Search Results - "Felfoldi, Karoly"
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New data on the effect of steric constraints on the chiral induction in the Orito reaction: Hydrogenation of activated steroid ketones
Published in Journal of molecular catalysis. A, Chemical (15-10-2008)“…After optimization of the experimental conditions, the Orito reaction may be rendered suitable for the asymmetric hydrogenation of activated steroid ketones. ▪…”
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Up to 96% Enantioselectivities in the Hydrogenation of Fluorine Substituted (E)-2,3-Diphenylpropenoic Acids over Cinchonidine-Modified Palladium Catalyst
Published in Advanced synthesis & catalysis (17-11-2008)“…The enantioselective hydrogenation of methoxy‐ and fluorine‐substituted (E)‐2,3‐diphenylpropenoic acid derivatives was studied over cinchonidine‐modified,…”
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Effect of the substituent position on the enantioselective hydrogenation of methoxy-substituted 2,3-diphenylpropenoic acids over palladium catalyst
Published in Journal of molecular catalysis. A, Chemical (01-07-2008)“…The position of the methoxy substituent has crucial influence on the enantioselective hydrogenation of the methoxy-substituted 2,3-diphenylpropenoic acids over…”
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Enantioselective hydrogenation of ethyl pyruvate catalyzed by α- and β-isocinchonine-modified Pt/Al2O3 in acetic acid
Published in Journal of catalysis (15-11-2003)Get full text
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Enantioselective hydrogenation of propenoic acids bearing heteroaromatic substituents over cinchonidine modified Pd/alumina
Published in Catalysis communications (10-03-2009)“…The hydrogenation of two 2,3-diarylpropenoic acids bearing heteroaromatic substituents, i.e. ( E)-2-phenyl-3-(2-furyl)propenoic acid and (…”
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Study of enantioselective hydrogenation of bulky esters of phenylglyoxylic acid on Pt-CD and Pt- β-ICN chiral catalysts: Steric effect of ester groups and inversion of enantioselectivity
Published in Journal of catalysis (01-07-2006)“…Enantioselective hydrogenation of seven different esters of phenylglyoxylic acid was investigated by variation of the bulkiness at ester side of the substrates…”
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C9-O-substituted derivatives of cinchona alkaloids as chiral modifiers in the Orito-reaction: Effects of structure of modifiers on sense of enantioselectivity
Published in Journal of molecular catalysis. A, Chemical (16-03-2006)“…In hydrogenation of ethyl pyruvate when the bulk of X was increased, the enantioselectivity not only decreased, but inversion also took place dependent on…”
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Enantioselective hydrogenation of trifluoromethylcyclohexyl ketone on cinchona alkaloid modified Pt-alumina catalyst
Published in Catalysis letters (01-08-2004)“…The enantioselective heterogeneous catalytic hydrogenation of trifluoromethylcyclohexyl ketone (2), on Pt-alumina (E4759) modified by different chiral…”
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Preparation of 3-substituted and 2,3-disubstituted-4,4,4-trifluoro-2-butenoic acids—Perkin condensation of activated aromatic ketones
Published in Journal of fluorine chemistry (01-07-2006)“…Stereoisomeric CF 3-substituted cinnamic acid derivatives have been prepared via the Perkin reaction using activated aromatic ketones. ▪ The Perkin reaction of…”
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Heterogeneous asymmetric reactions: Part 32. High enantioselectivities in the hydrogenation of activated ketones on cinchona alkaloid modified platinum-alumina catalysts
Published in Journal of molecular catalysis. A, Chemical (01-08-2003)“…The modifier concentration dependence of rate and enantioselectivity (ee) was investigated of the diethyl-2-oxoglutarate (EOG) and pyruvaldehyde dimethyl…”
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Heterogeneous asymmetric reactions 20. Effect of ultrasonic variables on the enantiodifferentiation in cinchona-modified platinum-catalyzed sonochemical hydrogenations
Published in Catalysis letters (01-07-2002)“…The effect of sonochemical variables on a cinchona alkaloid modified Pt/Al2O3 catalyst system and its application in α-ketoester hydrogenation are described…”
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Heterogeneous asymmetric reactions. 29. Enantioselective hydrogenation of ethyl benzoylformate over dihydrocinchonidine-modified platinum-alumina catalyst in acetic acid
Published in Catalysis letters (01-08-2002)“…The enantioselective hydrogenation of ethyl benzoylformate to (R)-ethyl mandelate over dihydrocinchonidine (DHCD)-modified Pt/Al2O3 catalyst in acetic acid was…”
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Preparation of new 2,3-diphenylpropenoic acid esters - good yields even for the more hindered Z isomers
Published in Molecules (Basel, Switzerland) (31-03-2004)“…The potassium salt of E- and Z-2,3-diphenylpropenoic acids prepared in situ could be esterified efficiently in DMSO with the appropriate alkyl halides at room…”
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Structural characterization of acetylpyridinium-ethyl pyruvate adducts by electrospray ionization mass spectrometry
Published in Journal of mass spectrometry. (01-10-2002)“…The reactions of ethyl pyruvate with acetic anhydride and pyridine were studied by electrospray ionization mass spectrometry (ESI‐MS). Ethyl…”
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98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al2O3 catalysts in the acetic acid
Published in Catalysis communications (01-03-2002)Get full text
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Heterogeneous asymmetric reactions: Part 38. Enantioselective hydrogenation of fluoroketones on Pt–alumina catalyst
Published in Journal of molecular catalysis. A, Chemical (12-07-2004)“…We investigated the enantioselective heterogeneous hydrogenation of some fluoroketones, e.g. 4-(trifluoroacetyl)biphenyl (max. 67% ee), on modified Pt–alumina…”
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Enantioselective hydrogenation of fluorinated unsaturated carboxylic acids over cinchona alkaloid modified palladium catalysts
Published in Catalysis communications (01-03-2008)“…The hydrogenation of trifluoromethyl substituted prochiral α,β-unsaturated carboxylic acids has been studied over cinchona alkaloid modified palladium…”
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