Search Results - "Eaton, Philip E"

The Bent Bonds of Cubane by Doedens, Robert J., Eaton, Philip E., Fleischer, Everly B.

“…The carbon–carbon bonding in cubane is shown not to be along the C–C vectors between carbon atoms at the corners of a cube. Instead, the bonding is “bent” as…”
Get full text

Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 6. On the Selective Hydroxylation of Cubane by Annese, Cosimo, D’Accolti, Lucia, Fusco, Caterina, Gandolfi, Remo, Eaton, Philip E, Curci, Ruggero

“…By using methyl(trifluoromethyl)dioxirane (TFDO), the direct mono- and bishydroxylation of cubane could be achieved in high yield under remarkably mild…”
Get full text

9‐Azahomocubane by Fahrenhorst‐Jones, Tyler, Marshall, David L., Burns, Jed M., Pierens, Gregory K., Van Meurs, Derek P., Kong, Dehui, Bernhardt, Paul V., Blanksby, Stephen J., Savage, G. Paul, Eaton, Philip E., Williams, Craig M.

“…Homocubane, a highly strained cage hydrocarbon, contains two very different positions for the introduction of a nitrogen atom into the skeleton, e. g., a…”
Get full text

1-Azahomocubane by Fahrenhorst-Jones, Tyler, Marshall, David L, Burns, Jed. M, Pierens, Gregory K, Hormann, Robert E, Fisher, Allison M, Bernhardt, Paul V, Blanksby, Stephen J, Savage, G. Paul, Eaton, Philip E, Williams, Craig M

“…Highly strained cage hydrocarbons have long stood as fundamental molecules to explore the limits of chemical stability and reactivity, probe physical…”
Get full text

LiCB11Me12:  A Catalyst for Pericyclic Rearrangements by Moss, Stefan, King, Benjamin T, de Meijere, Armin, Kozhushkov, Sergei I, Eaton, Philip E, Michl, Josef

“…Benzene and 1,2-dichloroethane solutions of the Li+ salt of the weakly coordinating anion CB11Me12 - catalyze the rearrangement of cubane to cuneane,…”
Get full text

A Computational Study of the Interactions among the Nitro Groups in Octanitrocubane by Hrovat, David A, Borden, Weston Thatcher, Eaton, Philip E, Kahr, Bart

“…Ab initio molecular orbital and density functional calculations on isodesmic disproportionation reactions of nitrated cubanes indicate that the repulsion…”
Get full text

Systematic substitution on the cubane nucleus. Synthesis and properties of 1,3,5-trinitrocubane and 1,3,5,7-tetranitrocubane by Eaton, Philip E, Xiong, Yusheng, Gilardi, Richard

Get full text

Dimerization of Cubene. 1-Iodoadamantane as a Probe for Radical Intermediates by Lukin, Kirill, Eaton, Philip E

Get full text

BuMgNiPr2: A New Base for Stoichiometric, Position-Selective Deprotonation of Cyclopropane Carboxamides and Other Weak CH Acids by Zhang, Mao-Xi, Eaton, Philip E.

“…Using the irreversible formation of an alkane, the proton‐removing ability of a magnesiated amine, and the activating effect of a carboxamido group, weakly…”
Get full text

The preparation and fate of cubylcarbinyl radicals by Eaton, Philip E, Yip, Yu Chi

Get full text

Octanitrocubane: A New Nitrocarbon by Eaton, Philip E., Zhang, Mao-Xi, Gilardi, Richard, Gelber, Nat, Iyer, Sury, Surapaneni, Rao

“…Octanitrocubane, the first new nitrocarbon in 18 years, is introduced as a potential explosive of great power. Its synthesis and characterization are described…”
Get full text

Picosecond radical kinetics. Bond cleavage of the cubylcarbinyl radical by Choi, Seung Yong, Eaton, Philip E, Newcomb, Martin, Yip, Yu Chi

Get full text

Synthesis and Chemistry of 1,3,5,7-Tetranitrocubane Including Measurement of Its Acidity, Formation of o-Nitro Anions, and the First Preparations of Pentanitrocubane and Hexanitrocubane1 by Lukin, Kirill A, Li, Jianchang, Eaton, Philip E, Kanomata, Nobuhiro, Hain, Jürgen, Punzalan, Eric, Gilardi, Richard

“…Nitro groups on alternate corners of cubane enhance the acidity of cubyl hydrogen (pK a ∼21) and provide sufficient activation for ready anion formation. The…”
Get full text

Bond lengths and quadratic force field for cubane by Hedberg, Lise, Hedberg, Kenneth, Eaton, Philip E, Nodari, Nereo, Robiette, Alan G

Get full text

Synthesis of alkynylcyclooctatetraenes and alkynylcubanes by Eaton, Philip E, Stossel, Daniel

Get full text

Cationic Species Can Be Produced in Soluble Methane Monooxygenase-Catalyzed Hydroxylation Reactions; Radical Intermediates Are Not Formed by Choi, Seung-Yong, Eaton, Philip E, Kopp, Daniel A, Lippard, Stephen J, Newcomb, Martin, Shen, Runnan

Get full text

Systematic substitution on the cubane nucleus: steric and electronic effects by Eaton, Philip E, Xiong, Yusheng, Zhou, Jian Ping

Get full text

Automerization of homocubylidene: proof of a reversible olefin/carbene rearrangement by Eaton, Philip E, Appell, Robert B

Get full text

Nitration of Organolithiums and Grignards with Dinitrogen Tetroxide:  Success at Melting Interfaces by Tani, Keita, Lukin, Kirill, Eaton, Philip E

Get full text

Alkynylcubanes as Precursors of Rigid-Rod Molecules and Alkynylcyclooctatetraenes by Eaton, Philip E, Galoppini, Elena, Gilardi, Richard

Get full text