Search Results - "Duan, Xin"
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1
Alkylative Dearomatization by Using an Unactivated Aryl Nitro Group as a Leaving Group: Access to Diversified Alkylated Spiro[5.5]trienones
Published in Organic letters (02-04-2021)“…The cleavage of an unactivated aryl nitro group triggered by alkyl radicals enables a dearomative cyclization, affording diversified alkylated…”
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2
Boosting Production of HCOOH from CO2 Electroreduction via Bi/CeOx
Published in Angewandte Chemie International Edition (12-04-2021)“…Formic acid (HCOOH) is one of the most promising chemical fuels that can be produced through CO2 electroreduction. However, most of the catalysts for CO2…”
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3
Iron-Catalyzed Dearomatization of Biaryl Ynones with Aldehydes via Double C–H Functionalization in Eco-Benign Solvents: Highly Atom-Economical Synthesis of Acylated Spiro[5.5]trienones
Published in Journal of organic chemistry (05-11-2021)“…The multiple C–H bonds of biaryl ynones render the 6-exo-trig regioselective C–H activation dearomatization to spiro[5.5]trienones challenging since the…”
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4
LDHA-mediated ROS generation in chondrocytes is a potential therapeutic target for osteoarthritis
Published in Nature communications (09-07-2020)“…The contribution of inflammation to the chronic joint disease osteoarthritis (OA) is unclear, and this lack of clarity is detrimental to efforts to identify…”
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5
Direct C–H Cyanoalkylation of Quinoxalin-2(1H)‑ones via Radical C–C Bond Cleavage
Published in Organic letters (16-02-2018)“…An efficient synthesis of cyanoalkylated heteroarenes via iron-catalyzed direct C–H cyanoalkylation of heteroarenes has been developed. Structurally diverse…”
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6
Predicting treatment response from longitudinal images using multi-task deep learning
Published in Nature communications (25-03-2021)“…Radiographic imaging is routinely used to evaluate treatment response in solid tumors. Current imaging response metrics do not reliably predict the underlying…”
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7
Amorphizing of Cu Nanoparticles toward Highly Efficient and Robust Electrocatalyst for CO2 Reduction to Liquid Fuels with High Faradaic Efficiencies
Published in Advanced materials (Weinheim) (05-04-2018)“…Conversion of carbon dioxide (CO2) into valuable chemicals, especially liquid fuels, through electrochemical reduction driven by sustainable energy sources, is…”
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8
Iron‐Catalyzed Ring‐Opening/Allylation of Cyclobutanone Oxime Esters with Allylic Sulfones
Published in Advanced synthesis & catalysis (02-05-2018)“…An iron‐catalyzed radical allylation of cyclobutanone oxime esters with allylic sulfones via C−C bond cleavage is reported. This protocol provides a…”
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9
Copper-Catalyzed Oxidative Benzylarylation of Acrylamides by Benzylic CH Bond Functionalization for the Synthesis of Oxindoles
Published in Chemistry : a European journal (23-09-2013)“…Radically changing benzyls: An efficient method for the benzylarylation of activated alkenes has been developed through a copper‐catalyzed tandem radical…”
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10
Direct C–H Cyanoalkylation of Heteroaromatic N‑Oxides and Quinones via C–C Bond Cleavage of Cyclobutanone Oximes
Published in Organic letters (03-11-2017)“…A direct C–H cyanoalkylation of heteroaromatic N-oxides and quinones with cyclobutanone oximes is reported. This redox-neutral, operationally simple…”
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11
Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media
Published in Advanced synthesis & catalysis (12-08-2013)“…A mild and efficient silver‐catalyzed acylarylation of activated alkenes with easily available α‐oxocarboxylic acids has been developed. The reactions provide…”
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12
Synthesis of Axially Chiral Biaryls via Enantioselective Ullmann Coupling of ortho‐Chlorinated Aryl Aldehydes Enabled by a Chiral 2,2′‐Bipyridine Ligand
Published in Angewandte Chemie International Edition (21-11-2022)“…The first nickel‐catalyzed highly enantioselective reductive Ullmann coupling of ortho‐chlorinated aryl aldehyde was achieved under mild reaction conditions…”
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13
Decarboxylative Acylation of Cyclic Enamides with α‑Oxocarboxylic Acids by Palladium-Catalyzed C–H Activation at Room Temperature
Published in Organic letters (07-09-2012)“…An efficient catalytic decarboxylative acylation of unactivated sp2 (alkenyl) C–H bonds has been developed. Various substituted α-oxocarboxylic acids with…”
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14
Decarboxylative Alkynylation of α‑Keto Acids and Oxamic Acids in Aqueous Media
Published in Organic letters (19-06-2015)“…A mild K2S2O8 promoted decarboxylative alkynylation of α-keto acids and oxamic acids has been developed. This process features mild reaction conditions, a…”
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15
Visible-Light Photoredox-Catalyzed Divergent 1,2-Diacylation and Hydroacylation of Alkenes with Carboxylic Acid Anhydride
Published in Organic letters (21-07-2023)“…A photoredox-catalyzed divergent 1,2-dicarbonylation and hydroacylation of alkenes with acid anhydride is presented. This approach offers a mild and efficient…”
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16
Iron-Catalyzed Decarboxylative Olefination of Cycloketone Oxime Esters with α,β-Unsaturated Carboxylic Acids via C–C Bond Cleavage
Published in Organic letters (03-08-2018)“…An iron-catalyzed redox-neutral, decarboxylative olefination of cycloketone oxime esters with α,β-unsaturated carboxylic acids has been developed. This…”
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17
Subtype-Specific Regeneration of Retinal Ganglion Cells following Axotomy: Effects of Osteopontin and mTOR Signaling
Published in Neuron (Cambridge, Mass.) (18-03-2015)“…In mammals, few retinal ganglion cells (RGCs) survive following axotomy, and even fewer regenerate axons. This could reflect differential extrinsic influences…”
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18
Transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters
Published in Chemical science (Cambridge) (2019)“…An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B (OH) reagent not only…”
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19
Transition-Metal-Free Tandem Radical Thiocyanooxygenation of Olefinic Amides: A New Route to SCN-Containing Heterocycles
Published in Organic letters (17-04-2015)“…A novel transition-metal-free tandem radical thiocyanooxygenation of olefinic amides with potassium thiocyanate has been developed under mild conditions. This…”
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20
Photoredox-Catalyzed Acylchlorination of α‑CF3 Alkenes with Acyl Chloride and Application as Masked Access to β‑CF3‑enones
Published in Organic letters (05-04-2024)“…We disclose a photocatalytic strategy that simultaneously addresses the construction of trifluoromethylated quaternary carbon centers and the preparation of…”
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