Search Results - "Dossmann, Héloïse"
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Iron Catalyzed Dearomatization of Pyridines into Annelated Azepine Derivatives in a One-Step, Three-Component Reaction
Published in Organic letters (13-01-2023)“…Commercially available Fe(TTP)Cl catalyzes three-component dearomative formal cycloaddition reactions between pyridines, diazo compounds, and coumalates…”
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2
Exploring Phosphine Electronic Effects on Molybdenum Complexes: A Combined Photoelectron Spectroscopy and Energy Decomposition Analysis Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (22-10-2020)“…In organometallic chemistry, especially in the catalysis area, accessing the finest tuning of a catalytic reaction pathway requires a detailed knowledge of the…”
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3
First Steps to Rationalize Host–Guest Interaction between α‑, β‑, and γ‑Cyclodextrin and Divalent First-Row Transition and Post-transition Metals (Subgroups VIIB, VIIIB, and IIB)
Published in Inorganic chemistry (18-01-2021)“…Cyclodextrins (CDs) are cyclic oligosaccharides mainly composed of six, seven, and eight glucose units, so-called α-, β-, and γ-CDs, respectively. They own a…”
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4
Photosensitized oxidative addition to gold(i) enables alkynylative cyclization of o-alkylnylphenols with iodoalkynes
Published in Nature chemistry (01-09-2019)“…The well-established oxidative addition–reductive elimination pathway is the most followed one in transition metal-catalysed cross-coupling reactions. While…”
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5
Bond-Dissociation Energies to Probe Pyridine Electronic Effects on Organogold(III) Complexes: From Methodological Developments to Application in π‑Backdonation Investigation and Catalysis
Published in Inorganic chemistry (21-08-2023)“…In this work, we report on the synthesis of several organogold(III) complexes based on 4,4′-diterbutylbiphenyl (C^C) and 2,6-bis(4-terbutylphenyl)pyridine…”
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Formation of 3‑Alkynylidenephthalides by Gold(I)-Catalyzed Alkynylative Cyclization of o‑Alkynylbenzoic Acids under Visible Light Irradiation
Published in Journal of organic chemistry (15-11-2024)“…Herein, we report a Csp2–Csp cross-coupling process involving the merger of gold catalysis and visible light photocatalysis leading to the alkynylative…”
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A Bis‐Chelating ONO^ /NN^ Ligand for the Synthesis of Heterobimetallic Platinum(II)/Rhenium(I) Complexes: Tools for the Optimization of a New Class of Platinum(II) Anticancer Agents
Published in Chemistry : a European journal (06-10-2020)“…The two independent and NN^ coordination sites of a newly synthesized bis[2‐(hydroxyphenyl)‐1,2,4‐triazole] platform have been exploited to prepare four…”
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8
Identifying and Understanding Strong Vibronic Interaction Effects Observed in the Asymmetry of Chiral Molecule Photoelectron Angular Distributions
Published in Chemphyschem (03-03-2017)“…Electron–ion coincidence imaging is used to study chiral asymmetry in the angular distribution of electrons emitted from randomly‐oriented enantiomers of two…”
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Ligand effects in gold-carbonyl complexes: Evaluation of the bond dissociation energies using blackbody infrared radiative dissociation
Published in International journal of mass spectrometry (01-05-2021)“…In a previous work, the ability of gold-carbonyl bond dissociation energies (BDEs) to describe ligand effects in gold(I) complexes was probed using…”
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10
Formation and Characterization of Gaseous Adducts of Carbon Dioxide to Magnesium, (CO2)MgX− (X=OH, Cl, Br)
Published in Angewandte Chemie International Edition (09-07-2012)“…A good fix: The structure and chemical reactivity of a reduced form of CO2 bonded to magnesium, XMg(η2‐O2C)−, is reported. Upon reaction with water it loses…”
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11
Spectroscopy and Photodissociation of the Perfluorooctanoate Anion
Published in Chemistry : a European journal (17-10-2018)“…Perfluorocarbons, a class of fully fluorinated compounds, are highly persistent and toxic pollutants that are receiving increasing attention due to their…”
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12
[(C C)Au(N N)]+ Complexes as a New Family of Anticancer Candidates: Synthesis, Characterization and Exploration of the Antiproliferative Properties
Published in Chemistry : a European journal (11-11-2021)“…A library of eleven cationic gold(III) complexes of the general formula [(C C)Au(N N)]+ when C C is either biphenyl or 4,4’‐ditertbutyldiphenyl and N N is a…”
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Binuclear Biphenyl Organogold(III) Complexes: Synthesis, Photophysical and Theoretical Investigation, and Anticancer Activity
Published in ChemPlusChem (Weinheim, Germany) (01-11-2023)“…A series of four binuclear complexes of general formula [(C^C)Au(Cl)(L^L)(Cl)Au(C^C)], where C^C is 4,4’‐diterbutylbiphenyl and L^L is either a bridging…”
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14
Improved Steroids Detection and Evidence for Their Regiospecific Decompositions Using Anion Attachment Mass Spectrometry
Published in Analytical chemistry (Washington) (05-04-2016)“…Nonpolar anabolic steroids are doping agents that typically do not provide strong signals by electrospray ionization-mass spectrometry (ESI-MS) owing…”
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15
Experimental bond dissociation energies of benzylpyridinium thermometer ions determined by threshold-CID and RRKM modeling
Published in International journal of mass spectrometry (01-06-2017)“…[Display omitted] •BDE of benzylpyridinium ions were determined by TCID measurements and RRKM modeling.•Commercial QhQ enables relative measurements of…”
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Synthesis and characterization of new neutral Mn(I) tricarbonyl complexes with 8‐hydroxyquinoline and imidazole ligands as CO releasing molecules
Published in Applied organometallic chemistry (01-08-2023)“…A series of manganese(I) tricarbonyl complexes formulated as [Mn(8‐HQ)(CO)3Imd] (HQ = hydroxyquinoline and Imd = imidazole derivatives) was synthesized and…”
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Reactant-induced photoactivation of in situ generated organogold intermediates leading to alkynylated indoles via Csp2-Csp cross-coupling
Published in Nature communications (28-04-2022)“…Photosensitization of organogold intermediates is an emerging field in catalysis. In this context, an access to 2,3-disubstituted indoles from o -alkynyl…”
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Trifluoromethyl radical triggered radical cyclization of N-benzoyl ynamides leading to isoindolinones
Published in Science China. Chemistry (01-11-2019)“…Under photocatalytic reductive conditions, trifluoromethyl radical addition onto an ynamide followed by cyclization on a benzoyl moiety produces diverse…”
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19
Extended kinetic method and RRKM modeling to reinvestigate proline’s proton affinity and approach the meaning of effective temperature
Published in European journal of mass spectrometry (Chichester, England) (01-04-2019)“…Proline proton affinity PA(Pro) was previously measured by extended kinetic methods with several amines as reference bases using a triple quadrupole mass…”
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Vacuum Ultraviolet Photoionization Study of Gas Phase Vitamins A and B1 Using Aerosol Thermodesorption and Synchrotron Radiation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (26-11-2014)“…Gas-phase studies of biomolecules are often difficult to initiate because of the thermolability of these systems. Such studies are nevertheless important to…”
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