Search Results - "Es, Daan"
-
1
Accelerated weathering of furanoate polyesters: Effect of molecular weight, crystallinity, and time
Published in Journal of applied polymer science (05-08-2023)“…Films of poly(ethylene furanoate) (PEF) and poly(neopentyl furanoate) (PNF) of different molecular weights were artificially weathered in a Q‐SUN test chamber…”
Get full text
Journal Article -
2
Catalytic pyrolysis of recalcitrant, insoluble humin byproducts from C6 sugar biorefineries
Published in Journal of analytical and applied pyrolysis (01-01-2017)“…•Humin depolymerisation by catalytic pyrolysis is reported.•Catalyst sceening studies showed that H-ZSM-5 gives highest aromatic yield.•Total aromatics yield…”
Get full text
Journal Article -
3
Unexpected Susceptibility of Poly(ethylene furanoate) to UV Irradiation: A Warning Light for Furandicarboxylic Acid?
Published in ACS macro letters (21-12-2021)“…Poly(ethylene furanoate) (PEF) is widely advocated as a renewable alternative to the fossil-based polyester poly(ethylene terephthalate) (PET). Whereas the…”
Get full text
Journal Article -
4
Reaction Pathways for the Deoxygenation of Vegetable Oils and Related Model Compounds
Published in ChemSusChem (01-09-2013)“…Vegetable oil‐based feeds are regarded as an alternative source for the production of fuels and chemicals. Paraffins and olefins can be produced from these…”
Get full text
Journal Article -
5
Antimicrobial Efficacy of a Vegetable Oil Plasticizer in PVC Matrices
Published in Polymers (01-04-2024)“…The growing prevalence of bacterial and viral infections, highlighted by the recent COVID-19 pandemic, urgently calls for new antimicrobial strategies. To this…”
Get full text
Journal Article -
6
Synthesis of Furandicarboxylic Acid Esters From Nonfood Feedstocks Without Concomitant Levulinic Acid Formation
Published in ChemSusChem (10-04-2017)“…5‐Hydroxymethylfurfural (HMF) is a versatile intermediate in biomass conversion pathways. However, the notoriously unstable nature of HMF imposes challenges to…”
Get full text
Journal Article -
7
Poly(hydroxy urethane)s based on renewable diglycerol dicarbonate
Published in European polymer journal (01-09-2015)“…[Display omitted] •Novel poly(hydroxy urethane)s (PHU) were prepared based on diglycerol dicarbonate.•Fatty acid and isohexide-based diamines were incorporated…”
Get full text
Journal Article -
8
Comparison of Tungsten and Molybdenum Carbide Catalysts for the Hydrodeoxygenation of Oleic Acid
Published in ACS catalysis (06-12-2013)“…Group 6 (W, Mo) metal carbide catalysts are promising alternatives to hydrodesulfurization (NiMo, CoMo) catalysts and group 10 (Pd) type catalysts in the…”
Get full text
Journal Article -
9
A Facile Solid-Phase Route to Renewable Aromatic Chemicals from Biobased Furanics
Published in Angewandte Chemie (International ed.) (22-01-2016)“…Renewable aromatics can be conveniently synthesized from furanics by introducing an intermediate hydrogenation step in the Diels–Alder (DA) aromatization…”
Get full text
Journal Article -
10
Isohexide Dinitriles: A Versatile Family of Renewable Platform Chemicals
Published in ChemSusChem (24-08-2017)“…Building blocks of isohexides extended by one carbon atom at the 2‐ or 5‐positions are now synthetically accessible by a convenient, selective, base‐catalyzed…”
Get full text
Journal Article -
11
Fully Isohexide-Based Polyesters: Synthesis, Characterization, and Structure–Properties Relations
Published in Macromolecules (22-01-2013)“…Here we present a novel series of biobased polyesters solely based on renewable isohexide building blocks, synthesized via melt polymerization. The recently…”
Get full text
Journal Article -
12
Hydrothermal Deoxygenation of Triglycerides over Pd/C aided by In Situ Hydrogen Production from Glycerol Reforming
Published in ChemSusChem (01-04-2014)“…A one‐pot catalytic hydrolysis–deoxygenation reaction for the conversion of unsaturated triglycerides and free fatty acids to linear paraffins and olefins is…”
Get full text
Journal Article -
13
Semi-Aromatic Polyesters Based on a Carbohydrate-Derived Rigid Diol for Engineering Plastics
Published in ChemSusChem (01-01-2015)“…New carbohydrate‐based polyesters were prepared from isoidide‐2,5‐dimethanol (extended isoidide, XII) through melt polymerization with dimethyl esters of…”
Get full text
Journal Article -
14
Substituted Phthalic Anhydrides from Biobased Furanics: A New Approach to Renewable Aromatics
Published in ChemSusChem (21-09-2015)“…A novel route for the production of renewable aromatic chemicals, particularly substituted phthalic acid anhydrides, is presented. The classical two‐step…”
Get full text
Journal Article -
15
Selectivity Control in the Tandem Aromatization of Bio‐Based Furanics Catalyzed by Solid Acids and Palladium
Published in ChemSusChem (10-01-2017)“…Bio‐based furanics can be aromatized efficiently by sequential Diels–Alder (DA) addition and hydrogenation steps followed by tandem catalytic aromatization…”
Get full text
Journal Article -
16
Synthesis and Thermal Properties of Bio-Based Copolyesters from the Mixtures of 2,5- and 2,4-Furandicarboxylic Acid with Different Diols
Published in ACS sustainable chemistry & engineering (18-11-2019)“…Recent works highlighted how interesting are the properties of furan-based polyesters. Most of the attention has been focused on the homopolyester obtained…”
Get full text
Journal Article -
17
Novel, Fully Biobased Semicrystalline Polyamides
Published in Macromolecules (10-05-2011)“…Novel, semicrystalline polyamides and co(polyamides) were synthesized from biobased sebacic acid (SA), 2,5-diamino-2,5-dideoxy-1,4;3,6-dianhydroiditol…”
Get full text
Journal Article -
18
Semicrystalline Polyesters Based on a Novel Renewable Building Block
Published in Macromolecules (26-06-2012)“…Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of dramatically increasing the glass transition temperature…”
Get full text
Journal Article -
19
A stabilized glycomimetic conjugate vaccine inducing protective antibodies against Neisseria meningitidis serogroup A
Published in Nature communications (07-09-2020)“…Neisseria meningitidis serogroup A capsular polysaccharide (MenA CPS) consists of (1 → 6)-2-acetamido-2-deoxy-α-D-mannopyranosyl phosphate repeating units, O…”
Get full text
Journal Article -
20
High molecular weight poly(ethylene-2,5-furanoate); critical aspects in synthesis and mechanical property determination
Published in Journal of polymer science. Part A, Polymer chemistry (01-10-2013)“…ABSTRACT Furan‐2,5‐dicarboxylic acid (FDCA) is a widely advocated renewable substitute for terephthalic acid (TA). Preparation of high molecular weight FDCA…”
Get full text
Journal Article