Search Results - "Fagan, Paul J"
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Catalytic Deoxygenation of 1,2-Propanediol to Give n-Propanol
Published in Advanced synthesis & catalysis (01-03-2009)“…Deoxygenation of 1,2‐propanediol (1.0 M in sulfolane) catalyzed by bis(dicarbonyl)(μ‐hydrido)(pentamethylcyclopentadiene)ruthenium trifluoromethanesulfonate…”
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Using Intelligent/Random Library Screening To Design Focused Libraries for the Optimization of Homogeneous Catalysts: Ullmann Ether Formation
Published in Journal of the American Chemical Society (31-05-2000)“…A 96-member “pyridine” library consisting of both rationally chosen and “random” members was used to screen Ullmann ether forming reactions. The reaction of…”
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Quantum interference of large organic molecules
Published in Nature communications (01-04-2011)“…The wave nature of matter is a key ingredient of quantum physics and yet it defies our classical intuition. First proposed by Louis de Broglie a century ago,…”
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Metal-Catalyzed Selective Deoxygenation of Diols to Alcohols
Published in Angewandte Chemie International Edition (15-10-2001)“…The internal OH group of 1,2‐propanediol is selectively removed in the deoxygenation catalyzed by [{Cp*Ru(CO)2}2(μ‐H)]+OTf− (1, Cp*=C3Me5,…”
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Metallacycle Transfer from Zirconium to Main Group Elements: A Versatile Synthesis of Heterocycles
Published in Journal of the American Chemical Society (01-03-1994)Get full text
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Synthesis of Novel (P,S) Ligands Based on Chiral Nonracemic Episulfides. Use in Asymmetric Hydrogenation
Published in Organometallics (24-05-1999)“…A strategy for the synthesis of new chiral (P,S) ligands is described. It is based on the opening of chiral nonracemic episulfides using phosphorus…”
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The Chemical Nature of Buckminsterfullerene (C$_60$) and the Characterization of a Platinum Derivative
Published in Science (American Association for the Advancement of Science) (24-05-1991)“…Little is known about the chemical nature of the recently isolated carbon clusters (C$_{60}$, C$_{70}$, C$_{84}$, and so forth). One potential application of…”
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Versatile Approaches to the Polymer-Supported Synthesis of Bidentate Phosphorus-Containing Ligands
Published in Angewandte Chemie International Edition (16-03-2001)“…A simple route to new diphosphane ligands: Merrifield's resin was used to construct diphosphanes of the general formula 1 that could be cleaved by reaction…”
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Molecular engineering of solid-state materials: organometallic building blocks
Published in Journal of the American Chemical Society (01-03-1989)Get full text
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Synthesis of main group heterocycles by metallacycle transfer from zirconium
Published in Journal of the American Chemical Society (01-03-1988)Get full text
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Synthesis of Ruthenium Carbonyl Complexes with Phosphine or Substituted Cp Ligands, and Their Activity in the Catalytic Deoxygenation of 1,2-Propanediol
Published in Inorganic chemistry (20-07-2009)“…A ruthenium hydride with a bulky tetra-substituted Cp ligand, (Cpi Pr4 )Ru(CO)2H (Cpi Pr4 = C5(i-C3H7)4H) was prepared from the reaction of Ru3(CO)12 with…”
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Catalytic Ionic Hydrogenation of Ketones by {[CpRu(CO)2]2(μ-H)}
Published in Organometallics (22-02-2010)“…{[Cp*Ru(CO)2]2(μ-H)}+OTf − functions as a homogeneous catalyst precursor for hydrogenation of ketones to alcohols, with hydrogenations at 1 mol % catalyst…”
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Production of Perfluoroalkylated Nanospheres from Buckminsterfullerene
Published in Science (American Association for the Advancement of Science) (15-10-1993)“…Perfluoroalkylated nanospheres have been prepared by reaction of fullerenes with a variety of fluoroalkyl radicals. The latter are generated by thermal or…”
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Design and Study of Rh(III) Catalysts for the Selective Tail-to-Tail Dimerization of Methyl Acrylate
Published in Journal of the American Chemical Society (01-09-1994)Get full text
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Molybdenum Carbonyl Complexes in the Solvent-Free Catalytic Hydrogenation of Ketones
Published in Organometallics (05-12-2005)“…The heterodifunctional ligand Li[η5-C5H4(CH2)2PR2] (R = Ph, Cy, and tBu) reacts with Mo(CO)3(diglyme) to give the molybdenum anion complex…”
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Estimation of Atmospheric Lifetimes of Hydrofluorocarbons, Hydrofluoroethers, and Olefins by Chlorine Photolysis Using Gas-Phase NMR Spectroscopy
Published in Analytical chemistry (Washington) (15-08-2008)“…An empirical correlation has been derived between accepted atmospheric lifetimes of a set of hydrofluorocarbons and hydrofluoroethers and relative rates of…”
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Synthesis and Nucleophilic Substitution of Highly Chlorinated Arene (.eta.5-Pentamethylcyclopentadienyl)ruthenium .pi.-Complexes
Published in Organometallics (01-08-1995)Get full text
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Automated Electrochemical Analysis with Combinatorial Electrode Arrays
Published in Analytical chemistry (Washington) (01-10-1999)“…Two combinatorial approaches for rapid automated screening of electrochemical activity of modified electrode surfaces are described. One approach enables…”
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