Search Results - "Elkhayat, Zobida"
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Exploring Modular Domino Reactions: Competing Processes Based on the Nature of the Angular Substituent
Published in Organic letters (08-11-2007)“…The octaline diol system 6 was found to undergo an interesting set of reactions upon treatment with PhI(OAc)2, leading, in a single synthetic operation, to…”
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Journal Article -
2
Synthesis of nor-sesquiterpene spirolactones and their steroidal hybrids revisited. The neopentyl dilemma: misassignment of one stereocentre may necessitate a completely new approach
Published in Tetrahedron: asymmetry (15-10-2014)“…Inversion at the highly congested C1 position of 1-epi-pathylactone A (1-epi-1), or its corresponding steroidal hybrid 8a, using a diverse range of published…”
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3
Diverging Pathways to Topologically Complex Polycyclic Bis-acetals and Their Ring System Interchange
Published in Organic letters (16-03-2012)“…Carbinol-tethered octalin-diols (1), which differ only by the C11 configuration at the angular position, were transformed selectively to three types of…”
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Journal Article -
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Competing Domino Processes: Path-Discriminating Ability of Epoxide Stereochemistry at the Angular Position
Published in Organic letters (20-08-2009)“…Structurally different products can be reached selectively from unsaturated vicinal bicyclic diols, which differ only by the epoxide configuration at the…”
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Journal Article -
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Microwave-Accelerated Competing Domino Processes: A Tether-Controlled Dual Pathway into High Molecular Complexity
Published in Organic letters (05-06-2008)“…Bicyclic unsaturated diols undergo a path selective modular domino transformation upon subjection to Pb(OAc)4, the reaction being biased to the nature of the…”
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Journal Article -
6
Efficient Construction of Highly Substituted and Stereodefined cis-Fused Lactones
Published in European Journal of Organic Chemistry (01-09-2010)“…The methodology described in this paper involves the epoxidation of cyclic ene‐acetals to spontaneously generate 6α‐hydroxy‐bis‐acetals that could serve as…”
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Book Review Journal Article -
7
Microwave‐Assisted Competing Domino Processes in the Octaline Diol Series
Published in European Journal of Organic Chemistry (01-06-2009)“…A Pb(OAc)4‐mediated, path selective, modular domino transformation using an octaline diol framework as a probe is described. Alteration of the nature of the…”
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Book Review Journal Article -
8
Pb(OAc) 4 mediated transannular oxidative ring cleavage
Published in Tetrahedron: asymmetry (2007)“…Pb(OAc) 4 oxidation of homoallylic alcohols at room temperature leads to the formation of a variety of fragmentation products, whose formation requires spatial…”
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Journal Article