Search Results - "Diederich, Francois"
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Structural Aspects of Fullerene ChemistryA Journey through Fullerene Chirality
Published in Chemical reviews (01-12-2006)“…The discovery of fullerenes have profoundly influenced all aspects of contemporary chemistry. This review focuses on the chirality of soluble fullerenes and…”
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Supramolecular Capsules: Strong versus Weak Chalcogen Bonding
Published in Angewandte Chemie International Edition (21-12-2018)“…Resorcin[4]arene cavitands containing either 2,1,3‐benzotelluradiazole or 2,1,3‐benzothiadiazole motifs were dimerized to supramolecular capsules by chalcogen…”
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Chalcogen Bonding “2S–2N Squares” versus Competing Interactions: Exploring the Recognition Properties of Sulfur
Published in Chemistry : a European journal (02-01-2019)“…Chalcogen bonding (CB) is the focus of increased attention for its applications in medicinal chemistry, materials science, and crystal engineering. However,…”
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Halogen‐Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase
Published in Angewandte Chemie International Edition (19-01-2017)“…Supramolecular capsules were assembled by neutral halogen bonding (XB) and studied in the solid state, in solution, and in the gas phase. The geometry of the…”
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Helicene Monomers and Dimers: Chiral Chromophores Featuring Strong Circularly Polarized Luminescence
Published in Chemistry : a European journal (18-06-2019)“…The synthesis and chiroptical properties of a series of enantiomerically pure, C2‐symmetrical carbo[6]helicene dimers are reported. Two helicene cores are…”
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Intense Ground-State Charge-Transfer Interactions in Low-Bandgap, Panchromatic Phthalocyanine-Tetracyanobuta-1,3-diene Conjugates
Published in Angewandte Chemie International Edition (25-04-2016)“…A cycloaddition–retroelectrocyclization reaction between tetracyanoethylene and two zinc phthalocyanines (ZnIIPcs) bearing one or four anilino‐substituted…”
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7
Selective Extraction of C 70 by a Tetragonal Prismatic Porphyrin Cage
Published in Journal of the American Chemical Society (24-10-2018)“…Along with the advent of supramolecular chemistry, research on fullerene receptors based on noncovalent bonding interactions has attracted a lot of attention…”
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Sub-Picosecond Singlet Exciton Fission in Cyano-Substituted Diaryltetracenes
Published in Angewandte Chemie International Edition (20-07-2015)“…Thin films of 5,11‐dicyano‐6,12‐diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of…”
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The hit-and-return system enables efficient time-resolved serial synchrotron crystallography
Published in Nature methods (01-11-2018)“…We present a ‘hit-and-return’ (HARE) method for time-resolved serial synchrotron crystallography with time resolution from milliseconds to seconds or longer…”
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10
Unraveling a Ligand‐Induced Twist of a Homodimeric Enzyme by Pulsed Electron–Electron Double Resonance
Published in Angewandte Chemie International Edition (18-10-2021)“…Mechanistic insights into protein–ligand interactions can yield chemical tools for modulating protein function and enable their use for therapeutic purposes…”
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11
Orthogonal dipolar interactions between amide carbonyl groups
Published in Proceedings of the National Academy of Sciences - PNAS (11-11-2008)“…Orthogonal dipolar interactions between amide C=O bond dipoles are commonly found in crystal structures of small molecules, proteins, and protein-ligand…”
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12
Targeting a Large Active Site: Structure‐Based Design of Nanomolar Inhibitors of Trypanosoma brucei Trypanothione Reductase
Published in Chemistry : a European journal (02-09-2019)“…Trypanothione reductase (TR) plays a key role in the unique redox metabolism of trypanosomatids, the causative agents of human African trypanosomiasis (HAT),…”
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Optical properties of highly nonlinear silicon-organic hybrid (SOH) waveguide geometries
Published in Optics express (28-09-2009)“…Geometry, nonlinearity, dispersion and two-photon absorption figure of merit of three basic silicon-organic hybrid waveguide designs are compared. Four-wave…”
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14
Origin of Intense Intramolecular Charge‐Transfer Interactions in Nonplanar Push–Pull Chromophores
Published in Chemistry : a European journal (07-09-2009)“…Nonplanar push–pull chromophores with tetrathiafulvalene and ferrocene donors (see picture) were prepared by formal [2+2] cycloadditions between electron‐rich…”
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Strain-Accelerated Formation of Chiral, Optically Active Buta-1,3-dienes
Published in Angewandte Chemie International Edition (02-01-2015)“…The formal [2+2] cycloaddition–retroelectrocyclization (CA–RE) reactions between tetracyanoethylene (TCNE) and strained, electron‐rich dibenzo‐fused…”
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Synthesis of Cyano-Substituted Diaryltetracenes from Tetraaryl[3]cumulenes
Published in Angewandte Chemie International Edition (22-04-2014)“…A versatile, two‐step synthesis of highly substituted, cyano‐functionalized diaryltetracenes has been developed, starting from easily accessible…”
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The [2+2] Cycloaddition‐Retroelectrocyclization (CA‐RE) Click Reaction: Facile Access to Molecular and Polymeric Push‐Pull Chromophores
Published in Angewandte Chemie International Edition (26-03-2018)“…The [2+2] cycloaddition‐retroelectrocyclization (CA‐RE) reaction between electron‐rich alkynes and electron‐deficient alkenes is an efficient procedure to…”
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Electronic Structures and Chiroptical Properties of Post-functionalized Helicene Quinones
Published in Chemistry : a European journal (17-05-2016)“…The synthesis of redox‐active p‐ and o‐quinones 2‐phenylamino‐4‐phenylimino[6]helicene‐1‐one 1, 2‐phenylamino[6]‐helicene‐1,4‐dione 2, and…”
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Modification of Supramolecular Binding Motifs Induced By Substrate Registry: Formation of Self-Assembled Macrocycles and Chain-Like Patterns
Published in Chemistry : a European journal (26-10-2009)“…The self‐assembly properties of two ZnII porphyrin isomers on Cu(111) are studied at different coverage by means of scanning tunneling microscopy (STM). Both…”
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Photoredox‐Switchable Resorcin[4]arene Cavitands: Radical Control of Molecular Gripping Machinery via Hydrogen Bonding
Published in Chemistry : a European journal (26-01-2018)“…Semiquinones (SQ) are generated in photosynthetic organisms upon photoinduced electron transfer to quinones (Q). They are stabilized by hydrogen bonding (HB)…”
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