Search Results - "Faetti, M."
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Rheological and Thermal Properties of Narrow Distribution Poly(ethyl acrylate)s
Published in Macromolecules (07-03-2006)“…In the present work, we characterize the rheological behavior of 10 nearly monodisperse poly(ethyl acrylate) samples, whose molar mass ranges from 1200 to 150…”
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Connecting Shear Stress Relaxation and Enthalpy Recovery in Polymers through a Modified TNM Approach
Published in Macromolecules (19-10-2004)“…The Tool−Narayanaswamy−Moynihan model (TNM) is widely accepted in order to describe the enthalpy recovery mechanism of polymers. However, some problems have…”
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Near-field optical writing on azo-polymethacrylate spin-coated films
Published in Optics communications (01-09-2002)“…We report on near-field optical writing and topographic reading of spin-coated azo-polymethacrylate films with subwavelength resolution. The sample is…”
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Scaling Analysis and Distribution of the Rotational Correlation Times of a Tracer in Rubbery and Glassy Poly(vinyl acetate): An Electron Spin Resonance Investigation
Published in Macromolecules (23-03-1999)“…We studied by ESR the rotational motion of a paramagnetic tracer (a deuterated 15N-enriched nitroxide) in poly(vinyl acetate) (PVAc). The reorientation of the…”
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Heterogeneities at short and long time scales of the dynamics of a probe molecule in different model glass formers
Published in Journal of non-crystalline solids (01-10-2006)“…The correlations, namely dynamic heterogeneity, and different relaxation time and length scales were investigated in two model glass formers. Decoupling…”
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Rotational probe relaxation and scaling in fragile glass formers
Published in Journal of non-crystalline solids (01-05-2002)“…The rotational dynamics of a stiff paramagnetic tracer dissolved in supercooled SALOL is investigated via electron spin resonance spectroscopy. The study shows…”
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Dynamics, fragility, and glass transition of low-molecular-weight linear homopolymers
Published in Philosophical magazine (2003. Print) (21-11-2008)“…Analysis of the dynamics of low-molar-mass linear homopolymers is important when trying to understand the mechanisms driving structural relaxation properties…”
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Free volume in poly(propylene glycol) and its relationships to spin probe reorientation
Published in Journal of non-crystalline solids (15-11-2006)“…In this work we carried out positron annihilation lifetime spectroscopy (PALS) on pure poly(propylene glycol) (PPG 4000) and an electron spin resonance (ESR)…”
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Previous exposure to (±) 3,4-methylenedioxymethamphetamine produces long-lasting alteration in limbic brain excitability measured by electroencephalogram spectrum analysis, brain metabolism and seizure susceptibility
Published in Neuroscience (2005)“…Seizures represent the most common neurological emergency in ecstasy abusers; however, no study addressed whether (±) 3,4-methylenedioxymethamphetamine…”
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Scaling of the Rotational Relaxation of Tracers in o-Terphenyl: A Linear and Nonlinear ESR Study
Published in The journal of physical chemistry. B (20-05-1999)“…The rotational dynamics at long and short times of nearly spherical and cylindrical tracers in supercooled and glassy o-terphenyl is investigated by linear and…”
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Phenomenological theory of structural relaxation based on a thermorheologically complex relaxation time distribution
Published in The European physical journal. E, Soft matter and biological physics (01-09-2008)“…The aim of this work is to explore the consequences on the kinetics of structural relaxation of considering a glass-forming system to consist of a series of…”
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An ESR Study on the Heterogeneity of Dynamics in a Nematic Polymer Induced by Thermal Annealing in the Isotropic Melt
Published in Macromolecules (09-10-2001)“…Heterogeneities induced in a nematic polymethacrylate by thermal annealing in the isotropic phase were investigated by studying the dynamics of the cholestane…”
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Thermorheological Simplicity and Fragility of Azobenzene Nematogenic Side-Chain Polymers
Published in Macromolecular symposia (01-02-2008)“…The linear viscoelastic response of polymers from a nematogenic azobenzene methacrylate and its copolymers with nonmesogenic methyl methacrylate was studied…”
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Journal Article Conference Proceeding -
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Heterogeneities in the Dynamics of a Molecular Tracer in Mesogenic and Nonmesogenic Azobenzene Copolymers
Published in Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) (01-07-2006)“…We studied by electron spin resonance (ESR) spectroscopy the reorientational dynamics of the cholestane spin probe dissolved in the matrix of the PMA4 40/60…”
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Probing the cooperative dynamics varying the side-chain length of poly(alkyl acrylate)s: ESR experiments
Published in Philosophical magazine (2003. Print) (01-01-2007)“…The rotational dynamics of the tracer cholestane dissolved in non-entangled nearly monodisperse poly(alkyl acrylate) melts has been investigated by means of…”
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17
Fragility and Glass Transition Temperature in the Rheological Response of Azobenzene Copolymers
Published in Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) (01-07-2006)“…Two copolymers containing nonmesogenic methyl methacrylate (MMA) and nematogenic azobenzene methacrylate (MA4) side groups (30/70 and 40/60 copolymers)…”
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Crossover region and entanglement in nearly monodisperse poly(ethyl acrylates) studied with electron spin resonance spectroscopy
Published in Philosophical magazine (2003. Print) (01-05-2004)“…The topic of dynamic changes undergone by glass-forming materials in the supercooled region is addressed in this study. Crossover regions and temperatures are…”
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Journal Article Conference Proceeding -
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A Trap Model Description of Enthalpy Relaxation in a Side Chain Liquid Crystal Polymethacrylate
Published in Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) (01-05-2005)“…The enthalpy relaxation mechanism of an azobenzene side chain liquid crystal polymethacrylate is investigated by means of DSC experiments after proper…”
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Heterogeneity in the dynamics of a molecular tracer dissolved in liquid crystal homopolymer and copolymer
Published in Molecular crystals and liquid crystals (Philadelphia, Pa. : 2003) (01-01-2004)“…ESR studies were carried out on the rotational dynamics of cholestane molecular tracer dissolved in liquid crystal homopolymer and copolymer from well above…”
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