Search Results - "Faustov, Valery I"
-
1
Structure and Stereodynamics of N,N-Bis(silyloxy)enamines
Published in Journal of the American Chemical Society (25-09-2002)“…The structure and stereodynamics of N,N-bis(silyloxy)enamines (1), a new class of enamines with extraordinary reactivity, have been simulated by the DFT…”
Get full text
Journal Article -
2
A Highly Delocalized Triplet Carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: Matrix IR Identification, Structure, and Reactions
Published in Journal of the American Chemical Society (21-10-2009)“…The first representative of highly delocalized triplet carbenes bearing both vinyl and ethynyl groups at the formal carbene center,…”
Get full text
Journal Article -
3
Gas-Phase Kinetics of Chlorosilylene Reactions. I. ClSiH + Me3SiH: Absolute Rate Measurements and Theoretical Calculations for Prototype Si−H Insertion Reactions
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-05-2009)“…Time-resolved studies of chlorosilylene, ClSiH, generated by the 193 nm laser flash photolysis of 1-chloro-1-silacyclopent-3-ene, have been carried out to…”
Get full text
Journal Article -
4
Surprisingly Slow Reaction of Dimethylsilylene with Dimethylgermane: Time-Resolved Kinetic Studies and Related Quantum Chemical Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (07-02-2008)“…Time-resolved studies of silylene, SiH2, and dimethylsilylene, SiMe2, generated by the 193 nm laser flash photolysis of appropriate precursor molecules have…”
Get full text
Journal Article -
5
A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies
Published in Physical chemistry chemical physics : PCCP (21-08-2007)“…Time-resolved studies of germylene, GeH(2), and dimethygermylene, GeMe(2), generated by the 193 nm laser flash photolysis of appropriate precursor molecules…”
Get more information
Journal Article -
6
First Gas-Phase Detection of Dimethylstannylene and Time-Resolved Study of Some of Its Reactions
Published in Journal of the American Chemical Society (26-06-2002)“…Using a laser flash photolysis/laser probe technique, we report the observation of strong absorption signals in the wavelength region 450−520 nm (highest…”
Get full text
Journal Article -
7
The Prototype Ge−H Insertion Reaction of Germylene with Germane. Absolute Rate Constants, Temperature Dependence, RRKM Modeling and the Potential Energy Surface
Published in Journal of the American Chemical Society (09-12-1998)“…Time-resolved studies of germylene, GeH2, generated by laser flash photolysis of 3,4-dimethylgermacyclopentene-3, have been carried out to obtain rate…”
Get full text
Journal Article -
8
Gas-Phase Kinetics of Chlorosilylene Reactions. I. ClSiH + Me 3 SiH: Absolute Rate Measurements and Theoretical Calculations for Prototype Si−H Insertion Reactions
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-05-2009)Get full text
Journal Article -
9
-
10
-
11
The insertion of germylene into the H-H bond; rate constant limits and thermochemistry. Ab initio and DFT calculations on the reactions of GeH(2) and SiH(2) with H(2)
Published in Canadian journal of chemistry (01-11-2000)“…The technique of laser flash photolysis in the gas-phase has been used to set limits on the rate constants for the bimolecular reaction of germylene (GeH2)…”
Get full text
Journal Article -
12
The insertion of germylene into the HH bond; rate constant limits and thermochemistry. Ab initio and DFT calculations on the reactions of GeH 2 and SiH 2 with H 2
Published in Canadian journal of chemistry (01-11-2000)“…The technique of laser flash photolysis in the gas-phase has been used to set limits on the rate constants for the bimolecular reaction of germylene (GeH 2 )…”
Get full text
Journal Article -
13
First gas-phase detection of dimethylstannylene and time-resolved study of some of its reactions
Published in Journal of the American Chemical Society (2002)Get full text
Journal Article -
14
Structure and stereodynamics of N, N-bis(silyloxy)enamines
Published in Journal of the American Chemical Society (2002)Get full text
Journal Article -
15
The insertion of germylene into the HH bond; rate constant limits and thermochemistry. Ab initio and DFT calculations on the reactions of GeH2 and SiH2 with H2
Published in Canadian journal of chemistry (01-11-2000)“…The technique of laser flash photolysis in the gas-phase has been used to set limits on the rate constants for the bimolecular reaction of germylene (GeH 2 )…”
Get full text
Journal Article