Search Results - "Dikarev, Evgeny V."
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1
Synthesis, Structure, and Characterizations of a Volatile/Soluble Heterometallic Hexanuclear Precursor [NaMn 2 (thd) 4 (OAc)] 2
Published in Molecules (Basel, Switzerland) (27-11-2023)“…The paper describes a hetero metallic mixed-ligand hexanuclear precursor [NaMn (thd) (OAc)] ( ) (thd = 2,2,6,6-tetramethyl-3,5-heptadionate; OAc = acetate)…”
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2
Assembling Polyiodides and Iodobismuthates Using a Template Effect of a Cyclic Diammonium Cation and Formation of a Low-Gap Hybrid Iodobismuthate with High Thermal Stability
Published in Molecules (Basel, Switzerland) (15-06-2020)“…Exploiting a template effect of 1,4-diazacycloheptane (also known as homopiperazine, Hpipe), four new hybrid iodides, (HpipeH ) Bi I ·2H O, (HpipeH )I(I ),…”
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3
Synthesis, Structure, and Characterizations of a Heterobimetallic Heptanuclear Complex [Pb2Co5(acac)14]
Published in Crystals (Basel) (01-07-2023)“…An unusual heterobimetallic volatile compound [Pb2Co5(acac)14] was synthesized by the gas phase/solid-state technique. The preparation can be readily scaled up…”
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4
Molecular and Supramolecular Structures of Triiodides and Polyiodobismuthates of Phenylenediammonium and Its N,N-dimethyl Derivative
Published in Molecules (Basel, Switzerland) (21-09-2021)“…Despite remarkable progress in photoconversion efficiency, the toxicity of lead-based hybrid perovskites remains an important issue hindering their…”
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5
From Solid State to Solution: Advancing Chemistry of Bi–Bi and Bi–Rh Paddlewheel Carboxylates
Published in Inorganic chemistry (02-01-2012)“…The first successful high-yield solution synthesis of homobimetallic Bi2(O2CCF3)4 (1), as well as heterobimetallic BiRh(O2CCF3)4 (2) and BiRh(O2CCF2CF3)4 (3),…”
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6
Monomeric Square-Planar Cobalt(II) Acetylacetonate: Mystery or Mistake?
Published in Inorganic chemistry (20-09-2010)“…No evidence was found for the existence of a previously reported mononuclear square-planar form of unsolvated cobalt(II) acetylacetonate, Co(acac)2, in all…”
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7
Protective Spinel Coating for Li1.17Ni0.17Mn0.50Co0.17O2 Cathode for Li-Ion Batteries through Single-Source Precursor Approach
Published in Nanomaterials (Basel, Switzerland) (18-09-2020)“…The Li1.17Ni0.17Mn0.50Co0.17O2 Li-rich NMC positive electrode (cathode) for lithium-ion batteries has been coated with nanocrystals of the LiMn1.5Co0.5O4…”
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8
Nowotny Chimney Ladder Phases with Group 5 Metals: Crystal and Electronic Structure and Relations to the CrSi2 Structure Type
Published in Crystals (Basel) (01-08-2020)“…Nowotny chimney ladder (NCL) phases are intermetallic compounds formed by transition metals and metals of groups 13 and 14. This family can be expanded by…”
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9
Trickier than It Looks: Isomerization between Five- and Six-Coordinated Zinc in Heterometallic Li2Zn2 Molecule
Published in Inorganic chemistry (08-07-2024)“…This report describes the synthesis and characterization of two heterobimetallic Li–Zn coordination isomers [Li2Zn2(tbaoac)6] (tbaoac = tert-butyl…”
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10
Trickier than It Looks: Isomerization between Five- and Six-Coordinated Zinc in Heterometallic Li 2 Zn 2 Molecule
Published in Inorganic chemistry (08-07-2024)“…This report describes the synthesis and characterization of two hetero metallic Li-Zn coordination isomers [Li Zn (tbaoac) ] (tbaoac = -butyl acetoacetato)…”
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11
Bismuth−Palladium Heterometallic Carboxylate as a Single-Source Precursor for the Carbon-Supported Pd−Bi/C Catalysts
Published in Inorganic chemistry (06-07-2009)“…The heterometallic complex [Bi2Pd2(O2CCF3)10(HO2CCF3)2] (1) was obtained by the solid state reaction of BiIII trifluoroacetate/trifluoroacetic acid adduct with…”
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12
Tuning the Properties at Heterobimetallic Core: Mixed-Ligand Bismuth−Rhodium Paddlewheel Carboxylates
Published in Journal of the American Chemical Society (08-03-2006)“…Mixed-ligand heterometallic compounds [BiRh(O2CCF3)4 - x (O2CR) x ] (R = Bu t , x = 2 (cis); R = Me, Bu i , x = 1) have been obtained by gas-phase reactions of…”
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13
Heterobimetallic Main-Group-Transition-Metal Paddle-Wheel Carboxylates
Published in Angewandte Chemie International Edition (04-03-2005)“…Bismuth(II) tetra(trifluoroacetate) acts as a metalloligand toward transition‐metal units to yield heterobimetallic homoleptic carboxylates [BiM(O2CCF3)4]…”
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14
Synthesis, Structure, and Chemistry of New, Mixed Group 14 and 16 Heterocycles: Nucleophile-Induced Ring Contraction of Mesocyclic Dications
Published in Journal of the American Chemical Society (22-11-2006)“…More than 40 new 4- to 12-membered ring heterocycles containing various combinations of Group 14 and 16 elements Si, Sn, S, Se, and Te have been synthesized…”
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15
Heterometallic Molecular and Ionic Isomers
Published in Inorganic chemistry (14-10-2024)“…Numerous descriptions of structural isomerism in metal complexes do not list any molecular vs ionic isomers. At the same time, one of the most striking…”
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16
Rational Syntheses, Structure, and Properties of the First Bismuth(II) Carboxylate
Published in Inorganic chemistry (31-05-2004)“…Bismuth(II) trifluoroacetate (1), the first inorganic salt of bismuth in oxidation state +2, has been obtained in its pure, unstabilized form. Several…”
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17
From cubane-assembled Mn-oxo clusters to monodispersed manganese oxide colloidal nanocrystals
Published in Chemical science (Cambridge) (10-07-2024)“…The assemblies of [M 4 O 4 ] (M = metal) cubanes represent a fascinating class of materials for a variety of application fields. Although such a structural…”
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18
Two polymorph modifications of tris(hexafluoroacetylacetonato)iron(III) revealed: is that common for other trivalent metals?
Published in Acta crystallographica. Section C, Crystal structure communications (01-09-2024)“…A long‐standing issue about the correct identification of an important starting reagent, iron(III) hexafluoroacetylacetonate, Fe(hfac)3 (1), has been resolved…”
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19
Multi-functional Single-Source Molecular Precursors for Carbon-Coated Mixed-Metal Phosphates
Published in Inorganic chemistry (14-08-2023)“…We introduce a new synthetic concept that can be broadly adopted for the low-temperature preparation of mixed-metal energy storage materials, such as…”
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20
Volatile Heterometallic Precursors for the Low-Temperature Synthesis of Prospective Sodium Ion Battery Cathode Materials
Published in Journal of the American Chemical Society (21-08-2013)“…Heterometallic single-source precursors with a proper sodium:transition-metal ratio for nonoxide sodium ion battery cathode materials are reported…”
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