Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis

Ethynyl silyl ketone 1 proved to be a very efficient Michael acceptor in carbocupration and metallocupration reactions. In particular, when using carbocuprates, a smooth entry to polyenals can be obtained, while, when using metallocuprates, silyl- and stannylpropenoyl silanes may be obtained, very p...

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Bibliographic Details

Published in:	Tetrahedron Vol. 57; no. 29; pp. 6267 - 6276
Main Authors:	Capperucci, Antonella, Degl'Innocenti, Alessandro, Dondoli, Paolo, Nocentini, Tiziano, Reginato, Gianna, Ricci, Alfredo
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 16-07-2001
Subjects:	acylsilanes cuprates Michael reactions polyenals polyenes polyenes polyenals acylsilanes Michael reactions cuprates
Online Access:	Get full text
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