Search Results - "Dobrinovitch, Isabel T."
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1
C−H Activation and C−C Coupling Reactions in 2-Vinylpyridine Cationic Complexes of Iridium
Published in Organometallics (12-04-2004)“…The complex [IrH2(NCCH3)3(PiPr3)]BF4 (1) reacts with 2-vinylpyridine to form the hydride [IrH{NC5H4-2-Z-(CHCH)-κ-N,C}(NCCH3)2(PiPr3)]BF4 (3) in a reaction…”
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2
Proton Conduction in a Nonporous One Dimensional Coordination Polymer
Published in Chemistry of materials (23-09-2014)“…Complex impedance measurements on single crystals and pellets of a CuCo-orotate coordination polymer, as a function of relative humidity and temperature,…”
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3
Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM2 (M = Rh, Ir) Early−Late Heterobimetallic Complexes
Published in Organometallics (17-03-2003)“…Reactions of the zirconium−sulfide metallocene anion [Cptt 2ZrS2]2- (Cptt = η5-1,3-di-tert-butylcyclopentadienyl) with [{M(μ-Cl)(diolefin)}2 gave the d0−d8…”
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4
Asymmetric 1,3-Dipolar Cycloaddition Reaction between α,β-Unsaturated Aldehydes and Nitrones Catalyzed by Well-Defined Iridium or Rhodium Catalysts
Published in Advanced synthesis & catalysis (02-07-2007)“…Reaction of the complexes (SM,RC)‐[(η5‐C5Me5)M{(R)‐Prophos}(H2O)](SbF6)2 (M=Rh, Ir) with α,β‐unsaturated aldehydes diastereoselectively gave complexes…”
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5
Unusual 1‐Alkyne Dimerization/Hydrogenation Sequences Catalyzed by [Ir(H) 2 (NCCH 3 ) 3 (P‐ i ‐Pr 3 )]BF 4 : Evidence for Homogeneous‐Like Mechanism in Imidazolium Salts
Published in Advanced synthesis & catalysis (01-01-2003)“…The reaction of complex [Ir(H) 2 (NCCH 3 ) 3 (P‐ i ‐Pr 3 )]BF 4 ( 1 ) with excess of 1‐alkynes such as t ‐BuC≡CH and PhC≡CH gave the butadiene compounds Ir[η 4…”
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6
Crescent-Shaped Rhodium(I) Complexes with Bis(o-carboxymethylphenyl)triazenide
Published in Inorganic chemistry (26-07-2004)“…Reaction of [{Rh(μ-Cl)(CO)2}2] with the triazene ArNNNHAr (Ar = o-CO2MeC6H4) produced the mononuclear complex [RhCl(ArNNNHAr)(CO)2] (1). Complex 1 reacted with…”
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7
Stereoselective Oxidative Additions of Iodoalkanes and Activated Alkynes to a Sulfido-Bridged Heterotrinuclear Early−Late (TiIr2) Complex
Published in Inorganic chemistry (16-06-2003)“…The reactions of the early−late trinuclear complex [Cp(acac)Ti(μ3-S)2Ir2(CO)4] (1) with electrophiles have been found to occur on the iridium atoms with no…”
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8
Unusual 1-Alkyne Dimerization/Hydrogenation Sequences Catalyzed by [Ir(H)2(NCCH3)3(P-i-Pr3)]BF4: Evidence for Homogeneous-Like Mechanism in Imidazolium Salts
Published in Advanced synthesis & catalysis (01-01-2003)“…The reaction of complex [Ir(H)2(NCCH3)3(P‐i‐Pr3)]BF4 (1) with excess of 1‐alkynes such as t‐BuC≡CH and PhC≡CH gave the butadiene compounds…”
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9
Synthesis and characterization of Ru(II), Rh(III) and Ir(III) complexes of the “Daniphos” ligands and their application in the hydrogen transfer catalysis
Published in Inorganica Chimica Acta (20-07-2004)“…The synthesis and characterization of arene–ruthenium(II) and C 5Me 5–rhodium(III) and –iridium(III) complexes of chiral arene-chromium-tricarbonyl-based P ∧P…”
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10
Two Jahn–Teller systems involved in different kinds of crystal-to-crystal transformations
Published in Acta crystallographica. Section A, Foundations and advances (29-07-2022)“…Abstract only…”
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11
The Anions [Cptt 2Zr(μ-S)2M(CO)2]- (M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds
Published in Organometallics (03-12-2007)“…The reaction of [Cptt 2Zr(μ3-S)2{Ir(CO)2}2] (Cptt = η5-1,3-di-tert-butylcyclopentadienyl) with dppe (1,2-bis-(diphenylphosphino)ethane) affords the ion-pair…”
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12
Asymmetric 1,3-Dipolar Cycloaddition Reaction between alpha,eta-Unsaturated Aldehydes and Nitrones Catalyzed by Well-Defined Iridium or Rhodium Catalysts
Published in Advanced synthesis & catalysis (02-07-2007)“…Reaction of the complexes (SM,RC)-[(5-C5Me5)M{(R)-Prophos}(H2O)](SbF6)2 (M=Rh, Ir) with ,-unsaturated aldehydes diastereoselectively gave complexes…”
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13
Novel gem-Dithiolato-Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry
Published in European Journal of Inorganic Chemistry (01-12-2007)“…The direct protonation of the bridging hydroxo ligands in [Rh(μ‐OH)(cod)]2 by 1,1‐dimercaptocyclohexane [Chxn(SH)2] yields the gem‐dithiolato‐bridged compound…”
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14
Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions (Eur. J. Inorg. Chem. 9/2005)
Published in European journal of inorganic chemistry (01-05-2005)“…The cover picture shows the structure of a new chiral iridium(I) complex with the (4S)‐2‐[2‐(diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline ligand…”
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15
Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM 2 (M = Rh, Ir) Early−Late Heterobimetallic Complexes
Published in Organometallics (01-03-2003)Get full text
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16
Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions
Published in European Journal of Inorganic Chemistry (01-05-2005)“…The chiral iridium compounds [IrCl(COE){(S)‐PN}] {COE = cyclooctene, PN = (4S)‐2‐[2‐(diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline, (1)},…”
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Book Review Journal Article