Search Results - "Elliott, Mark C."
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Regioselective synthesis of important chlorophenols in the presence of methylthioalkanes with remote SMe, OMe or OH substituents
Published in Journal of sulfur chemistry (02-11-2018)“…Various methylthio alcohols, methoxy(methylthio)alkanes and bis(methylthio)alkanes have been used as regioselectivity modifiers in the chlorination reactions…”
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Studies towards the total synthesis of lycoposerramine A. Synthesis of a model for the tetracyclic core
Published in Organic & biomolecular chemistry (01-01-2009)“…Lycoposerramine A (1) is a pentacyclic alkaloid isolated in 2001 by Takayama and co-workers. A concise synthesis of a model compound 8 for the tetracyclic core…”
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Diastereoselective alkylation reactions of 1-methylcyclohexa-2,5-diene-1-carboxylic acid
Published in Organic & biomolecular chemistry (21-05-2012)“…The deprotonation and alkylation of 1-methylcyclohexa-2,5-diene-1-carboxylic acid has been investigated under a range of conditions. In all cases, the…”
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4
Synthesis and stereochemical determination of batzelladine C methyl ester
Published in Organic & biomolecular chemistry (01-01-2009)“…Batzelladine C (3) is a tricyclic guanidine alkaloid of unknown stereochemistry at one centre as well as unknown absolute stereochemistry. The two possible…”
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(E)-2-(1,1-Di-cyclo-hexyl-3-phenyl-all-yl)-5,5-dimethyl-1,3,2-dioxaborinane
Published in Acta crystallographica. Section E, Structure reports online (01-09-2013)“…The crystal structure of the title compound, C26H39BO2, which contains no strong hydrogen bond donors, displays only long C-H⋯O contacts between…”
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The Limits of Tartary: Manchuria in Imperial and National Geographies
Published in The Journal of Asian studies (01-08-2000)“…This essay examines the transformation from undifferentiated frontier to geographic region of that part of northeast Asia controversially referred to as…”
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Migratory Aptitudes of Alkyl Groups on Boron: A Computational Study of Halomethyllithium-Induced Migration Reactions
Published in Organometallics (09-09-2013)“…For reactions of alkyldioxaborolanes with halomethyllithium reagents, migrations of tertiary alkyl groups and benzylic groups often give lower yields of…”
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3‑Chloro-1-lithiopropene, a Functional Organolithium Reagent, and Its Reactions with Alkylboronates To Give 3‑Alkylprop-1-en-3-ols
Published in Journal of organic chemistry (20-09-2013)“…The reagent 3-chloro-1-lithiopropene (4) can be generated by treating 1-bromo-3-chloropropene with t-BuLi. It is unstable but if generated at low temperature…”
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An efficient one-pot multicomponent approach to 5-amino-7-aryl-8-nitrothiazolo[3,2- a]pyridines
Published in Tetrahedron (09-12-2011)“…A series of thiazolo[3,2- a]pyridines have been prepared using a multicomponent reaction between aromatic aldehydes, 2-nitromethylenethiazolidine and nitriles…”
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Factors Affecting Migration of Tertiary Alkyl Groups in Reactions of Alkylboronic Esters with Bromomethyllithium
Published in Journal of organic chemistry (05-04-2013)“…The reactions of bromomethyllithium with tert-alkylboronic esters could be of great potential for the formation of quaternary carbon centers but often give…”
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Studies towards the total synthesis of batzelladine A
Published in Organic & biomolecular chemistry (21-07-2004)“…Application of a diastereoselective three-component coupling to the bicyclic core of the batzelladine alkaloids is described. The synthesis features the…”
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An unexpected Prins desymmetrisation reaction driven by silyl migration
Published in ARKIVOC (01-08-2012)Get full text
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Frederic Wakeman, Jr., 1937–2006
Published in The China quarterly (London) (01-03-2007)“…Frederic Wakeman Jr., pre-eminent historian of modern China and Haas Professor of Asian Studies emeritus at the University of California, Berkeley, died of…”
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Diastereospecific Tandem Prins Cyclisation/Rearrangement Reactions for the Desymmetrisation of Cyclohexa-1,4-dienes
Published in European Journal of Organic Chemistry (01-02-2007)“…The Prins cyclisation has been used for the first time to desymmetrise a 1,4‐diene. Products derived from both normal Prins and rearrangement pathways were…”
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Directed epoxidation of cyclohexa-1,4-dienes-stereoselective formation of up to six contiguous stereogenic centres
Published in Organic & biomolecular chemistry (01-01-2008)“…Epoxidation/cyclisation of cyclohexa-1,4-dienes containing pendant hydroxyl groups provides stereocontrolled access to highly-functionalised reduced…”
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Asymmetric hetero-Diels–Alder reactions. Reactions of oxazolo[3,2- c ]pyrimidines
Published in Tetrahedron (17-12-2001)Get full text
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Diastereoselective Dimerisation of Alkenylthiazolines: A Combined Synthetic and Computational Study
Published in European Journal of Organic Chemistry (01-09-2005)“…The acylative dimerisation of 2‐alkenyl‐1,3‐thiazolines 1 gives compounds 3 and 8 upon treatment with trichloroacetyl chloride and trifluoroacetic anhydride,…”
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A convenient synthesis of 2-methyl-3-oxoheptane-1,7-dicarboxylic esters and amides
Published in Tetrahedron letters (29-03-2004)“…Birch reduction followed by solvolysis provides two or three step access to the title compounds. A range of simple derivatives of…”
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Highly diastereoselective dimerisation of alkenylthiazolines
Published in Tetrahedron letters (16-07-2001)“…Alkenylthiazolines undergo a highly diastereoselective novel dimerisation when treated with trichloroacetyl chloride or with trifluoroacetic anhydride. Graphic…”
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