Search Results - "FUJDALA, Kyle L"
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Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters
Published in Journal of the American Chemical Society (30-03-2011)“…Kinetic, isotopic, and infrared studies on well-defined dispersed Pt clusters are combined here with first-principle theoretical methods on model cluster…”
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An Efficient, Single-Source Molecular Precursor to Silicoaluminophosphates
Published in Journal of the American Chemical Society (17-10-2001)Get full text
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Correction to Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters
Published in Journal of the American Chemical Society (11-01-2012)Get full text
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Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous Silica: A Detailed X-ray Absorption Spectroscopy Study
Published in The journal of physical chemistry. B (02-12-2004)“…A low-temperature grafting approach using two CuI molecular precursors ([CuOSi(O t Bu)3]4 and [CuO t Bu]4) and a high-temperature exchange reaction using CuCl…”
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Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor approach
Published in Journal of catalysis (15-05-2003)Get full text
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Atomic Level Control over Surface Species via a Molecular Precursor Approach: Isolated Cu(I) Sites and Cu Nanoparticles Supported on Mesoporous Silica
Published in Journal of the American Chemical Society (08-09-2004)“…A nonaqueous molecular precursor grafting approach was employed for the generation of well-defined surface structures featuring Cu on a mesoporous silica…”
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New Tris(tert-butoxy)siloxy Complexes of Aluminum and Their Transformation to Homogeneous Aluminosilicate Materials via Low-Temperature Thermolytic Pathways
Published in Chemistry of materials (18-02-2002)“…The new tris(tert-butoxy)siloxy complexes of aluminum, Al[OSi(O t Bu)3]3(THF) (1), Al[OSi(O t Bu)3]3(HO i Pr)·0.5[Al(O i Pr)3]4 (2), and [( i PrO)2AlOSi(O t…”
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New Vanadium Tris(tert-butoxy)siloxy Complexes and Their Thermolytic Conversions to Vanadia−Silica Materials
Published in Chemistry of materials (18-03-2002)“…The V(IV) alkoxysiloxy complexes ( t BuO)3VOSi(O t Bu)3 (1) and ( t BuO)2V[OSi(O t Bu)3]2 (2) were synthesized via the silanolysis of V(O t Bu)4 with 1 and 2…”
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Tris(tert-butoxy)siloxy Derivatives of Boron, Including the Boronous Acid HOB[OSi(O t Bu)3]2 and the Metal (Siloxy)boryloxide Complex Cp2Zr(Me)OB[OSi(O t Bu)3]2: A Remarkable Crystal Structure with 18 Independent Molecules in Its Asymmetric Unit
Published in Inorganic chemistry (24-02-2003)“…Silanolysis of B(O t Bu)3 with 2 and 3 equiv of HOSi(O t Bu)3 led to the formation of t BuOB[OSi(O t Bu)3]2 (1) and B[OSi(O t Bu)3]3 (2), respectively…”
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Thermolytic Transformation of Tris(alkoxy)siloxychromium(IV) Single-Source Molecular Precursors to Catalytic Chromia−Silica Materials
Published in Chemistry of materials (21-05-2001)“…Reactions of 1 and 2 equiv of HOSi(O t Bu)3 with Cr(O t Bu)4 afforded the first Cr(IV) alkoxysiloxy complexes ( t BuO)3CrOSi(O t Bu)3 (1) and ( t BuO)2Cr[OSi(O…”
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Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane
Published in Journal of catalysis (15-08-2003)“…Cothermolyses of ( t BuO) 3CrOSi(O t Bu) 3 ( 1) and either [Al(O t Bu) 3] 2 ( 2) or Zr[OCMe 2Et] 4 ( 3) as solutions in n-octane resulted in formation of gels…”
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Dimolybdenum(III) Complexes of −OSi(O t Bu)3, −O2P(O t Bu)2, and −OB[OSi(O t Bu)3]2 as Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials
Published in Chemistry of materials (23-03-2004)“…The following dimolybdenum complexes containing −OSi(O t Bu)3, −O2P(O t Bu)2, and −OB[OSi(O t Bu)3]2 ligands have been synthesized and structurally…”
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Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-κP]}-{[2,4,6-tri(tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]): Catalytic C−P Bond Formation via Intramolecular C−H/P−H Dehydrogenative Cross-Coupling
Published in Helvetica chimica acta (17-10-2001)“…The complex [Rh(η3‐benzyl)(dippe)] (1; dippe=bis(diisopropylphosphino)ethane=(ethane‐1,2‐diyl)bis[diisopropylphosphine]) reacted cleanly with Mes*PH2 (2;…”
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The addition of organometallic reagents to tetramesityldigermene
Published in Canadian journal of chemistry (01-11-2002)“…The thermolysis and photolysis of hexamesitylcyclotrigermane in the presence of ethylmagnesium bromide has been investigated. Under photochemical conditions,…”
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Dimolybdenum(III) complexes of -OSi(OtBu)3, -O2P(OtBu)2 and-OB[OSi(OtBu)3]2 as single-source molecular precursors tomolybdenum-containing, multicomponent oxide materials
Published in Chemistry of materials (15-01-2004)“…The following dimolybdenum complexes containing -OSi(O{sup t}Bu){sub 3}, -O{sub 2}P(O{sup t}Bu){sub 2}, and -OB[OSi(O{sup t}Bu){sub 3}]{sub 2} ligands have…”
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Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-10-2005)“…Two new transition metal complexes containing the –OB[OSi(OtBu)3]2 ligand, Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf), are reported. These species are the 4th and…”
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Synthesis and Characterization of Et 2 NM{OB[OSi(O t Bu) 3 ] 2 } 3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-10-2005)“…Abstract Two new transition metal complexes containing the –OB[OSi(O t Bu) 3 ] 2 ligand, Et 2 NM{OB[OSi(O t Bu) 3 ] 2 } 3 (M = Zr, Hf), are reported. These…”
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Thermolytic molecular precursor routes to Cr/Si/Al/O andCr/Si/Zr/O catalysts for the oxidative dehydrogenation anddehydrogenation of propane
Published in Journal of catalysis (29-10-2002)Get full text
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