Oxidative Metabolites of Lycopene and γ‑Carotene in Gac (Momordica cochinchinensis)

Three new oxidative metabolites of lycopenes, (erythro)-lycopene-5,6-diol, (threo)-lycopene-5,6-diol, and 1,16-dehydro-2,6-cyclolycopene-5-ol B, and four new oxidative metabolites of γ-carotenes, 2′,6′-cyclo-γ-carotene-1′,5′-diol A, 2′,6′-cyclo-γ-carotene-1′,5′-diol B, (erythro)-γ-carotene-5,6-diol,...

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Bibliographic Details
Published in:Journal of agricultural and food chemistry Vol. 63; no. 5; pp. 1622 - 1630
Main Authors: Maoka, Takashi, Yamano, Yumiko, Wada, Akimori, Etho, Tetsuji, Terada, Yukimasa, Tokuda, Harukuni, Nishino, Hoyoku
Format: Journal Article
Language:English
Published: United States American Chemical Society 11-02-2015
American Chemical Society, Books and Journals Division
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Summary:Three new oxidative metabolites of lycopenes, (erythro)-lycopene-5,6-diol, (threo)-lycopene-5,6-diol, and 1,16-dehydro-2,6-cyclolycopene-5-ol B, and four new oxidative metabolites of γ-carotenes, 2′,6′-cyclo-γ-carotene-1′,5′-diol A, 2′,6′-cyclo-γ-carotene-1′,5′-diol B, (erythro)-γ-carotene-5,6-diol, and (threo)-γ-carotene-5,6-diol, were isolated as minor components from the aril of gac, Momordica cochinchinensis . These structures were determined on the basis of spectroscopic data, and some of them were compared to the structures of synthetic samples. Furthermore, the oxidative metabolic conversion pathways of lycopene and γ-carotene were discussed.
Bibliography:http://dx.doi.org/10.1021/jf505008d
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0021-8561
1520-5118
DOI:10.1021/jf505008d