Search Results - "Ernsting, Jan Meine"
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P‐N Bridged Dinuclear Rh‐METAMORPhos Complexes: NMR and Computational Studies
Published in European journal of inorganic chemistry (09-09-2018)“…Sulfonamido‐phosphoramidites are known to form six‐membered ring Rh‐P‐N‐Rh‐P‐N‐ dinuclear complexes. Apart from a single X‐ray structure, little is known about…”
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Reactions of [RhCl(diene)]2 with Bi- and Terdentate Nitrogen Ligands. X-ray Structures of Five-Coordinate Complexes
Published in Organometallics (07-01-1997)“…Reaction of [RhCl(diene)]2 (diene = 1,5-cyclooctadiene (COD) or bicyclo[2.2.1] hepta-2,5-diene (NBD)) with the N−N−N nitrogen ligands 2,6-(C(R1)N−R2)2C5H3N in…”
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Supercritical Carbon Dioxide as Solvent and Temporary Protecting Group for Rhodium-Catalyzed Hydroaminomethylation
Published in Chemistry : a European journal (05-11-2001)“…Supercritical carbon dioxide (scCO2) acts simultaneously as solvent and temporary protecting group during homogeneously rhodium‐catalyzed hydroaminomethylation…”
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(Bis(imino)aryl)rhodium(III) Halide and Methyl Compounds
Published in Organometallics (27-09-2004)“…The synthesis and X-ray crystal structure of a number of aryl−rhodium dihalide and aryl−rhodium methyl halide complexes [RhX2(NCN)] and [RhX(CH3)(NCN)] with…”
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CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN2S2 Metallodithiolate Ligand
Published in Organometallics (12-02-2007)“…Neutral ((Ni-1)Pd(CH3)(Cl)) and cationic ([(Ni-1)Pd(CH3)(OEt2)][BAr‘4]) complexes containing the strongly electron-donating metallodithiolate ligand Ni-1…”
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CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN 2 S 2 Metallodithiolate Ligand
Published in Organometallics (01-02-2007)Get full text
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Facile Synthesis of New, Stable, Palladium-Ethyl Derivatives Containing Nitrogen-Donor Ligands
Published in Organometallics (26-04-2004)“…A study of the insertion reaction of ethylene into the Pd−C bond on complexes of general formula [Pd(CH3)(N−N)2][OTf] and [Pd(CH3)(phen)(L)][OTf] led to the…”
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103 Rh NMR spectroscopy and its application to rhodium chemistry
Published in Magnetic resonance in chemistry (01-09-2004)“…Abstract Rhodium is used for a number of large processes that rely on homogeneous rhodium‐catalyzed reactions, for instance rhodium‐catalyzed hydroformylation…”
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New monocationic methylpalladium(II) compounds with several bidentate nitrogen-donor ligands: synthesis, characterisation and reactivity with CO
Published in Inorganica Chimica Acta (10-01-2002)“…Two series of methylpalladium(II) compounds with mono and bidentate nitrogen-donor ligands, namely [Pd(N-N) 2(CH 3)][X] (N-N=phen ( 1a), dm-phen ( 1b)…”
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103Rh NMR spectroscopy and its application to rhodium chemistry
Published in Magnetic resonance in chemistry (01-09-2004)“…Rhodium is used for a number of large processes that rely on homogeneous rhodium‐catalyzed reactions, for instance rhodium‐catalyzed hydroformylation of…”
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Steric and Electronic Effects on the103Rh NMR Chemical Shifts of RhI(cyclooctadiene) Compounds Bearing N-Donor Ligands
Published in European journal of inorganic chemistry (01-01-1999)Get full text
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Steric and Electronic Effects on the 103Rh NMR Chemical Shifts of RhI(cyclooctadiene) Compounds Bearing N-Donor Ligands
Published in European journal of inorganic chemistry (01-01-1999)“…In order to study electronic and steric effects on δ(103Rh), the103Rh‐NMR spectra of a series of [Rh(cod)L2] complexes (with L = nitrogen, oxygen, or chloride)…”
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1H, 31P and 195Pt NMR characterization, and X-ray molecular structures of five- and six-membered platinum(II) and palladium(II) metallacycles from the alcoholysis of di- and triazaphosphole complexes
Published in Inorganica Chimica Acta (15-11-1997)“…The 1,2,3-diazaphosphole P=C(H)C(Me)=NNMe (LA) (LA) and the 1,2,4,3-triazaphospholes P=NC(Ph)=NNMe (LB) (LB) and P=NN(Me)C(Me)=N (LC) (LC) form Pt(II) and…”
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Alkene rotation in [Ru( η5-C 5H 5) (L 2) ( η2-alkene][CF 3SO 3] with L 2 = iPr- or pTol-diazabutadiene. X-ray crystal structure of [Ru( η5-C 5H 5( pTol-DAB) ( η2-ethene][CF 3SO 3]
Published in Inorganica Chimica Acta (1995)“…Reaction of RuCl( η 5-C 5H 5( pTol-DAB) with AgOTf (OTf = CF 3SO 3) in CH 2Cl 2 or THF and subsequent addition of L′ (L′ = ethene ( a), dimethyl fumarate ( b),…”
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On the relation of the dynamic behavior between the two diastereomers of the linear tetranuclear ruthenium cluster Ru4(CO)10[CH3C=C(H)C(H)=N-i-Pr]2 and their isolobal counterparts [η5-CpM(CO)2]2 (M=Fe, Ru)
Published in Journal of the American Chemical Society (01-02-1993)Get full text
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Structural features of silver(I) and copper(I) bis(thiophene-2-carbaldehyde imine) trifluoromethanesulfonate complexes in the solid state and in solution: crystal structures of [Ag{Th-2-CH:N-(S)-CHMePh}2](O3SCF3) and [Cu{5-Me-Th-2-CH:N-iso-Pr}2](O3SCF3) and a proton, fluorine-19 and silver-109 NMR study
Published in Inorganic chemistry (01-03-1991)Get full text
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Pseudo-allyl complexes from monoazadienes and Co2(CO)8 by activation of dihydrogen under mild conditions
Published in Organometallics (01-11-1992)Get full text
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