Search Results - "FURUTA, Hiroyuki"
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Creation from Confusion and Fusion in the Porphyrin WorldThe Last Three Decades of N‑Confused Porphyrinoid Chemistry
Published in Chemical reviews (11-05-2022)“…Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady stream of new chemistry since the discovery of N-confused porphyrin, a…”
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Blooming of confused porphyrinoids--fusion, expansion, contraction, and more confusion
Published in Chemical communications (Cambridge, England) (25-01-2012)“…This article introduces an overview of progressively developing chemistry of N-confused porphyrin and related macrocycles. Study on confusion results in…”
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Introduction: Expanded, Contracted, and Isomeric Porphyrins
Published in Chemical reviews (22-02-2017)Get full text
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Macrocycle Contraction and Expansion of a Dihydrosapphyrin Isomer
Published in Journal of the American Chemical Society (26-12-2013)“…Cyclization of a pentapyrrane with two terminal β-linked pyrroles afforded a dihydrosapphyrin isomer (1) with the pyrroles linked in a unique β,α–α,β mode,…”
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5
Benzo[c,d]indole-Containing Aza-BODIPY Dyes: Asymmetrization-Induced Solid-State Emission and Aggregation-Induced Emission Enhancement as New Properties of a Well-Known Chromophore
Published in Chemistry : a European journal (07-09-2015)“…A series of symmetric and asymmetric benzo[c,d]indole‐containing aza boron dipyrromethene (aza‐BODIPY) compounds was synthesized by a titanium…”
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Benzo‐Tetrathiafulvalene‐ (BTTF‐) Annulated Expanded Porphyrins: Potential Next‐Generation Multielectron Reservoirs
Published in Chemistry : a European journal (01-03-2021)“…Two sterically crowded benzo‐tetrathiafulvalene (BTTF)‐annulated expanded porphyrins (BTTF7‐F and BTTF8) are synthesized. Detailed photophysical investigations…”
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Iridium Complex of N‐Fused Bilatrienone: Oxidative Cleavage of N‐Fused Porphyrin Induced by Iridium‐Cyclooctadiene Complexation
Published in Chemistry : a European journal (04-06-2021)“…N‐fused porphyrin (NFP) is a unique class of photostable near‐infrared dyes with an 18π aromatic tetrapyrrole macrocyclic skeleton containing a tri‐fused…”
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Bis-Metal Complexes of Doubly N‑Confused Dioxohexaphyrins as Potential Near-Infrared-II Photoacoustic Dyes
Published in Journal of the American Chemical Society (04-03-2020)“…We investigated the detailed photophysical properties of a series of bis-metal (Zn and Cu) dioxohexaphyrin complexes as potential second near-infrared…”
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Expanded N‑Confused Phlorin: A Platform for a Multiply Fused Polycyclic Ring System via Oxidation within the Macrocycle
Published in Journal of the American Chemical Society (07-10-2020)“…Novel interrupted π-conjugated macrocycles derived from expanded porphyrinoids were synthesized, and their unique reactivity was investigated in this work. The…”
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Doubly N‐Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis‐Metal Coordination, and Topological Chirality
Published in Angewandte Chemie International Edition (06-11-2017)“…A novel [36]octaphyrin analogue embedding two N‐confused pyrrole units demonstrated unique prototropy‐coupled isomerization between the Figure‐of‐eight and…”
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Regioselectively α- and β-alkynylated BODIPY dyes via gold(I)-catalyzed direct C-H functionalization and their photophysical properties
Published in Beilstein journal of organic chemistry (01-04-2020)“…A series of α- and β-ethynyl-substituted BODIPY derivatives ( , , , ) were synthesized by gold(I)-catalyzed direct C-H alkynylation reactions of dipyrromethane…”
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NH Tautomerism of N‑Confused Porphyrin: Solvent/Substituent Effects and Isomerization Mechanism
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-07-2020)“…The effects of substituents and solvents on the NH tautomerism of N-confused porphyrin (2) were investigated. The structures, electronic states, and…”
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Ruthenocene-Type Complexes of N-Fused Porphyrins
Published in Chemistry : a European journal (06-06-2016)“…Ruthenocene‐type hybrid complexes with N‐fused porphyrinato ligands, [Ru(NFp)Cp] (NFp=N‐fused porphyrin, Cp=cyclopentadienyl), have been prepared and…”
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Ground-State Copper(III) Stabilized by N‑Confused/N-Linked Corroles: Synthesis, Characterization, and Redox Reactivity
Published in Journal of the American Chemical Society (06-06-2018)“…Stable square planar organocopper(III) complexes (CuNCC2, CuNCC4, and CuBN) supported by carbacorrole-based tetradentate macrocyclic ligands with NNNC…”
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A Computational Study on the Mechanism of Catalytic Cyclopropanation Reaction with Cobalt N-Confused Porphyrin: The Effects of Inner Carbon and Intramolecular Axial Ligand
Published in Molecules (Basel, Switzerland) (26-10-2022)“…The factors that affect acceleration and high trans/cis selectivity in the catalytic cyclopropanation reaction of styrene with ethyl diazoacetate by cobalt…”
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Theoretical Study on the Conformation and Aromaticity of Regular and Singly N‑Confused [28]Hexaphyrins
Published in Journal of organic chemistry (20-09-2013)“…Structures and electronic states of regular and singly N-confused [28]hexaphyrins(1.1.1.1.1.1) were thoroughly studied with the aid of DFT calculations. To…”
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Near‐Infrared‐III‐Absorbing and ‐Emitting Dyes: Energy‐Gap Engineering of Expanded Porphyrinoids via Metallation
Published in Angewandte Chemie International Edition (07-09-2020)“…The synthesis of organometallic complexes of modified 26π‐conjugated hexaphyrins with absorption and emission capabilities in the third near‐infrared region…”
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Spectroscopic and Theoretical Studies of Acid–Base Behaviors of N‑Confused Porphyrins: Effects of meso-Aryl Substituents
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-02-2015)“…The acid–base properties of a series of meso-aryl-substituted N-confused porphyrins (NCPs) were examined in aqueous sodium dodecyl sulfate (SDS) micellar…”
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2‑(Naphthalen-1-yl)thiophene as a New Motif for Porphyrinoids: Meso-Fused Carbaporphyrin
Published in Journal of the American Chemical Society (20-04-2016)“…The first synthesis of meso-fused carbaporphyrin via a premodification method was accomplished by substituting two pyrrole moieties and one meso-carbon with…”
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Heptacene: Synthesis and Its Hole‐Transfer Property in Stable Thin Films
Published in Chemistry : a European journal (21-07-2021)“…Heptacene (1) has been produced via a monoketone precursor, 2, which was prepared from 1,2,4,5‐tetrabromobenzene in nine steps in a total yield of 10 %…”
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