Search Results - "Fabretti, Antonio C."
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Direct Observation of Single-Molecule Magnets Organized on Gold Surfaces
Published in Angewandte Chemie International Edition (11-04-2003)“…Scanning tunneling microscopy can be utilized to individually probe single‐molecule magnets that have been deposited on gold substrates (see schematic). Dilute…”
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Energy-Barrier Enhancement by Ligand Substitution in Tetrairon(III) Single-Molecule Magnets
Published in Angewandte Chemie International Edition (20-02-2004)“…A relaxing time: A dramatic increase of the energy barrier (Ueff) in tetrairon(III) single‐molecule magnets can be achieved by simple chemical modification…”
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Structure and Magnetic Properties of a Dodecanuclear Twisted-Ring Iron(III) Cluster
Published in Angewandte Chemie International Edition (03-05-1999)“…An unprecedented nonplanar structure characterizes the complex [Fe(OCH3)2(dbm)]12 (on the left in the picture), which contains the largest cyclic ferric…”
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Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Cluster
Published in Inorganic chemistry (27-07-1998)“…Two novel polynuclear manganese(II,III) complexes have been synthesized by exploiting controlled methanolysis. A one-pot reaction of MnCl2, NaOMe,…”
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Tuning Anisotropy Barriers in a Family of Tetrairon(III) Single-Molecule Magnets with an S = 5 Ground State
Published in Journal of the American Chemical Society (12-04-2006)“…Tetrairon(III) Single-Molecule Magnets (SMMs) with a propeller-like structure exhibit tuneable magnetic anisotropy barriers in both height and shape. The…”
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Molecule-Based Magnets: Ferro- and Antiferromagnetic Interactions in Copper(II)−Polyorganosiloxanolate Clusters
Published in Inorganic chemistry (17-07-1996)“…The magnetic behavior of the clusters [(PhSiO2)6Cu6(O2SiPh)6]·6EtOH (1), Na4[(PhSiO2)12Cu4]·8 n BuOH (2), and K4[(C2H3SiO2)12Cu4]·6 n BuOH (3) has been…”
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Manganese(III) Formate: A Three-Dimensional Framework That Traps Carbon Dioxide Molecules
Published in Angewandte Chemie International Edition (14-06-1999)“…Carbon dioxide, formic acid, and water molecules are trapped in the crystal lattice of manganese(III) formate (see 1), which was obtained by reducing…”
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Self-Assembly of High-Nuclearity Metal Clusters: Programmed Expansion of a Metallasiloxane Cage to an Octacopper(II) Cluster
Published in Inorganic chemistry (26-07-2004)“…The novel octanuclear copper(II) cluster [Cu6{(PhSiO2)6}2{NCCu(Me6tren)}2(MeOH)4]2+ (1) has been isolated as a perchlorate salt by reacting the hexacopper(II)…”
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A Ferromagnetic Ring of Six Manganese(III) Ions with a S = 12 Ground State
Published in Inorganic chemistry (06-04-1998)Get full text
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Synthesis, crystal structures and magnetic characterization of four β-diketonate-alkoxide iron(III) dimers. Dependence of the magnetic properties on geometrical and electronic parameters
Published in Inorganica Chimica Acta (01-10-1997)“…Synthesis, crystallographic characterization and magnetic properties of the dinuclear iron(III) complexes [Fe(OMe)(dbm) 2] 2 ( 1), [Fe(OMe)(dpm) 2] 2 ( 2),…”
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Modulated Magnetic Coupling in Alkoxoiron(III) Rings by Host−Guest Interactions with Alkali Metal Cations
Published in Inorganic chemistry (31-12-1997)Get full text
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Towards Stepwise Cluster Assembly: A Decacopper(II) Complex Obtained by Controlled Expansion of a Metallasiloxane Cage
Published in Angewandte Chemie International Edition (02-12-2002)“…A decacopper(II) cluster. Clusters (shown in blue) can be expanded and their magnetic properties tuned by the addition of suitable metal‐complex ligands (shown…”
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Single-Ion versus Dipolar Origin of the Magnetic Anisotropy in Iron(III)-Oxo Clusters: A Case Study
Published in Chemistry : a European journal (17-04-2001)“…A multitechnique approach has allowed the first experimental determination of single‐ion anisotropies in a large iron(III)‐oxo cluster, namely…”
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Post-synthetic isotopic labeling of an azamacrocyclic ligand
Published in Tetrahedron letters (28-01-2002)Get full text
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New perspectives in phosphonodithioate coordination chemistry. Synthesis and X-ray crystal structure of trans-bis-[ O-ethyl-(4-methoxyphenyl)phosphonodithioato] nickel(II)
Published in Inorganica Chimica Acta (30-09-1997)“…Attempts to optimise the synthesis of a new class of nickel(II) dithiolene complexes starting from 1,3-dialkylimidazolidine-2-thione-4,5-dione ( 1) and…”
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Molecule-Based Magnets: Ferro- and Antiferromagnetic Interactions in Nickel(II) Cyclohexasiloxanolate Sandwich Complexes
Published in Inorganic chemistry (01-10-1995)Get full text
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Structure ofcatena-(2-amino-1,3,4-thiadiazolium, 2-amino-1,3,4-thiadiazole bis(μ-iodo)-di-iodo-bismuth(III)
Published in Journal of chemical crystallography (01-04-1994)Get full text
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Electronic Structure of Manganese(III) Compounds from High-Frequency EPR Spectra
Published in Angewandte Chemie International Edition (14-11-1997)“…The use of high magnetic field and high frequency in an unconventional spectrometer has provided very informative EPR spectra of a manganese(III) octahedral…”
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Cover Picture: Angew. Chem. Int. Ed. 23/2002
Published in Angewandte Chemie International Edition (02-12-2002)“…The cover picture shows a magnetic cluster, which was rationally designed by following a two‐step synthetic approach (color code: light blue = Cu, orange = Si,…”
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