Search Results - "Ekanayake, Danushka M."

Diverse Coordination Geometries Derived from Trisaminocyclohexane Ligands with Appended Outer‐Sphere Hydrogen Bond Donors by Ekanayake, Danushka M., Sheridan, Patrick E., Lindeman, Sergey V., Fiedler, Adam T.

“…With the aim of constructing hydrogen‐bonding networks in synthetic complexes, two new ligands derived from cis,cis ‐1,3,5‐triaminocyclohexane (TACH) have been…”
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Spectroscopic and Computational Comparisons of Thiolate-Ligated Ferric Nonheme Complexes to Cysteine Dioxygenase: Second-Sphere Effects on Substrate (Analogue) Positioning by Fischer, Anne A, Miller, Joshua R, Jodts, Richard J, Ekanayake, Danushka M, Lindeman, Sergey V, Brunold, Thomas C, Fiedler, Adam T

“…Parallel spectroscopic and computational studies of iron­(III) cysteine dioxygenase (CDO) and synthetic models are presented. The synthetic complexes utilize…”
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Electronic structures and spectroscopic signatures of diiron intermediates generated by O 2 activation of nonheme iron(II)-thiolate complexes by Ekanayake, Danushka M, Pham, Dao, Probst, Andrew L, Miller, Joshua R, Popescu, Codrina V, Fiedler, Adam T

“…The activation of O at thiolate-ligated iron(II) sites is essential to the function of numerous metalloenzymes and synthetic catalysts. Iron-thiolate bonds in…”
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Nonheme iron-thiolate complexes as structural models of sulfoxide synthase active sites by Ekanayake, Danushka M, Fischer, Anne A, Elwood, Maya E, Guzek, Alexandra M, Lindeman, Sergey V, Popescu, Codrina V, Fiedler, Adam T

“…Two mononuclear iron(ii)-thiolate complexes have been prepared that represent structural models of the nonheme iron enzymes EgtB and OvoA, which catalyze the…”
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Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties by Wang, Denan, Ekanayake, Danushka M., Lindeman, Sergey V., Verani, Cláudio N., Fiedler, Adam T.

“…A new redox‐active, diarylamido‐based ligand (LN3P2) capable of κ5‐N,N,N,P,P chelation has been used to prepare a series of complexes with the general formula…”
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Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N 3 P 2 Ligand: Synthesis, Characterization, and Catalytic Properties by Wang, Denan, Ekanayake, Danushka M., Lindeman, Sergey V., Verani, Cláudio N., Fiedler, Adam T.

“…A new redox‐active, diarylamido‐based ligand ( L N3P2 ) capable of κ 5 ‐ N , N , N,P,P chelation has been used to prepare a series of complexes with the…”
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Insights and Challenges in the Development of Molecular Copper-based Electrocatalysts for Water Reduction by Ekanayake, Danushka M

“…The development of molecular electro/photocatalysts for water splitting is a promising method for hydrogen-based energy production. We focus on understanding…”
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