Search Results - "Dyar, Scott M."
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Singlet Exciton Fission in Polycrystalline Thin Films of a Slip-Stacked Perylenediimide
Published in Journal of the American Chemical Society (02-10-2013)“…The crystal structure of N,N-bis(n-octyl)-2,5,8,11-tetraphenylperylene-3,4:9,10-bis(dicarboximide), 1, obtained by X-ray diffraction reveals that 1 has a…”
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2
Triplet State Formation in Photoexcited Slip-Stacked Perylene-3,4:9,10-bis(dicarboximide) Dimers on a Xanthene Scaffold
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-10-2013)“…Two covalent perylene-3,4:9,10-bis(dicarboximide) (PDI) dimers in which the PDI molecules are attached to a xanthene (Xan) scaffold in which the long axes of…”
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3
Relative Unidirectional Translation in an Artificial Molecular Assembly Fueled by Light
Published in Journal of the American Chemical Society (11-12-2013)“…Motor molecules present in nature convert energy inputs, such as a chemical fuel or incident photons of light, into directed motion and force biochemical…”
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4
Redox Control of the Binding Modes of an Organic Receptor
Published in Journal of the American Chemical Society (02-09-2015)“…The modulation of noncovalent bonding interactions by redox processes is a central theme in the fundamental understanding of biological systems as well as…”
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5
Enhanced Photochemical Hydrogen Evolution from Fe4S4‑Based Biomimetic Chalcogels Containing M2+ (M = Pt, Zn, Co, Ni, Sn) Centers
Published in Journal of the American Chemical Society (24-09-2014)“…Naturally abundant enzymes often feature active sites comprising transition metal cluster units that catalyze chemical processes and reduce small molecules as…”
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6
Long-lived charge carrier generation in ordered films of a covalent perylenediimide-diketopyrrolopyrrole-perylenediimide molecule
Published in Chemical science (Cambridge) (01-01-2015)“…The photophysics of a covalently linked perylenediimide-diketopyrrolopyrrole-perylenediimide acceptor-donor-acceptor molecule (PDI-DPP-PDI, ) were investigated…”
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7
Photodriven Charge Separation and Transport in Self-Assembled Zinc Tetrabenzotetraphenylporphyrin and Perylenediimide Charge Conduits
Published in Angewandte Chemie International Edition (24-03-2014)“…Zinc tetrabenzotetraphenyl porphyrin (ZnTBTPP) covalently attached to four perylenediimide (PDI) acceptors self‐assembles into a π‐stacked, segregated columnar…”
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8
Spin-Selective Charge Recombination in Complexes of CdS Quantum Dots and Organic Hole Acceptors
Published in Journal of the American Chemical Society (15-10-2014)“…This paper describes the mechanisms of charge recombination on both the nanosecond and microsecond time scales in a donor–acceptor system comprising…”
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9
Electron Spin Polarization Transfer from Photogenerated Spin-Correlated Radical Pairs to a Stable Radical Observer Spin
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (27-06-2013)“…A series of donor–chromophore–acceptor–stable radical (D–C–A–R•) molecules having well-defined molecular structures were synthesized to study the factors…”
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10
Electron Transfer and Multi-Electron Accumulation in ExBox4
Published in Angewandte Chemie International Edition (19-05-2014)“…Molecules capable of accepting and storing multiple electrons are crucial components of artificial photosynthetic systems designed to drive catalysts, such as…”
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11
Mechanical Bonds and Topological Effects in Radical Dimer Stabilization
Published in Journal of the American Chemical Society (06-08-2014)“…While mechanical bonding stabilizes tetrathiafulvalene (TTF) radical dimers, the question arises: what role does topology play in catenanes containing TTF…”
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12
Photoinduced Charge and Energy Transfer within meta- and para-Linked Chlorophyll a‑Perylene-3,4:9,10-bis(dicarboximide) Donor–Acceptor Dyads
Published in The journal of physical chemistry. B (04-02-2016)“…Connecting electron donors and acceptors to a benzene ring in a meta or para relationship results in quantum interference effects that can strongly influence…”
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13
Mechanically induced intramolecular electron transfer in a mixed-valence molecular shuttle
Published in Proceedings of the National Academy of Sciences - PNAS (17-07-2012)“…The kinetics and thermodynamics of intramolecular electron transfer (IET) can be subjected to redox control in a bistable [2]rotaxane comprised of a dumbbell…”
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14
Tetrathiafulvalene Hetero Radical Cation Dimerization in a Redox-Active [2]Catenane
Published in Journal of the American Chemical Society (21-11-2012)“…The electronic properties of tetrathiafulvalene (TTF) can be tuned by attaching electron-donating or electron-withdrawing substituents. An electron-rich…”
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15
Photoinduced Electron Transfer within a Zinc Porphyrin-Cyclobis(paraquat-p-phenylene) Donor-Acceptor Dyad
Published in Chemistry : a European journal (03-11-2014)“…Understanding the mechanism of efficient photoinduced electron‐transfer processes is essential for developing molecular systems for artificial photosynthesis…”
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16
Energy Flow Dynamics within Cofacial and Slip-Stacked Perylene-3,4-dicarboximide Dimer Models of π‑Aggregates
Published in Journal of the American Chemical Society (22-10-2014)“…Robust perylene-3,4-dicarboximide (PMI) π-aggregates provide important light-harvesting and electron–hole pair generation advantages in organic photovoltaics…”
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17
Modification of the Optoelectronic Properties of Membranes via Insertion of Amphiphilic Phenylenevinylene Oligoelectrolytes
Published in Journal of the American Chemical Society (28-07-2010)“…We report on the modification of membranes by incorporation of phenylenevinylene oligoelectrolytes with the goal of tailoring their optical and electronic…”
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18
Photogenerated Quartet State Formation in a Compact Ring-Fused Perylene-Nitroxide
Published in The journal of physical chemistry. B (29-10-2015)“…We report on a novel small organic molecule comprising a perylene chromophore fused to a six-membered ring containing a persistent nitroxide radical to give a…”
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19
A Radically Configurable Six-State Compound
Published in Science (American Association for the Advancement of Science) (25-01-2013)“…Most organic radicals possess short lifetimes and quickly undergo dimerization or oxidation. Here, we report on the synthesis by radical templation of a class…”
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20
Mixed-Valence Superstructure Assembled from a Mixed-Valence Host–Guest Complex
Published in Journal of the American Chemical Society (01-08-2018)“…Herein, we report an unprecedented mixed-valence crystal superstructure that consists of a 2:1 host–guest complex [MV⊂(CBPQT)2]2/3+ [MV = methyl viologen,…”
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