Search Results - "Dorta, Romano"

Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of Catalyst-Substrate Adducts by Dorta, Romano, Broggini, Diego, Stoop, Robert, Rüegger, Heinz, Spindler, Felix, Togni, Antonio

“…Iridium complexes relevant to the catalytic enantioselective hydrogenation of 2‐methyl‐6‐ethylphenyl‐1′‐methyl‐2′‐methoxyethylimine (MEA‐imine, 1) in the…”
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The [IrCl(Diphosphine)]2/Fluoride System. Developing Catalytic Asymmetric Olefin Hydroamination by Dorta, Romano, Egli, Patrick, Zürcher, Fabio, Togni, Antonio

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On the Effect of Iodide and Acids in the Metolachlor Process by Breitwieser, Kevin, Dorta, Romano, Munz, Dominik

“…Iridium-catalyzed asymmetric imine hydrogenation is the key step in the industrial syntheses of dextromethorphan and metolachlor. Nevertheless, the mechanism…”
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Room Temperature Liquid Salts of Cr and Mo as Self-Supported Oxidants by Noguera, Gladys, Mostany, Jorge, Agrifoglio, Giuseppe, Dorta, Romano

“…Room temperature liquid salts of Cr and Mo were synthesized and fully characterized including cyclic voltammetry of the neat Mo salt. These liquid salts were…”
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Facile and Reversible O−H and C−H Activation by a Chiral Iridium(I) Complex by Dorta, Romano, Togni, Antonio

“…The reactivity of the dinuclear Ir(I) complexes cis- and trans-[Ir2(μ-Cl)2((R)-(S)-PPFPPh2)2] (1, (R)-(S)-PPFPPh2 =…”
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(Z)-4-(2,5-Di-tert-butyl-anilino)pent-3-en-2-one by Pastrán, Jesús, Ramírez, Andrea, Agrifoglio, Giuseppe, Linden, Anthony, Dorta, Romano

“…In the crystal structure of the title ketoamine, C(19)H(29)NO, the bond lengths from the N atom through the alkene group to the ketone O atom show the presence…”
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Diarylformamides as a Safe Reservoir and Room Temperature Source of Ultra‐Pure CO in the Context of a ‘Green’ rWGS Reaction by Hurtado, Royel, Lou, Lisha, Klerner, Lukas, Inaloo, Iman Dindarloo, Heineman, Frank W., Harder, Sjoerd, Schmid, Günter, Dorta, Romano

“…Abstract Diphenylformamide 1 and bisformamide 9 are shown to be safe reservoirs and sources of CO. Their perfectly selective decarbonylations are achieved in…”
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Diarylformamides as a safe reservoir and room temperature source of ultra-pure CO for a 'green' rWGS reaction by Hurtado, Royel, Lou, Lisha, Klerner, Lukas, Inaloo, Iman Dindarloo, Heineman, Frank W, Harder, Sjoerd, Schmid, Günter, Dorta, Romano

“…Diarylformamides are shown to be a safe reservoir and source of CO. Perfectly selective decarbonylation is achieved in solution at room temperature with…”
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Stable Meisenheimer Complexes as Powerful Photoreductants Readily Obtained from Aza‐Hetero Aromatic Compounds by Calogero, Francesco, Wilczek, Leonie, Pinosa, Emanuele, Gualandi, Andrea, Dorta, Romano, Herrera, Alberto, Dai, Yasi, Rossignol, Arthur, Negri, Fabrizia, Ziani, Zakaria, Fermi, Andrea, Ceroni, Paola, Cozzi, Pier Giorgio

“…Excited states of radical anions derived from the photoreduction of stable organic molecules are suggested to serve as potent reductants. However, excited…”
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C 2 and C 1 ‐Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins by Aguilera, Tania, Pastrán, Jesús, Llovera, Ligia, Linden, Anthony, Herrera, Alberto, Venuti, Doménico, Agrifoglio, Giuseppe, Dorta, Romano

“…Abstract Dioxomolybdenum(VI) complexes ( 1 ‐ 6 ) were prepared in good yields (≥79 %) using enantiopure C 2 and C 1 ‐symmetric bidentate N,N‐ligands ( L 1 ‐ L…”
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Synthesis, X-Ray, Hirshfeld Surface, DFT, and Molecular Docking Investigation of N-(5H-Dibenzo[a,d][7]Annulen-5-Ylidene)-2-Methylpropane-2-Sulfinamide by Chelouan, Ahmed, Herrera, Alberto, Dorta, Romano, Filali, Insaf, Anouar, El Hassane

“…Dibenzocycloheptene antidepressants are tricyclic antidepressants (TCAs) that contain the dibenzocycloheptene moiety in their chemical structures. They are…”
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Stereochemical Stability of Planar-Chiral Benzazepine Tricyclics: Inversion Energies of P- and S-Alkene Ligands by Calderón, Jacqueline C., Herrera, Alberto, Heinemann, Frank W., Langer, Jens, Linden, Anthony, Chelouan, Ahmed, Grasruck, Alexander, Añez, Rafael, Clark, Timothy, Dorta, Romano

“…Inversion barriers ΔG‡ for planar chiral phosphine-alkene and sulfonamide-alkene hybrid ligands based on phenyl-dibenz[b,f]azepine have been determined by…”
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C2 and C1‐Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins by Aguilera, Tania, Pastrán, Jesús, Llovera, Ligia, Linden, Anthony, Herrera, Alberto, Venuti, Doménico, Agrifoglio, Giuseppe, Dorta, Romano

“…Dioxomolybdenum(VI) complexes (1‐6) were prepared in good yields (≥79 %) using enantiopure C2 and C1‐symmetric bidentate N,N‐ligands (L1‐L6) derived from…”
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Towards enantiopure macrocyclic trans-dinucleating hemilabile P-Alkene ligands: Syntheses, structures, and Chiral Pd-Complexes by Frieß, Sibylle, Herrera, Alberto, Linden, Anthony, Heinemann, Frank W., Dorta, Romano

“…Dibenzazepinyl dichlorophosphine 2 reacts with (R,R)-2,3-O-isopropylidene-threitol (3) in Et2O solution to afford gram-quantities of the enantiopure macrocylic…”
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s‑Block Metal Dibenzoazepinate Complexes: Evidence for Mg–Alkene Encapsulation by Freitag, Benjamin, Elsen, Holger, Pahl, Jürgen, Ballmann, Gerd, Herrera, Alberto, Dorta, Romano, Harder, Sjoerd

“…The dibenzo­[b,f]­azepinate (DBAP) complexes (DBAP)­Li·(THF)3, (DBAP)2Mg·(THF)2, and (DBAP)2Ca·(THF)3 could be isolated as highly air-sensitive compounds in…”
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Tricyclic Sulfoxide–Alkene Hybrid Ligands for Chiral Rh(I) Complexes: The “Matched” Diastereomer Catalyzes Asymmetric C–C Bond Formations by Nikol, Alexander, Zhang, Ziyun, Chelouan, Ahmed, Falivene, Laura, Cavallo, Luigi, Herrera, Alberto, Heinemann, Frank W, Escalona, Ana, Frieß, Sibylle, Grasruck, Alexander, Dorta, Romano

“…Deprotonation of phenyldibenzo­[b,f]­tropylidene (8) with LDA/t-BuOK followed by quenching with either diastereomer of inexpensive glucose-based t-Bu-sulfinate…”
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Synthesis and Characterization of Chiral Bis(aminato)iridate(I) and Aminato-Bridged Iridium(I) Complexes by Dorta, Romano, Togni, Antonio

“…The two dinuclear IrI complexes [Ir2(μ‐Cl)2 {(R)‐(S)‐PPF‐PPh2}2] (1; (R)‐(S)‐PPF‐PPh2=(S)‐1‐(diphenylphosphino)‐2‐[(R)‐1‐(diphenylphosphino)ethyl]ferrocene and…”
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Ruthenium (II) complexes with C- and C-symmetric bis-(+)-camphopyrazole ligands and their evaluation in catalytic transfer hydrogenation of aldehydes by Blanco, Christian O., Llovera, Ligia, Herrera, Alberto, Dorta, Romano, Agrifoglio, Giuseppe, Venuti, Doménico, Landaeta, Vanessa R., Pastrán, Jesús

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Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br 2 and I 2 . Unprecedented Trap-Free Reductive Elimination of I 2 from a formal d 5 Metal by Frieß, Sibylle, Benyak, Anna, Herrera, Alberto, Escalona, Ana M, Heinemann, Frank W, Langer, Jens, Fehn, Dominik, Pividori, Daniel, Grasruck, Alexander, Munz, Dominik, Meyer, Karsten, Dorta, Romano

“…Oxidative addition of 1.5 equiv of bromine or iodine to a Ir(I) sulfoxide pincer complex affords the corresponding Ir(IV) tris-bromido or tris-iodido…”
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Developing Chiral Dibenzazepine-Based S(O)-Alkene Hybrid Ligands for Rh(I) Complexation: Catalysts for the Base-Free Hayashi–Miyaura Reaction by Chelouan, Ahmed, Bao, Siyuan, Frieß, Sibylle, Herrera, Alberto, Heinemann, Frank W, Escalona, Ana, Grasruck, Alexander, Dorta, Romano

“…A stereodivergent synthesis using inexpensive reagents, i.e., dibenzazepine and glucose-derived t-Bu-sulfinate diastereomers (R S)-6 or (S S)-6, affords…”
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