Search Results - "Epps, Thomas H"
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Toward polymer upcycling—adding value and tackling circularity
Published in Science (American Association for the Advancement of Science) (02-07-2021)“…Plastics have revolutionized modern life, but have created a global waste crisis driven by our reliance and demand for low-cost, disposable materials. New…”
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Directed Block Copolymer Thin Film Self-Assembly: Emerging Trends in Nanopattern Fabrication
Published in Macromolecules (08-10-2013)“…Block copolymers have garnered significant attention in the past few decades due to their ability to self-assemble into nanoscale structures (∼10–100 nm),…”
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Block copolymers: controlling nanostructure to generate functional materials - synthesis, characterization, and engineering
Published in Chemical science (Cambridge) (01-03-2016)“…In this perspective, we survey recent advances in the synthesis and characterization of block copolymers, discuss several key materials opportunities enabled…”
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Biobased building blocks for the rational design of renewable block polymers
Published in Soft matter (01-01-2014)“…Block polymers (BPs) derived from biomass (biobased) are necessary components of a sustainable future that relies minimally on petroleum-based plastics for…”
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5
Block copolymer electrolytes for rechargeable lithium batteries
Published in Journal of polymer science. Part B, Polymer physics (01-01-2014)“…ABSTRACT Ion‐conducting block copolymers (BCPs) have attracted significant interest as conducting materials in solid‐state lithium batteries. BCP self‐assembly…”
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100th Anniversary of Macromolecular Science Viewpoint: Polymers from Lignocellulosic Biomass. Current Challenges and Future Opportunities
Published in ACS macro letters (21-04-2020)“…Sustainable polymers from lignocellulosic biomass have the potential to reduce the environmental impact of commercial plastics while also offering significant…”
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Ionic-Liquid-Mediated Deconstruction of Polymers for Advanced Recycling and Upcycling
Published in ACS macro letters (15-08-2023)“…Ionic liquids (ILs) are a promising medium to assist in the advanced (chemical and biological) recycling of polymers, owing to their tunable catalytic…”
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8
Stimuli-responsive copolymer solution and surface assemblies for biomedical applications
Published in Chemical Society reviews (07-09-2013)“…Stimuli-responsive polymeric materials is one of the fastest growing fields of the 21st century, with the annual number of papers published more than…”
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Block Copolymer Vitrimers
Published in Journal of the American Chemical Society (08-01-2020)“…In this report, we merge block copolymers with vitrimers in an effort to realize the prospect of higher-order, nanoscale control over associative cross-link…”
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From Tree to Tape: Direct Synthesis of Pressure Sensitive Adhesives from Depolymerized Raw Lignocellulosic Biomass
Published in ACS central science (27-06-2018)“…We report a new and robust strategy toward the development of high-performance pressure sensitive adhesives (PSAs) from chemicals directly obtained from raw…”
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Circularity in polymers: addressing performance and sustainability challenges using dynamic covalent chemistries
Published in Chemical science (Cambridge) (24-05-2023)“…The circularity of current and future polymeric materials is a major focus of fundamental and applied research, as undesirable end-of-life outcomes and waste…”
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Lignin-derivable alternatives to bisphenol A with potentially undetectable estrogenic activity and minimal developmental toxicity
Published in Food and chemical toxicology (01-08-2024)“…Lignin-derivable bisguaiacols/bissyringols are viable alternatives to commercial bisphenols; however, many bisguaiacols/bissyringols (e.g., bisguaiacol F…”
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13
Salt Doping in PEO-Containing Block Copolymers: Counterion and Concentration Effects
Published in Macromolecules (14-04-2009)“…The phase behavior of lithium salt-doped poly(styrene-b-ethylene oxide) (PS−PEO) was studied as a function of salt concentration, lithium (Li) counterion (X),…”
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Bent‐But‐Not‐Broken: Reactive Metal‐Organic Framework Composites from Elastomeric Phase‐Inverted Polymers
Published in Advanced functional materials (01-12-2020)“…A phase inversion process is used to fabricate composite beads from the metal–organic framework (MOF) UiO‐66‐NH2 and the elastomeric block copolymer…”
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15
Electrophoretic Deposition as a Versatile Low-Cost Tool to Construct a Synthetic Polymeric Solid-Electrolyte Interphase on Silicon Anodes: A Model System Investigation
Published in ACS applied materials & interfaces (14-02-2024)“…The cycling of next-generation, high-capacity silicon (Si) anodes capable of 3579 mAh·g–1 is greatly hindered by the instability of the solid-electrolyte…”
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Sustainability of Synthetic Plastics: Considerations in Materials Life-Cycle Management
Published in JACS Au (24-01-2022)“…The sustainability of current and future plastic materials is a major focus of basic research, industry, government, and society at large. There is a general…”
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Metal–organic framework polymer composite enhancement via acyl chloride modification
Published in Polymer international (01-06-2021)“…Ideal mixed‐matrix composites fabricated from metal–organic frameworks (MOFs) and polymers should exhibit good compatibility between components, high…”
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Synthesis and Characterization of Amphiphilic Cyclic Diblock Copolypeptoids from N-Heterocyclic Carbene-Mediated Zwitterionic Polymerization of N-Substituted N-Carboxyanhydride
Published in Macromolecules (27-12-2011)“…N-Heterocyclic carbene (NHC)-mediated ring-opening polymerization of N-decyl-N-carboxylanhydride monomer (De-NCA) has been shown to occur in a controlled…”
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Single pot catalyst strategy to branched products via adhesive isomerization and hydrocracking of polyethylene over platinum tungstated zirconia
Published in Applied catalysis. B, Environmental (15-12-2021)“…[Display omitted] •Pt-WZr is a prototypical catalyst to probe LDPE hydrocracking at low temperatures.•The metal-acid balance (MAB) is a crucial descriptor in…”
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Enhanced Conductivity via Homopolymer-Rich Pathways in Block Polymer-Blended Electrolytes
Published in Macromolecules (24-12-2019)“…The optimization of ionic conductivity and lithium-ion battery stability can be achieved by independently tuning the ion transport and mechanical robustness of…”
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