicated reactor systems and an added electrolyte, although some paired electrosynthesis processes are possible at…”
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Analysis of mosaic mortars from the Roman, Byzantine and Early Islamic periods sourced from Gerasa’s Northwest Quarter
Published in Heritage science (24-05-2024)“…This study analyses and compares around 650 years of mosaic mortar production spanning the Roman, late Roman and Umayyad periods, at Gerasa/Jerash in Jordan,…”
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Defect-Engineered β‑MnO2−δ Precursors Control the Structure–Property Relationships in High-Voltage Spinel LiMn1.5Ni0.5O4−δ
Published in ACS omega (05-10-2021)“…This study examines the role of defects in structure–property relationships in spinel LiMn1.5Ni0.5O4 (LMNO) cathode materials, especially in terms of Mn3+…”
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Switching ionic diode states with proton binding into intrinsically microporous polyamine films (PIM-EA-TB) immersed in ethanol
Published in Journal of electroanalytical chemistry (Lausanne, Switzerland) (01-10-2022)“…[Display omitted] •HClO4 leads to protonation of PIM-EA-TB and to chemical gating as confirmed by EDX and binding constant measurements.•Electrochemical gating…”
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Tuning and Coupling Irreversible Electroosmotic Water Flow in Ionic Diodes: Methylation of an Intrinsically Microporous Polyamine (PIM-EA-TB)
Published in ACS applied materials & interfaces (13-09-2023)“…Molecularly rigid polymers with internal charges (positive charges induced by amine methylation) allow electroosmotic water flow to be tuned by adjusting the…”
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Triphasic Oxygen Storage in Wet Nanoparticulate Polymer of Intrinsic Microporosity (PIM-1) on Platinum: An Electrochemical Investigation
Published in ACS applied materials & interfaces (24-07-2024)“…The triphasic interaction of gases with electrode surfaces immersed in aqueous electrolyte is crucial in electrochemical technologies (fuel cells, batteries,…”
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Effects of g‑C3N4 Heterogenization into Intrinsically Microporous Polymers on the Photocatalytic Generation of Hydrogen Peroxide
Published in ACS applied materials & interfaces (04-05-2022)“…Graphitic carbon nitride (g-C3N4) is known to photogenerate hydrogen peroxide in the presence of hole quenchers in aqueous environments. Here, the g-C3N4…”
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Indirect (hydrogen-driven) electrodeposition of porous silver onto a palladium membrane
Published in Journal of solid state electrochemistry (01-11-2020)“…Hydrogen permeation through a pure palladium film (25 μm thickness, optically dense) is employed to trigger electron transfer (hydrogen-driven) reactions at…”
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Effects of dissolved gases on partial anodic passivation phenomena at copper microelectrodes immersed in aqueous NaCl
Published in Journal of electroanalytical chemistry (Lausanne, Switzerland) (01-09-2020)“…Anodic passivation for copper exposed to aqueous NaCl (model seawater) is rate limited by diffusion of a poorly soluble Cu(I) chloro species. As a result, a…”
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Polymer indicator displacement assay: electrochemical glucose monitoring based on boronic acid receptors and graphene foam competitively binding with poly-nordihydroguaiaretic acid
Published in Analyst (London) (14-02-2022)“…The concept of a reversible polymer displacement sensor mechanism for electrochemical glucose monitoring is demonstrated. A pyrene-derivatised boronic acid…”
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Electroanalysis with a single microbead of phosphate binding resin (FerrIX™) mounted in epoxy film
Published in Journal of solid state electrochemistry (01-12-2021)“…Commercial resin microbeads are widely applied in ion exchange and extraction. Here, a single anion-selective and phosphate binding resin microbead (FerrIX™)…”
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Effects of g-C 3 N 4 Heterogenization into Intrinsically Microporous Polymers on the Photocatalytic Generation of Hydrogen Peroxide
Published in ACS applied materials & interfaces (04-05-2022)“…Graphitic carbon nitride (g-C N ) is known to photogenerate hydrogen peroxide in the presence of hole quenchers in aqueous environments. Here, the g-C N…”
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Hydrogen Peroxide Versus Hydrogen Generation at Bipolar Pd/Au Nano-catalysts Grown into an Intrinsically Microporous Polyamine (PIM-EA-TB)
Published in Electrocatalysis (01-11-2021)“…Binding of PdCl 4 2− into the polymer of intrinsic microporosity PIM-EA-TB (on a Nylon mesh substrate) followed by borohydride reduction leads to uncapped…”
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Linking the Cu(II/I) and the Ni(IV/II) Potentials to Subsequent Passive Film Breakdown for a Cu−Ni Alloy in Aqueous 0.5 M NaCl
Published in ChemElectroChem (02-01-2020)“…Copper and copper–nickel alloys are known to form partially passive films in marine conditions, both naturally and under positive potential bias. Here, the…”
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Ionic diode desalination: Combining cationic Nafion™ and anionic Sustainion™ rectifiers
Published in Micro and Nano Engineering (01-08-2022)“…Microscale ionic rectifier effects are commonly observed in devices based on semipermeable ionomer coated on an array of microholes with potential applications…”
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Ionic Diode and Molecular Pump Phenomena Associated with Caffeic Acid Accumulated into an Intrinsically Microporous Polyamine (PIM‐EA‐TB)
Published in ChemElectroChem (01-06-2021)“…The polymer of intrinsic microporosity PIM‐EA‐TB provides a molecularly rigid micropore structure containing tertiary amine sites and is shown here to interact…”
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Size‐Selective Photoelectrochemical Reactions in Microporous Environments: Clark Probe Investigation of Pt@g‐C3N4 Embedded into Intrinsically Microporous Polymer (PIM‐1)
Published in ChemElectroChem (13-09-2021)“…Graphitic carbon nitride (g‐C3N4) with photo‐attached platinum (Pt@g‐C3N4) is known to generate hydrogen under illumination in aqueous environments in the…”
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Pyrene-Appended Boronic Acids on Graphene Foam Electrodes Provide Quantum Capacitance-Based Molecular Sensors for Lactate
Published in ACS sensors (22-03-2024)“…Molecular recognition and sensing can be coupled to interfacial capacitance changes on graphene foam surfaces linked to double layer effects and coupled to…”
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