Search Results - "Fairbanks, Benjamin D"

Toward Stimuli‐Responsive Dynamic Thermosets through Continuous Development and Improvements in Covalent Adaptable Networks (CANs) by Podgórski, Maciej, Fairbanks, Benjamin D., Kirkpatrick, Bruce E., McBride, Matthew, Martinez, Alina, Dobson, Adam, Bongiardina, Nicholas J., Bowman, Christopher N.

“…Covalent adaptable networks (CANs), unlike typical thermosets or other covalently crosslinked networks, possess a unique, often dormant ability to activate one…”
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Biomedical applications of polymers derived by reversible addition – fragmentation chain-transfer (RAFT) by Fairbanks, Benjamin D., Gunatillake, Pathiraja A., Meagher, Laurence

“…RAFT- mediated polymerization, providing control over polymer length and architecture as well as facilitating post polymerization modification of end groups,…”
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Efficient Polymer‐Polymer Conjugation via Thiol‐ene Click Reaction by Fairbanks, Benjamin D., Love, Dillon M., Bowman, Christopher N.

“…Despite the rapid reaction rates and high efficiency of the radical‐mediated thiol‐ene reactions in high concentrations, complications arise when implementing…”
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A Versatile Synthetic Extracellular Matrix Mimic via Thiol-Norbornene Photopolymerization by Fairbanks, Benjamin D., Schwartz, Michael P., Halevi, Alexandra E., Nuttelman, Charles R., Bowman, Christopher N., Anseth, Kristi S.

“…Step‐growth, radically mediated thiol‐norbornene photopolymerization is used to create versatile, stimuli‐responsive poly(ethylene glycol)‐co‐peptide hydrogels…”
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Evaluation of Aromatic Thiols as Photoinitiators by Love, Dillon M, Fairbanks, Benjamin D, Bowman, Christopher N

“…The unique photodynamics of aromatic thiols (relative to alkyl thiols) allowed their employment as effective ultraviolet and visible light photoinitiators…”
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Thiol−Yne Photopolymerizations: Novel Mechanism, Kinetics, and Step-Growth Formation of Highly Cross-Linked Networks by Fairbanks, Benjamin D, Scott, Timothy F, Kloxin, Christopher J, Anseth, Kristi S, Bowman, Christopher N

“…Radical-mediated thiol−yne step-growth photopolymerizations are utilized to form highly cross-linked polymer networks. This reaction mechanism is shown to be…”
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Characterization of valvular interstitial cell function in three dimensional matrix metalloproteinase degradable PEG hydrogels by Benton, Julie A, Fairbanks, Benjamin D, Anseth, Kristi S

“…Abstract Valvular interstitial cells (VICs) maintain functional heart valve structure and display transient fibroblast and myofibroblast properties. Most cell…”
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Reaction Rates and Mechanisms for Radical, Photoinitated Addition of Thiols to Alkynes, and Implications for Thiol−Yne Photopolymerizations and Click Reactions by Fairbanks, Benjamin D, Sims, Evan A, Anseth, Kristi S, Bowman, Christopher N

“…Because of its utility in network polymerization, dendrimer synthesis, and monomer development, the photoinitiated addition of thiols to alkynes has rapidly…”
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Inhibition of Protein and Cell Attachment on Materials Generated from N‑(2-Hydroxypropyl) Acrylamide by Fairbanks, Benjamin D, Thissen, Helmut, Maurdev, George, Pasic, Paul, White, Jacinta F, Meagher, Laurence

“…Effective control over biointerfacial interactions is essential for a broad range of biomedical applications. At this point in time, only a relatively small…”
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Radical‐Mediated Degradation of Thiol–Maleimide Hydrogels by Hebner, Tayler S., Kirkpatrick, Bruce E., Fairbanks, Benjamin D., Bowman, Christopher N., Anseth, Kristi S., Benoit, Danielle S.W.

“…Michael addition between thiol‐ and maleimide‐functionalized molecules is a long‐standing approach used for bioconjugation, hydrogel crosslinking, and the…”
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Photoclick Chemistry: A Bright Idea by Fairbanks, Benjamin D, Macdougall, Laura J, Mavila, Sudheendran, Sinha, Jasmine, Kirkpatrick, Bruce E, Anseth, Kristi S, Bowman, Christopher N

“…At its basic conceptualization, photoclick chemistry embodies a collection of click reactions that are performed via the application of light. The emergence of…”
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Fast self-healing engineered by UV-curable polyurethane contained Diels-Alder structure by Wang, Zhengyue, Yang, Haitao, Fairbanks, Benjamin D., Liang, Hongbo, Ke, Junjun, Zhu, Chunfang

“…[Display omitted] A series of UV-curable polyurethanes were made by copolymerization of isocyanate monomers with various diols (PLA1000/PEG2000/HPDMS). The…”
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Development of thiourethanes as robust, reprocessable networks by Wen, Zhibin, Han, Xun, Fairbanks, Benjamin D., Yang, Keke, Bowman, Christopher N.

“…In this letter, we present a robust covalent adaptable network (CAN) that relies on dynamic, exchangeable thiourethanes. A primary aliphatic isocyanate,…”
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Photodegradable, Photoadaptable Hydrogels via Radical-Mediated Disulfide Fragmentation Reaction by Fairbanks, Benjamin D, Singh, Samir P, Bowman, Christopher N, Anseth, Kristi S

“…Various techniques have been adopted to impart a biological responsiveness to synthetic hydrogels for the delivery of therapeutic agents as well as the study…”
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Synthesis and Assembly of Click‐Nucleic‐Acid‐Containing PEG–PLGA Nanoparticles for DNA Delivery by Harguindey, Albert, Domaille, Dylan W., Fairbanks, Benjamin D., Wagner, Justine, Bowman, Christopher N., Cha, Jennifer N.

“…Co‐delivery of both chemotherapy drugs and siRNA from a single delivery vehicle can have a significant impact on cancer therapy due to the potential for…”
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Photoinitiated polymerization of PEG-diacrylate with lithium phenyl-2,4,6-trimethylbenzoylphosphinate: polymerization rate and cytocompatibility by Fairbanks, Benjamin D, Schwartz, Michael P, Bowman, Christopher N, Anseth, Kristi S

“…Abstract Due to mild reaction conditions and temporal and spatial control over material formation, photopolymerization has become a valuable technique for the…”
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Photoinduced Dithiolane Crosslinking for Multiresponsive Dynamic Hydrogels by Nelson, Benjamin R., Kirkpatrick, Bruce E., Miksch, Connor E., Davidson, Matthew D., Skillin, Nathaniel P., Hach, Grace K., Khang, Alex, Hummel, Sydney N., Fairbanks, Benjamin D., Burdick, Jason A., Bowman, Christopher N., Anseth, Kristi S.

“…While many hydrogels are elastic networks crosslinked by covalent bonds, viscoelastic hydrogels with adaptable crosslinks are increasingly being developed to…”
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Spatial and Temporal Control of Photomediated Disulfide–Ene and Thiol–Ene Chemistries for Two-Stage Polymerizations by Soars, Shafer M, Bongiardina, Nicholas J, Fairbanks, Benjamin D, Podgórski, Maciej, Bowman, Christopher N

“…A new strategy is reported for the design and synthesis of high sulfur-containing materials for potential use in covalent adaptable networks and optical…”
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Sequence‐Controlled Synthesis of Advanced Clickable Synthetic Oligonucleotides by Han, Xun, Fairbanks, Benjamin D., Sinha, Jasmine, Bowman, Christopher N.

“…Through thiol‐ene photopolymerization of presynthesized oligomers, advanced clickable nucleic acids (CNA‐2G) are synthesized with sequence‐controlled repeating…”
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Light‐Activated Stress Relaxation, Toughness Improvement, and Photoinduced Reversal of Physical Aging in Glassy Polymer Networks by Sowan, Nancy, Song, Han Byul, Cox, Lewis M., Patton, James R., Fairbanks, Benjamin D., Ding, Yifu, Bowman, Christopher N.

“…A covalent adaptable network (CAN) with high glass transition temperature (Tg), superior mechanical properties including toughness and ductility, and…”
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