Search Results - "Falcone, R. Dario"
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Physicochemical, in vitro antioxidant and cytotoxic properties of water-soluble chitosan-lactose derivatives
Published in Carbohydrate polymers (15-11-2019)“…•Water-soluble chitosan-lactose derivatives were synthesized by Maillard reaction.•Derivatives with lower Mw, DD and greater solubility than chitosan were…”
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AOT reverse micelles as versatile reaction media for chitosan nanoparticles synthesis
Published in Carbohydrate polymers (01-09-2017)“…AOT Reverse Micelles can be used as versatile and controlled reaction media to synthesis of monodisperse Chitosan nanoparticles. [Display omitted] •Ch-NPs were…”
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Hydrolysis Reactions of Two Benzoyl Chlorides as a Probe to Investigate Reverse Micelles Formed by the Ionic Liquid-Surfactant bmim–AOT
Published in Journal of organic chemistry (04-12-2020)“…In this work, two hydrolysis reactions were used as a probe to investigate the properties of reverse micelles (RMs) formed by the ionic liquid-surfactant…”
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4
Interfacial Dynamics and Its Relations with “Negative” Surface Viscosities Measured at Water–Air Interfaces Covered with a Cationic Surfactant
Published in Langmuir (25-06-2019)“…We studied the dynamics of a cationic surfactant monolayer, Gemini 12-2-12, at the air–water interface for surfactant aqueous solutions at concentrations below…”
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Influence of the AOT Counterion Chemical Structure on the Generation of Organized Systems
Published in Langmuir (15-09-2020)“…The impact of the imidazolium counterion structure on the organized systems formed by the surfactant 1,4-bis-2-ethylhexylsulfosuccinate, AOT, both in aqueous…”
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Characterization of Reverse Micelles Formulated with the Ionic-Liquid-like Surfactant Bmim-AOT and Comparison with the Traditional Na-AOT: Dynamic Light Scattering, 1H NMR Spectroscopy, and Hydrolysis Reaction of Carbonate as a Probe
Published in Langmuir (01-10-2019)“…The present study investigated how the presence of butylmethylimidazolium cation (bmim+) alters the interfacial properties of reverse micelles (RMs) created…”
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Structural Characterization of Biocompatible Reverse Micelles Using Small-Angle X‑ray Scattering, 31P Nuclear Magnetic Resonance, and Fluorescence Spectroscopy
Published in The journal of physical chemistry. B (19-04-2018)“…The most critical problem regarding the use of reverse micelles (RMs) in several fields is the toxicity of their partial components. In this sense, many…”
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Is it Necessary for the Use of Fluorinated Compounds to Formulate Reverse Micelles in a Supercritical Fluid? Searching the Best Cosurfactant to Create "Green" AOT Reverse Micelle Media
Published in Langmuir (12-01-2021)“…Herein, we report the effect of employing two different alcohols, such as -pentanol and 2,2,3,3,4,4,5,5-octafluoro pentanol (from now on F-pentanol), into…”
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9
Catanionic nanocarriers as a potential vehicle for insulin delivery
Published in Colloids and surfaces, B, Biointerfaces (01-04-2020)“…[Display omitted] •Stability of BHD-AOT Catanionic vesicles were investigated in different conditions.•BHD-AOT vesicles are an excellent nanocarrier for oral…”
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Spontaneous formation of unilamellar vesicles based on the surfactant 1-methylimidazolium bis-(2-ethylhexyl) phosphate, evaluated as a function of pH and in saline solution
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (05-12-2020)“…1-methylimidazolium bis-(2-ethylhexyl) phosphate as an interesting surfactant able to create spontaneously unilamellar vesicles in water under different…”
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A Unique Ionic Liquid with Amphiphilic Properties That Can Form Reverse Micelles and Spontaneous Unilamellar Vesicles
Published in Chemistry : a European journal (03-12-2012)“…Catanionic surfactants: The synthesis of a new surfactant ionic liquid with unique properties is described. The formation of reverse micelles in benzene and…”
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12
Ionic Liquids Entrapped in Reverse Micelles as Nanoreactors for Bimolecular Nucleophilic Substitution Reaction. Effect of the Confinement on the Chloride Ion Availability
Published in Langmuir (21-10-2014)“…In this work was explored how the confinement of two ionic liquids (ILs), 1-butyl-3-methylimidazolium chloride (bmimCl) and 1-butyl-3-methylimidazolium…”
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13
More Evidence on the Control of Reverse Micelles Sizes. Combination of Different Techniques as a Powerful Tool to Monitor AOT Reversed Micelles Properties
Published in The journal of physical chemistry. B (11-04-2013)“…In this work, we have investigated the behavior of 4-aminophthalimide (4-AP) in solvent mixtures of ethyl lactate (EL)– water and EL–n-heptane and in reversed…”
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14
Comparison between Phosphonium Docusate Ionic Liquids and Their Equimolar Mixtures with Alkanes: Temperature-Dependent Viscosity, Glass Transition, and Fragility
Published in ACS omega (17-09-2024)“…In this study, we determined the temperature-dependent viscosities, glass transition temperatures, and fragilities of tetraalkylphosphonium docusate ionic…”
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Catanionic Reverse Micelles as an Optimal Microenvironment To Alter the Water Electron Donor Capacity in a SN2 Reaction
Published in Journal of organic chemistry (01-02-2019)“…The effect of interfacial water entrapped in two types of catanionic reverse micelles (RMs) on the kinetic parameters of the SN2 reaction between…”
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Biocompatible Solvents and Ionic Liquid-Based Surfactants as Sustainable Components to Formulate Environmentally Friendly Organized Systems
Published in Polymers (23-04-2021)“…In this review, we deal with the formation and application of biocompatible water-in-oil microemulsions commonly known as reverse micelles (RMs). These RMs are…”
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Singularities in the physicochemical properties of spontaneous AOT-BHD unilamellar vesicles in comparison with DOPC vesicles
Published in Physical chemistry chemical physics : PCCP (14-07-2015)“…In the present work, we study different physicochemical properties of the spontaneous unilamellar vesicles created by the catanionic ionic liquid-like…”
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18
Comparison between Two Anionic Reverse Micelle Interfaces: The Role of Water-Surfactant Interactions in Interfacial Properties
Published in Chemphyschem (16-01-2012)“…The water/sodium bis(2‐ethylhexyl) phosphate (NaDEHP) reverse micelle (RM) system is revisited by using, for the first time, molecular probes to investigate…”
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19
Solvent Blends Can Control Cationic Reversed Micellar Interdroplet Interactions. The Effect of n-Heptane:Benzene Mixture on BHDC Reversed Micellar Interfacial Properties: Droplet Sizes and Micropolarity
Published in The journal of physical chemistry. B (27-10-2011)“…We have investigated, for the first time, the effect of the composition of the nonpolar organic media on the benzyl-n-hexadecyl-dimethylammonium chloride…”
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20
Effect of Confinement on the Properties of Sequestered Mixed Polar Solvents: Enzymatic Catalysis in Nonaqueous 1,4-Bis-2-ethylhexylsulfosuccinate Reverse Micelles
Published in Chemphyschem (03-06-2016)“…The influence of different glycerol, N,N‐dimethylformamide (DMF) and water mixtures encapsulated in 1,4‐bis‐2‐ethylhexylsulfosuccinate (AOT)/n‐heptane reverse…”
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