Search Results - "Estevan, F."
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High yield synthesis of trinuclear [M 3S 4X 3(diphos) 3] + (M=Mo, W; X=Cl, Br and diphos=dmpe, dppe) molecular clusters from solid state materials. Synthesis and structure of [W 3S 4H 3(dppe) 3](BPh 4)
Published in Polyhedron (30-03-2001)“…The excision of polymeric {M 3S 7X 4} x (M=Mo, W; X=Cl, Br) cluster phases with diphosphines (dmpe, dppe) in acetonitrile affords a one step general synthetic…”
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Rhodium (II) compounds with functionalized metalated phosphines as bridging ligands
Published in Journal of organometallic chemistry (10-10-2005)“…Two biscyclometalated compounds of formula Rh 2(O 2CCH 3) 2[PC] · [PC′] · 2CH 3CO 2H containing a mixed set of orthometalated phosphimes, P(4-BrC 6H 4) 2(C 6H…”
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Synthesis, Reactivity, and X-ray Crystallographic Characterization of Mono-, Di-, and Tetranuclear Palladium(II)-Metalated Species
Published in Inorganic chemistry (25-12-2000)“…The reactivity of the tetranuclear metallated palladium compound {Pd[μ2-(C6H4)PPh2]Br}4 (1) with different ligands has been investigated with the aim of…”
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Synthesis and Characterization of a New Ruthenium(II)-1, 2,4-Triazepine Complex
Published in Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry (01-06-2005)“…The reaction of [RuCl 2 (PPh 3 ) 3 ] complex with 2,7-dimethyl-3, 5-dithioxo-3, 4, 5, 6-tetrahydro-2H-1, 2, 4-triazepine (H 2 TAZS) provide the cis-[Ru(PPh 3 )…”
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Low-temperature Ti-containing 3:2 and 2:1 mullite nanocrystals from single-phase gels
Published in Journal of the European Ceramic Society (2007)“…TiO 2-containig single-phase gels with (Al 2O 3 + TiO 2)/(SiO 2) molar ratios 3/2 and 2/1 were prepared by gelling mixtures of aluminium nitrate,…”
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Chiral Dirhodium(II) Catalysts with Orthometalated Aryl Phosphine Ligands: Synthesis and Application for Enantioselective C−H Insertion of α-Diazo Ketones
Published in Organometallics (05-03-2001)“…Racemic dirhodium(II) complexes derived from orthometalated aryl phosphines, Rh2(O2CCH3)2(pc)2 (pc = orthometalated phosphine, with head-to-tail arrangement)…”
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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines
Published in Chemical communications (Cambridge, England) (07-11-2004)“…Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the…”
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Effect of thermal treatment on the structural evolution of 3:2 and 2:1 mullite monophasic gels
Published in Journal of non-crystalline solids (15-05-2005)“…Single phase mullite gels with composition 3Al 2O 3 · 2SiO 2 (3:2) and 2Al 2O 3 · SiO 2 (2:1) were prepared by the semialkoxide method using aluminum nitrate…”
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Stereoselective Synthesis and Catalytic Behavior of Rhodium(II) Compounds with Metalated Chiral Phospholanes as Ligands
Published in Organometallics (15-03-2004)“…The reaction of Rh2(O2CR)4 (R = CH3, CF3) with the chiral phosphine (2R,5R)-2,5-dimethyl-1-phenylphospholane (1) results in the formation of the mono-metalated…”
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Synthesis and structure of the incomplete cuboidal clusters [W3Se4H3(dmpe)3]+, [W3Se4H(3-x)(OH)x(dmpe)3]+ and [W3Se4(OH)3(dmpe)3]+, and the mechanism of the acid-assisted substitution of the coordinated hydrides
Published in Dalton transactions : an international journal of inorganic chemistry (21-02-2004)“…The novel incomplete cuboidal cluster [W3Se4H3(dmpe)3](PF6), [1](PF6), has been prepared by reduction of [W3Se4Br3(dmpe)3](PF6) with LiBH4 in THF solution. The…”
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New dinuclear catalysts Rh(2)(N-O)(2)[(C6H4)P(C6H5)2]2 with imidate ligands: synthesis and isomerization from head-to-tail to head-to-head configuration of the imidate ligands
Published in Inorganic chemistry (13-08-2001)“…Two new dirhodium(II) catalysts of general formula Rh(2)(N-O)(2)[(C(6)H(4))P(C(6)H(5))(2)](2) (N-O = C(4)H(4)NO(2)) are prepared, starting from…”
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New Dinuclear Catalysts Rh2(N−O)2[(C6H4)P(C6H5)2]2 with Imidate Ligands: Synthesis and Isomerization from Head-to-Tail to Head-to-Head Configuration of the Imidate Ligands
Published in Inorganic chemistry (13-08-2001)“…Two new dirhodium(II) catalysts of general formula Rh2(N−O)2[(C6H4)P(C6H5)2]2 (N−O = C4H4NO2) are prepared, starting from Rh2(O2CCH3)2(PC)2L2 [PC =…”
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Reactivity and Selectivity of Ortho-Metalated Rhodium(II) Complexes in C−H Insertion Reactions of α-Diazo Compounds
Published in Organometallics (03-08-1998)“…Regioselective intramolecular C−H insertion reactions of α-diazo β-keto esters and α-diazo ketones are mediated by Rh2[OOCR]4 - x [PC] x (x = 1, 2; PC =…”
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Zinc complexation to N-substituted sulfonamide ligands.: Preparation, properties and crystal structure of copper(II) doped {[Zn(sulfamethizolate) 2(py)]·H 2O}
Published in Inorganica Chimica Acta (30-01-2003)“…The single crystal structure and spectroscopic properties of the copper(II) doped {[Zn(sulfamethizolate) 2(py)]·H 2O} ∞ are reported. The complex is a polymer…”
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Ligand Effects on the Chemoselectivity of Ortho-Metalated Rhodium(II) Catalyzed α-Diazo Ketone Transformations
Published in Organometallics (04-03-1997)“…Rh2(OOCR)2(PC)2 complexes (PC = orthometalated phosphines, OOCR = carboxylates) with very polarizable ligands, such as aromatic rings directly joined to the…”
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Synthesis and X-ray Structure of Metalated Rhodium(II) Catalysts with a Chiral Phospholane
Published in European journal of inorganic chemistry (01-01-2001)“…The reaction of Rh2(O2CR)4 (R = CH3, CF3) with the chiral phosphane (2S,5S)‐2,5‐dimethyl‐1‐phenylphospholane (PC*H), results in the formation of two…”
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Synthesis, characterization and kinetics of the metallation of the intermediate compound [formula omitted] to produce compound [formula omitted] · (H 2O) from Rh(II) tetraacetate
Published in Inorganica Chimica Acta (01-08-1998)“…Photochemical irradiation of mixtures of [Rh 2(μ-O 2CCH 3) 4]·(HOCH 3) 2 and P(2-(CH 3O)C 6H 4)Ph 2 (POMe) in CH 2Cl 2 solution (1:1 molar ratio) yields…”
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Hepatic epithelioid angiomatosis in the absence of HIV infection
Published in Revista clínica espanõla (01-10-1991)Get more information
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Antihypertensive treatment and insulin resistance
Published in Anales de medicina interna (Madrid, Spain : 1984) (01-02-1991)Get more information
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