Search Results - "Enriquez, Lourdes"
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Molecular Rotation Spectrum of Tetracyclic Quinolizidines: Observation of trans -Matrine and the Elusive cis -Matrine
Published in Journal of organic chemistry (15-01-2021)“…We characterized the bis-quinolizidine tetracyclic alkaloid (5 , 6 , 7 , 11 )-matrine in a supersonic jet expansion, using chirped-pulsed broadband microwave…”
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2
Torsional chirality and molecular recognition: the homo and heterochiral dimers of thenyl and furfuryl alcohol
Published in Physical chemistry chemical physics : PCCP (13-04-2022)“…Furfuryl alcohol and thenyl alcohol contain a labile torsional chiral center, producing transiently chiral enantiomers interconverting in the nanosecond…”
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3
Sulfur Hydrogen Bonding in Isolated Monohydrates: Furfuryl Mercaptan versus Furfuryl Alcohol
Published in Chemistry : a European journal (02-05-2018)“…The hydrogen bonds involving sulfur in the furfuryl mercaptan monohydrate are compared with the interactions originating from the hydroxyl group in furfuryl…”
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4
Mimicking Halimane Synthases: Monitoring a Cascade of Cyclizations and Rearrangements from Epoxypolyprenes
Published in Journal of organic chemistry (01-11-2019)“…We have developed and rationalized a biomimetic transformation mimicking halimane synthases based on a Lewis acid-catalyzed cascade of cyclizations and…”
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5
Reduction of furfural by Mn/2,4,6‐Coll.HCl/H2O: Mechanistic aspects of this reaction
Published in Applied organometallic chemistry (01-07-2019)“…A simple, mild and safe reduction of furfural to furfuryl alcohol by the Mn/2,4,6‐Coll.HCl/H2O system is described. An experimental study on the role played by…”
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6
Parkinson disease and progressive supranuclear palsy: protein expression in skin
Published in Annals of clinical and translational neurology (01-03-2016)“…Objective This study characterizes the expression of tau (p‐tau) and α‐synuclein (α‐syn) by immunohistochemistry in the skin of three different populations:…”
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7
Rotational Spectrum, Tunneling Motions, and Intramolecular Potential Barriers in Benzyl Mercaptan
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (03-10-2019)“…The rotational spectrum of benzyl mercaptan (parent and four isotopologues) has been assigned in a supersonic jet expansion using chirped-pulse Fourier…”
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Hydrogen Bonding in the Dimer and Monohydrate of 2-Adamantanol: A Test Case for Dispersion-Corrected Density Functional Methods
Published in Molecules (Basel, Switzerland) (17-04-2022)“…Weakly-bound intermolecular clusters constitute reductionist physical models for non-covalent interactions. Here we report the observation of the monomer, the…”
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9
An Efficient Microkinetic Modeling Protocol: Start with Only the Dominant Mechanisms, Adjust All Parameters, and Build the Complete Model Incrementally
Published in ACS catalysis (07-06-2019)“…In a recent article (ACS Catal. 2018, 8, 11119–11133), a comprehensive catalytic mechanism is proposed to explain the effects of residual water on the…”
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10
A research capacity strengthening project for infectious diseases in Honduras: experience and lessons learned
Published in Global health action (01-01-2013)“…In Honduras, research capacity strengthening (RCS) has not received sufficient attention, but an increase in research competencies would enable local…”
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11
Rotational Spectroscopy and Conformational Flexibility of 2‐Phenylethanethiol: The Dominant S−H⋅⋅⋅π Intramolecular Hydrogen Bond
Published in Chemphyschem (01-03-2024)“…We present a rotational‐computational investigation of the aromatic mercaptan 2‐phenylethanethiol, addressing its potential energy surface, conformational…”
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12
Research capacity strengthening in Honduras
Published in The Lancet global health (01-08-2013)Get full text
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13
Tau Protein in Oral Mucosa and Cognitive State: A Cross-sectional Study
Published in Frontiers in neurology (13-10-2017)“…Neurodegenerative diseases are characterized by the presence of abnormal aggregates of proteins in brain tissue. Among them, the presence of aggregates of…”
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14
A Concise Route for the Synthesis of Tetracyclic Meroterpenoids: (±)-Aureol Preparation and Mechanistic Interpretation
Published in Marine drugs (26-08-2020)“…A new concise general methodology for the synthesis of different tetracyclic meroterpenoids is reported: (±)-aureol ( ), the key intermediate of this general…”
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15
Monitoring of Microbial Contamination of Groundwater in the Upper Choluteca River Basin, Honduras
Published in Water (Basel) (01-06-2023)“…Water can act as a vector for several microbes with significant pathogenic potential for both humans and animals. Waterborne infections are a critical public…”
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16
Understanding the color change of the solutions of Cp2TiCl upon addition of water
Published in Applied organometallic chemistry (01-02-2023)“…Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp2TiCl2) with manganese dust in dry THF produces a green solution that turns deep blue upon…”
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17
A DFT-Based Computational-Experimental Methodology for Synthetic Chemistry: Example of Application to the Catalytic Opening of Epoxides by Titanocene
Published in Journal of organic chemistry (07-04-2017)“…A novel DFT-based Reaction Kinetics (DFT-RK) simulation approach, employed in combination with real-time data from reaction monitoring instrumentation (like…”
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18
Newly diagnosed versus relapsed idiopathic thrombotic thrombocytopenic purpura: a comparison of presenting clinical characteristics and response to treatment
Published in Annals of hematology (01-10-2009)“…The remission rate with plasma exchange (PE) in thrombotic thrombocytopenic purpura (TTP) exceeds 80%, but the disease relapses in up to 20–30% of the cases…”
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19
Ti-Mediated Efficient Reductive Dehalogenation of Carbon-Halogen Bonds
Published in Asian journal of organic chemistry (01-08-2016)“…A mild and efficient methodology for the reductive dehalogenation of carbon–halogen bonds in both activated (allylic or benzylic) and non‐activated halides…”
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A 1.2 V, 130 nm CMOS parallel continuous-time Σ Δ ADC for OFDM UWB receivers
Published in Microelectronics (01-04-2012)Get full text
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