Search Results - "Elemans, Johannes A.A.W"
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Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity
Published in Angewandte Chemie (International ed.) (21-09-2009)“…The invention of the scanning tunneling microscope has led to the visualization of molecules in real space on atomically flat conductive substrates. This has…”
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Water oxidation electrocatalysis using ruthenium coordination oligomers adsorbed on multiwalled carbon nanotubes
Published in Nature chemistry (01-11-2020)“…Photoelectrochemical cells that utilize water as a source of electrons are one of the most attractive solutions for the replacement of fossil fuels by clean…”
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3
A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water
Published in Angewandte Chemie International Edition (12-02-2016)“…Oxygen reduction and water oxidation are two key processes in fuel cell applications. The oxidation of water to dioxygen is a 4 H+/4 e− process, while oxygen…”
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4
The development of self-assembled liquid crystal display alignment layers
Published in Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences (15-06-2007)“…In this paper efforts to develop alignment layers (also called command layers) by processes other than rubbing, namely self-assembly of molecular and…”
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Host–Guest Exchange of Viologen Guests in Porphyrin Cage Compounds as Studied by Selective Exchange Spectroscopy (1D EXSY) NMR
Published in Angewandte Chemie International Edition (18-01-2021)“…Dynamics in complexes of porphyrin cage compounds and viologen‐derived guest molecules are investigated by selective exchange NMR spectroscopy (1D EXSY)…”
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6
Stabilization of thermally unstable photoisomers of pyridinium-functionalized hemithioindigo switches by host-guest complexation
Published in Tetrahedron (03-12-2021)“…Pyridine-functionalized hemithioindigo photoswitches (Z)-6-(Z)-8 were obtained by an aldol condensation of benzothiophenone 5 with the appropriate…”
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Processive Catalysis
Published in Angewandte Chemie International Edition (20-10-2014)“…Nature’s enzymes are an ongoing source of inspiration for scientists. The complex processes behind their selectivity and efficiency is slowly being unraveled,…”
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Self-Assembly of Covalently Linked Porphyrin Dimers at the Solid-Liquid Interface
Published in Molecules (Basel, Switzerland) (20-08-2019)“…The synthesis and surface self-assembly behavior of two types of metal-porphyrin dimers is described. The first dimer type consists of two porphyrins linked…”
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Tip-Induced Chemical Manipulation of Metal Porphyrins at a Liquid/Solid Interface
Published in Journal of the American Chemical Society (17-12-2014)“…Changing abruptly the potential between a scanning tunneling microscope tip and a graphite substrate induces “high-conductance” spots at the molecular level in…”
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10
Designing Processive Catalytic Systems. Threading Polymers through a Flexible Macrocycle Ring
Published in Journal of the American Chemical Society (25-06-2014)“…The translocation of polymers through pores is widely observed in nature and studying their mechanism may help understand the fundamental features of these…”
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Epitaxial Crystallization of Insulin on an Ordered 2D Polymer Template
Published in Chemistry : a European journal (12-03-2019)“…Two‐dimensional polymers (2DP) are a new class of materials that consist of a monolayer of ordered molecular building blocks, which have been covalently…”
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12
Macroscopic Hierarchical Surface Patterning of Porphyrin Trimers via Self-Assembly and Dewetting
Published in Science (American Association for the Advancement of Science) (01-12-2006)“…The use of bottom-up approaches to construct patterned surfaces for technological applications is appealing, but to date is applicable to only relatively small…”
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13
Aerobic Epoxidation of Low-Molecular-Weight and Polymeric Olefins by a Supramolecular Manganese Porphyrin Catalyst
Published in Catalysts (01-02-2019)“…We report on the highly efficient epoxidation of low-molecular-weight and polymeric olefins catalyzed by a supramolecular manganese porphyrin complex using…”
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14
Organothiol Monolayer Formation Directly on Muscovite Mica
Published in Angewandte Chemie (International ed.) (03-02-2020)“…Organothiol monolayers on metal substrates (Au, Ag, Cu) and their use in a wide variety of applications have been extensively studied. Here, the growth of…”
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Mechanism of Threading a Polymer Through a Macrocyclic Ring
Published in Science (American Association for the Advancement of Science) (12-12-2008)“…The translocation of biopolymers through pores and channels plays a fundamental role in numerous biological processes. We describe here the mechanism of the…”
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Slippage of a Porphyrin Macrocycle over Threads of Varying Bulkiness: Implications for the Mechanism of Threading Polymers through a Macrocyclic Ring
Published in Chemistry : a European journal (02-01-2015)“…Threading of a polymer through a macrocyclic ring may occur directly, that is, by finding the end of the polymer chain, or by a process in which the polymer…”
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Interlocked Porphyrin Switches
Published in Chemistry : a European journal (10-06-2013)“…We describe the synthesis of a series of interlocked structures from porphyrin–glycoluril cage compounds and bis(olefin)‐terminated viologens by an…”
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Nanostructuring of Self-Assembled Porphyrin Networks at a Solid/Liquid Interface: Local Manipulation under Global Control
Published in Chemphyschem (10-11-2014)“…Molecules of (5,10,15,20‐tetraundecylporphyrinato)‐copper(II) [(TUP)Cu] can self‐assemble into four different polymorphs at the interface between highly…”
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Strong Induced-Fit Binding of Viologen and Pyridine Derivatives in Adjustable Porphyrin Cavities
Published in Chemistry : a European journal (01-09-2014)“…The synthesis and binding properties of new porphyrin cage compounds consisting of a rigid diphenylglycoluril part, which is connected via flexible…”
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Processive enzyme mimic: Kinetics and thermodynamics of the threading and sliding process
Published in Proceedings of the National Academy of Sciences - PNAS (26-12-2006)“…The kinetics and thermodynamics of the treading and dethreading process of polymers through the cavity of a synthetic toroidal host is investigated by studying…”
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