Search Results - "Farley, Robert D."
-
1
Direct Observation of Enantiomer Discrimination of Epoxides by Chiral Salen Complexes Using ENDOR
Published in Journal of the American Chemical Society (08-12-2004)“…Electron nuclear double resonance (ENDOR) spectroscopy was used to investigate the weak enantioselective binding between chiral salen complexes [VO(1)] ((R,R)-…”
Get full text
Journal Article -
2
Surface Defect Sites Formed on Partially and Fully Dehydrated MgO: An EPR/ENDOR Study
Published in The journal of physical chemistry. B (18-03-1999)“…EPR and ENDOR spectroscopy have been used to investigate a variety of trapped electron centers on the surface of polycrystalline MgO. The oxide was dehydrated…”
Get full text
Journal Article -
3
Principles and applications of ENDOR spectroscopy for structure determination in solution and disordered matrices
Published in Chemical Society reviews (01-03-2006)“…Both electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) spectroscopies are extremely powerful and versatile methods for the…”
Get more information
Journal Article -
4
Early Transition Metal Complexes of Triphosphorus Macrocycles
Published in European journal of inorganic chemistry (01-08-2002)“…The reactions of 1,5,9‐triethyl‐1,5,9‐triphosphacyclododecane, [12]aneP3Et3, with first‐row transition metal halides MCl3 [M = Ti (1), V (2), and Cr (3)] or…”
Get full text
Journal Article -
5
A Thiazyl-Based Organic Ferromagnet
Published in Angewandte Chemie International Edition (13-10-2003)“…The sulfur–nitrogen radical p‐O2NC6F4CNSSN. (see packing diagram) provides a rare example of an organic radical that orders ferromagnetically above 1 K. It is…”
Get full text
Journal Article -
6
An EPR and ENDOR Investigation of a Series of Diazabutadiene-Group 13 Complexes
Published in Chemistry : a European journal (06-05-2005)“…Paramagnetic diazabutadienegallium(II or III) complexes, [(Ar‐DAB)2Ga] and [{(Ar‐DAB.)GaX}2] (X=Br or I; Ar‐DAB={N(Ar)C(H)}2, Ar=2,6‐diisopropylphenyl), have…”
Get full text
Journal Article -
7
Engineering a Remarkably Low HOMO-LUMO Gap by Covalent Linkage of a Strong π-Donor and a π-Acceptor-Tetrathiafulvalene-σ-Polynitrofluorene Diads: Their Amphoteric Redox Behavior, Electron Transfer and Spectroscopic Properties
Published in Chemistry : a European journal (18-10-2002)“…Novel R3TTF–σ–A compounds 14, 16 and 19 (R3TTF=trialkyltetrathiafulvalene, σ=saturated spacer, A=polynitrofluoren‐9‐dicyanomethylene acceptor) incorporating…”
Get full text
Journal Article -
8
The synthesis and structure of terpyridine-N-oxide complexes of copper(II) perchlorate
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2008)“…The co-ordination of a series of terpyridine-N-oxide ligands to the Cu(ii) ion is reported. Addition of two equivalents of ligand results in the formation of…”
Get more information
Journal Article -
9
An ENDOR and DFT analysis of ‘solvatochromic’ effects in an oxovanadium (IV) complex
Published in Chemical physics letters (28-10-2003)“…The ‘solvatochromic’ effects of a vanadyl salen complex [VO IV(salen)] in frozen solution was studied by ENDOR and DFT calculations. In a non-coordinating…”
Get full text
Journal Article -
10
The [1,2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression
Published in Tetrahedron letters (06-11-2006)“…The lithium enolate formed from methyl S-trityl mercaptoacetate can be C-alkylated in high yield at or below −40 °C, but at higher temperatures the…”
Get full text
Journal Article -
11
Long range superhyperfine interactions in polycrystalline vanadium doped SnO 2 investigated by CW and pulsed ENDOR spectroscopy
Published in Chemical physics letters (2004)“…CW and pulsed ENDOR was used to probe the electron nuclear superhyperfine interactions between V 4+ ions and distant Sn nuclei in vanadium doped tin oxide…”
Get full text
Journal Article -
12
Long range superhyperfine interactions in polycrystalline vanadium doped SnO2 investigated by CW and pulsed ENDOR spectroscopy
Published in Chemical physics letters (11-06-2004)Get full text
Journal Article -
13
Engineering a Remarkably Low HOMO–LUMO Gap by Covalent Linkage of a Strong -Donor and a -Acceptor—Tetrathiafulvalene--Polynitrofluorene Diads: Their Amphoteric Redox Behavior, Electron Transfer and Spectroscopic Properties
Published in Chemistry : a European journal (18-10-2002)Get full text
Journal Article -
14
An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other heteroatoms
Published in Magnetic resonance in chemistry (01-11-2002)“…11B hyperfine and quadrupolar couplings have been observed by the electron magnetic resonance techniques electron nuclear double resonance and hyperfine…”
Get full text
Journal Article -
15
THE ORGANIC FERROMAGNET p -O 2 NC 6 F 4 CNSSN
Published in Phosphorus, sulfur, and silicon and the related elements (01-04-2004)Get full text
Journal Article -
16
Heterogeneity of surface colour centres on alkaline earth metal oxides as revealed through EPR/ENDOR spectroscopy
Published in Magnetic resonance in chemistry (01-06-2002)“…A variety of surface anion vacancies, or point defects, are created by high‐temperature activation of a series of polycrystalline alkaline earth metal oxides…”
Get full text
Journal Article -
17
THE ORGANIC FERROMAGNET p-O2NC6F4CNSSN
Published in Phosphorus, sulfur, and silicon and the related elements (01-04-2004)Get full text
Journal Article -
18
A Thiazyl-Based Organic Ferromagnet
Published in Angewandte Chemie (13-10-2003)“…Das Schwefel‐Stickstoff‐Radikal p‐O2NC6F4CNSSN. (siehe Kristallstrukturbild) ist eines von wenigen organischen Radikalen, die oberhalb von 1 K Ferromagnetismus…”
Get full text
Journal Article -
19
A Thiazyl‐Based Organic Ferromagnet
Published in Angewandte Chemie (13-10-2003)Get full text
Journal Article