Search Results - "Fadaei Tirani, Farzaneh"

The role of bridging ligands in dinitrogen reduction and functionalization by uranium multimetallic complexes by Falcone, Marta, Barluzzi, Luciano, Andrez, Julie, Fadaei Tirani, Farzaneh, Zivkovic, Ivica, Fabrizio, Alberto, Corminboeuf, Clemence, Severin, Kay, Mazzanti, Marinella

“…Cooperativity between metal centres is identified as a crucial step in dinitrogen reduction both for the industrial Haber–Bosch process and for the natural…”
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Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex by Falcone, Marta, Poon, Lok Nga, Fadaei Tirani, Farzaneh, Mazzanti, Marinella

“…Cleavage of dihydrogen is an important step in the industrial and enzymatic transformation of N2 into ammonia. The reversible cleavage of dihydrogen was…”
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Synthesis of Heteroaryl Triazenes via Rh(III)‐catalyzed Annulation Reactions with Alkynyl Triazenes by Wezeman, Tim, Scopelliti, Rosario, Tirani, Farzaneh Fadaei, Severin, Kay

“…A synthetic route towards polycyclic heteroaryl triazenes has been developed. Alkynyl triazenes were coupled to phenyl‐substituted indoles, imidazoles and…”
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Light‐Switchable Buffers by Berton, Cesare, Busiello, Daniel Maria, Zamuner, Stefano, Scopelliti, Rosario, Fadaei‐Tirani, Farzaneh, Severin, Kay, Pezzato, Cristian

“…A visible light‐switchable buffer system based on a merocyanine photoacid is presented. Para‐substitution of the indolium side with a methoxy group affords a…”
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Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle by Li, Ru‐Jin, Fadaei‐Tirani, Farzaneh, Scopelliti, Rosario, Severin, Kay

“…Spherical assemblies of the type [PdnL2n]2n+ can be obtained from PdII salts and curved N‐donor ligands, L. It is well established that the bent angle, α, of…”
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LiBF4‐Induced Rearrangement and Desymmetrization of a Palladium‐Ligand Assembly by Sudan, Sylvain, Fadaei‐Tirani, Farzaneh, Scopelliti, Rosario, Ebbert, Kristina E., Clever, Guido H., Severin, Kay

“…Thirteen palladium‐ligand assemblies with different structures and topologies were investigated for the ability to bind lithium ions. In one case, the addition…”
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Synthesis and Reactivity of an Anionic Diazoolefin by Kooij, Bastiaan, Dong, Zhaowen, Fadaei‐Tirani, Farzaneh, Scopelliti, Rosario, Severin, Kay

“…Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C‐donor ligands, and diverse applications in coordination chemistry…”
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Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4 by Chatelain, Lucile, Faizova, Radmila, Fadaei‐Tirani, Farzaneh, Pécaut, Jacques, Mazzanti, Marinella

“…Herein we report the assembly of large uranium(IV) clusters with novel nuclearities and/or shapes from the controlled hydrolysis of UCl4 in organic solution…”
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Synthetic Receptors with Micromolar Affinity for Chloride in Water by Sudan, Sylvain, Chen, Damien W., Berton, Cesare, Fadaei‐Tirani, Farzaneh, Severin, Kay

“…A water‐soluble coordination cage was obtained by reaction of Pd(NO3)2 with a 1,3‐di(pyridin‐3‐yl)benzene ligand featuring a short PEG chain. The cavity of the…”
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Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand by Kooij, Bastiaan, Chen, Damien W., Fadaei‐Tirani, Farzaneh, Severin, Kay

“…Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a…”
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Synthesis of Tetraarylethene Luminogens by C−H Vinylation of Aromatic Compounds with Triazenes by Suleymanov, Abdusalom A., Doll, Martin, Ruggi, Albert, Scopelliti, Rosario, Fadaei‐Tirani, Farzaneh, Severin, Kay

“…Tetraarylethenes are obtained by acid‐induced coupling of vinyl triazenes with aromatic compounds. This new C−H activation route for the synthesis of…”
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Ligand‐Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media by Faizova, Radmila, Fadaei‐Tirani, Farzaneh, Bernier‐Latmani, Rizlan, Mazzanti, Marinella

“…Reduction of uranyl(VI) to UV and to UIV is important in uranium environmental migration and remediation processes. The anaerobic reduction of a uranyl UVI…”
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Lewis Acid‐Mediated One‐Electron Reduction of Nitrous Oxide by Liu, Yizhu, Solari, Euro, Scopelliti, Rosario, Fadaei Tirani, Farzaneh, Severin, Kay

“…The one‐electron reduction of nitrous oxide (N2O) was achieved using strong Lewis acids E(C6F5)3 (E=B or Al) in combination with metallocenes. In the case of…”
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Synthesis and Characterization of Water Stable Uranyl(V) Complexes by Faizova, Radmila, Fadaei‐Tirani, Farzaneh, Chauvin, Anne‐Sophie, Mazzanti, Marinella

“…The importance of uranyl(V) (UO2+) species associated with environmental and geologic applications is becoming increasingly evident, but the tendency of the…”
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Delivery of a Masked Uranium(II) by an Oxide‐Bridged Diuranium(III) Complex by Modder, Dieuwertje K., Palumbo, Chad T., Douair, Iskander, Fadaei‐Tirani, Farzaneh, Maron, Laurent, Mazzanti, Marinella

“…Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are…”
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Head‐to‐Tail Dimerization of N‐Heterocyclic Diazoolefins by Varava, Paul, Wong, Tak Hin, Dong, Zhaowen, Gitlina, Anastasia Yu, Sienkiewicz, Andrzej, Feuerstein, Wolfram, Scopelliti, Rosario, Fadaei‐Tirani, Farzaneh, Severin, Kay

“…The head‐to‐tail dimerization of N‐heterocyclic diazoolefins is described. The products of these formal (3+3) cycloaddition reactions are strongly reducing…”
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Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study by Dong, Zhaowen, Blaskovits, J. Terence, Fadaei‐Tirani, Farzaneh, Scopelliti, Rosario, Sienkiewicz, Andrzej, Corminboeuf, Clémence, Severin, Kay

“…Mesoionic imidazolylidenes are recognized as excellent electron‐donating ligands in organometallic and main group chemistry. However, these carbene ligands…”
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A catalytically active [Mn]-hydrogenase incorporating a non-native metal cofactor by Pan, Hui-Jie, Huang, Gangfeng, Wodrich, Matthew D., Tirani, Farzaneh Fadaei, Ataka, Kenichi, Shima, Seigo, Hu, Xile

“…Nature carefully selects specific metal ions for incorporation into the enzymes that catalyse the chemical reactions necessary for life. Hydrogenases, enzymes…”
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One-Pot Synthesis of Trisubstituted Triazenes from Grignard Reagents and Organic Azides by Suleymanov, Abdusalom A, Scopelliti, Rosario, Fadaei Tirani, Farzaneh, Severin, Kay

“…A simple and versatile method for the preparation of linear, trisubstituted triazenes is reported. The procedure is based on the reaction of Grignard reagents…”
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Ethynylbenziodazolones (EBZ) as Electrophilic Alkynylation Reagents for the Highly Enantioselective Copper‐Catalyzed Oxyalkynylation of Diazo Compounds by Hari, Durga Prasad, Schouwey, Lionel, Barber, Verity, Scopelliti, Rosario, Fadaei‐Tirani, Farzaneh, Waser, Jerome

“…Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents are now established reagents for the alkynylation of radicals and nucleophiles, yet they…”
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