Search Results - "Fiedler, Pavel"
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Asymmetric Synthesis of Diastereo‐ and Enantiopure Bioxahelicene 2,2′‐Bipyridines
Published in European journal of organic chemistry (09-10-2018)“…A versatile asymmetric synthesis of five C2 symmetric enantio‐ and diastereopure bioxa[5]‐ and bioxa[6]helicene 2,2′‐bipyridines was developed. It relied…”
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Highly modular assembly of cationic helical scaffolds: rapid synthesis of diverse helquats via differential quaternization
Published in Tetrahedron (08-05-2010)“…A protocol for rapid and highly modular assembly of a diverse set of helquats is described. From a common bis-isoquinoline precursor, two successive distinct…”
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Synthesis of 3-Hexahelicenol and Its Transformation to 3-Hexahelicenylamines, Diphenylphosphine, Methyl Carboxylate, and Dimethylthiocarbamate
Published in Journal of organic chemistry (27-06-2003)“…A nonphotochemical synthetic route to 3-hexahelicenol is reported. It involves a key [2+2+2] cycloisomerization of CH3O-substituted triyne that is readily…”
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A Convenient Route to 2-Hydroxy- and 2,15-Dihydroxyhexahelicene
Published in European Journal of Organic Chemistry (01-09-2007)“…2‐Hydroxy‐ and 2,15‐dihydroxyhexahelicene were synthesised from simple benzene and naphthalene building blocks by intramolecular CoI‐ or Ni0‐catalysed [2+2+2]…”
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The synthesis of phosphonic acids derived from homocysteine via transesterification reactions
Published in ARKIVOC (01-01-2012)Get full text
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The quest for alternative routes to racemic and nonracemic azahelicene derivatives
Published in Collection of Czechoslovak chemical communications (2009)“…A series of diverse aromatic azadienetriyne and azatriynes was synthesised. These compounds were subjected to transition metal-mediated [2+2+2]…”
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Conformation and Steric Effects in Mono- and Dimethoxybenzoic Acids
Published in Journal of organic chemistry (14-05-1999)“…The conformation of mono- and dimethoxybenzoic acids in solution was determined from their IR spectra and 13C and 1H NMR spectra. The main feature is a strong…”
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Rapid Access to Dibenzohelicenes and their Functionalized Derivatives
Published in Angewandte Chemie International Edition (16-09-2013)“…Spiraling up: Easy access to dibenzo[5]‐, dibenzo[6]‐, and dibenzo[7]helicenes (see picture) as well as their functionalized derivatives includes Sonogashira…”
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[2+2+2] Cycloisomerisation of Aromatic Cyanodiynes in the Synthesis of Pyridohelicenes and Their Analogues
Published in Chemistry : a European journal (26-09-2016)“…We have developed a methodology for the synthesis of pyridohelicenes and their analogues based on the Ni0‐, CoI‐ or RhI‐mediated intramolecular [2+2+2]…”
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Synthesis of Racemic, Diastereopure, and Enantiopure Carba- or Oxa[5]‑, [6]‑, [7]‑, and -[19]helicene (Di)thiol Derivatives
Published in Journal of organic chemistry (03-01-2020)“…A series of carba- or oxa[5]-, [6]-, [7]-, and -[19]helicene (di)thiols was prepared. The Miyazaki–Newman–Kwart rearrangement of (dimethylcarbamothioyl)oxy…”
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Synthesis of [alpha]-carboxyphosphinopeptides derived from norleucine
Published in Amino acids (01-11-2010)“…In the present study, we describe in detail the synthesis of a relatively rare class of phosphorus compounds, α-carboxyphosphinopeptides. We prepared several…”
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A convenient, high-yield synthesis of 1-substituted uracil and thymine derivatives
Published in Tetrahedron (10-10-2009)“…Novel reagents for the synthesis of 1-substituted uracil and thymine derivatives have been developed. The aminolysis of 2- or 4-nitrophenyl…”
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A Ferrier-Type Allylic Rearrangement of 3′-Deoxy-3′,4′-didehydronucleosides Mediated by DMF Dimethyl Acetal: Direct Access to 4′-Alkoxy-2′,3′-didehydro-2′,3′-dideoxynucleosides
Published in Organic letters (19-08-2011)“…A straightforward synthesis of epimeric 4′-alkoxy-substituted 2′,3′-didehydro-2′,3′-dideoxynucleosides via a DMF dimethyl acetal mediated allylic rearrangement…”
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Synthesis of [5]-, [6]-, and [7]Helicene via Ni(0)- or Co(I)-Catalyzed Isomerization of Aromatic cis,cis-Dienetriynes
Published in Journal of the American Chemical Society (07-08-2002)“…An original approach to helicene frameworks exploiting atom economic isomerization of appropriate energy-rich aromatic cis,cis-dienetriynes has been developed…”
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Synthesis of α-carboxyphosphinopeptides derived from norleucine
Published in Amino acids (01-11-2010)“…In the present study, we describe in detail the synthesis of a relatively rare class of phosphorus compounds, α-carboxyphosphinopeptides. We prepared several…”
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Efficient synthesis of phosphonodepsipeptides derived from norleucine
Published in Tetrahedron (01-08-2009)“…In the present work, we describe in detail an efficient solution synthesis of norleucine-derived phosphonopeptides mimicking the peptide sequences Nle-Gly(Ala)…”
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Rapid Access to Dibenzohelicenes and their Functionalized Derivatives
Published in Angewandte Chemie (16-09-2013)“……︁ 5,6,7 …︁: Über Sonogashira‐ und Suzuki‐Miyaura‐Kupplungen, Desilylierung und [2+2+2]‐Alkincycloisomerisierung sind Dibenzo[5]‐, Dibenzo[6]‐ und…”
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Transition metal control in the reaction of alkyne-substituted phenyl iodides with terminal alkynes: Sonogashira coupling vs cyclic carbopalladation
Published in Tetrahedron (28-10-2002)“…Reaction between terminal alkynes and phenyl iodides bearing a tethered alkyne unit can be effectively controlled by the nature of a transition metal catalyst…”
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Nonsaponifiable lipid components of the pollen of elder ( Sambucus nigra L.)
Published in Journal of Chromatography A (30-11-2001)“…Pollen of the elder ( Sambucus nigra L.) was extracted with chloroform–methanol. The extract was separated by column chromatography into the following groups…”
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