Search Results - "Fellhauer, D."
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The role of the 5f valence orbitals of early actinides in chemical bonding
Published in Nature communications (06-07-2017)“…One of the long standing debates in actinide chemistry is the level of localization and participation of the actinide 5 f valence orbitals in covalent bonds…”
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Thermodynamic description of U(IV) solubility and hydrolysis in chloride systems: Pitzer activity model for the system U4+–Na+–Mg2+–Ca2+–H+–Cl––OH––H2O(l)
Published in Applied geochemistry (01-09-2024)“…This study presents updated chemical, thermodynamic, and activity models for the system U4+–Na+–Mg2+–Ca2+–H+–Cl––OH––H2O(l) derived using the Pitzer formalism…”
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3
Solubility and stability of liebigite, Ca2UO2(CO3)3·10H2O(cr), in dilute to concentrated NaCl and NaClO4 solutions at T = 22–80 °C
Published in Applied geochemistry (01-12-2019)“…The solubility and thermodynamic stability of a synthetic liebigite was investigated in NaCl and NaClO4 solutions within a wide range of ionic strength…”
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Plutonium retention in the isosaccharinate – cement system
Published in Applied geochemistry (01-03-2021)“…Uptake of plutonium by Portland cement in degradation stage II was investigated in the presence of α-D-isosaccharinic acid (ISA) under reducing conditions set…”
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Thermodynamic description of the plutonium – α-d-isosaccharinic acid system I: Solubility, complexation and redox behavior
Published in Applied geochemistry (01-11-2018)“…The impact of α-d-isosaccharinic acid (HISA), a degradation product of cellulose, on the solubility and redox behavior of hydrous Pu(IV) oxide was investigated…”
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Thermodynamic description of the plutonium – α–d–isosaccharinic acid system ii: Formation of quaternary Ca(II)–Pu(IV)–OH–ISA complexes
Published in Applied geochemistry (01-11-2018)“…The quaternary system Ca(II)–Pu(III/IV)–OH–ISA was investigated in a series of solubility experiments where equilibrium conditions were reached from…”
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