Search Results - "DiSalvo, Francis"
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Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts
Published in Journal of the American Chemical Society (11-12-2019)“…Developing high-performance, low-cost, and conductive nonprecious electrocatalysts for the oxygen reduction reaction (ORR) has been a key challenge for…”
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Metal–Organic-Framework-Derived Co–Fe Bimetallic Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells
Published in Journal of the American Chemical Society (10-07-2019)“…The oxygen reduction reaction (ORR) is considered the cornerstone for regenerative energy conversion devices involving fuel cells and electrolyzers. The…”
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High-Performance Pd3Pb Intermetallic Catalyst for Electrochemical Oxygen Reduction
Published in Nano letters (13-04-2016)“…Extensive efforts to develop highly active and strongly durable electrocatalyst for oxygen reduction are motivated by a need for metal–air batteries and fuel…”
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Yolk–Shell Structure of Polyaniline-Coated Sulfur for Lithium–Sulfur Batteries
Published in Journal of the American Chemical Society (06-11-2013)“…Lithium–sulfur batteries have attracted much attention in recent years due to their high theoretical capacity of 1672 mAh g–1 and low cost. However, a rapid…”
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High-Loading Intermetallic Pt3Co/C Core–Shell Nanoparticles as Enhanced Activity Electrocatalysts toward the Oxygen Reduction Reaction (ORR)
Published in Chemistry of materials (13-03-2018)“…A facile, seed-mediated growth method and postannealing treatment have been employed to synthesize a single-phase 40% mass loading intermetallic Pt3Co/Vulcan…”
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Synergistic Bimetallic Metallic Organic Framework-Derived Pt–Co Oxygen Reduction Electrocatalysts
Published in ACS nano (27-10-2020)“…The rational design of Pt-based electrocatalysts is of paramount importance for the commercialization of proton exchange membrane fuel cells (PEMFCs). Pt–Co…”
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A Strategy for Increasing the Efficiency of the Oxygen Reduction Reaction in Mn-Doped Cobalt Ferrites
Published in Journal of the American Chemical Society (13-03-2019)“…Alkaline fuel cells have drawn increasing attention as next-generation energy-conversion devices for electrical vehicles, since high pH enables the use of…”
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Mesoporous Ti0.5Cr0.5N Supported PdAg Nanoalloy as Highly Active and Stable Catalysts for the Electro-oxidation of Formic Acid and Methanol
Published in ACS nano (24-06-2014)“…We report a robust noncarbon Ti0.5Cr0.5N support synthesized by an efficient solid–solid phase separation method. This ternary nitride exhibits highly porous,…”
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Multifunctional Electrocatalysts: Ru–M (M = Co, Ni, Fe) for Alkaline Fuel Cells and Electrolyzers
Published in ACS catalysis (17-04-2020)“…Moving from proton exchange membrane fuel cells to anion exchange membrane fuel cells (AEMFCs) enables the use of non-Pt-group (NPG) metals as cathodes for the…”
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Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
Published in Nature materials (01-01-2013)“…To enhance and optimize nanocatalyst performance and durability for the oxygen reduction reaction in fuel-cell applications, we look beyond Pt–metal disordered…”
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Mesoporous Chromium Nitride as High Performance Catalyst Support for Methanol Electrooxidation
Published in Chemistry of materials (14-05-2013)“…A simple process for preparing mesoporous chromium nitride (CrN) by the ammonolysis of a bulk ternary oxide (K2Cr2O7) is reported. The products were…”
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Synthesis of Structurally Ordered Pt3Ti and Pt3V Nanoparticles as Methanol Oxidation Catalysts
Published in Journal of the American Chemical Society (23-07-2014)“…Structurally ordered Pt3Ti or Pt3V intermetallic nanoparticle catalysts with ultrasmall particle sizes have never been successfully synthesized. Herein, we…”
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Pt-Decorated Composition-Tunable Pd–Fe@Pd/C Core–Shell Nanoparticles with Enhanced Electrocatalytic Activity toward the Oxygen Reduction Reaction
Published in Journal of the American Chemical Society (13-06-2018)“…Design of electrocatalysts with both a high-Pt-utilization efficiency and enhanced electrochemical activity is still the key challenge in the development of…”
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14
Structurally Ordered Pt3Cr as Oxygen Reduction Electrocatalyst: Ordering Control and Origin of Enhanced Stability
Published in Chemistry of materials (10-11-2015)“…Ordered intermetallic phases provide predictable control over structure and electronic effects, not afforded by the widely studied alloys. However, because of…”
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Enhancing the Electrocatalytic Activity of Pd/M (M = Ni, Mn) Nanoparticles for the Oxygen Reduction Reaction in Alkaline Media through Electrochemical Dealloying
Published in ACS catalysis (15-05-2020)“…We have developed a facile and effective electrochemical dealloying strategy to enhance the electrocatalytic activity of Pd/M (M = Ni, Mn) nanoparticles for…”
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Octahedral spinel electrocatalysts for alkaline fuel cells
Published in Proceedings of the National Academy of Sciences - PNAS (03-12-2019)“…Designing high-performance nonprecious electrocatalysts to replace Pt for the oxygen reduction reaction (ORR) has been a key challenge for advancing fuel cell…”
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Combinatorial Studies of Palladium-Based Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells
Published in Journal of the American Chemical Society (26-02-2020)“…Hydrogen fuel cells have emerged as promising, potentially renewable energy-based, energy conversion technologies for powering electric vehicles. However, the…”
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18
Operando Methods in Electrocatalysis
Published in ACS catalysis (05-02-2021)“…Electrocatalysis has been the cornerstone for enhancing energy efficiency, minimizing environmental impacts and carbon emissions, and enabling a more…”
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Nonprecious transition metal nitrides as efficient oxygen reduction electrocatalysts for alkaline fuel cells
Published in Science advances (04-02-2022)“…Hydrogen fuel cells have attracted growing attention for high-performance automotive power but are hindered by the scarcity of platinum (and other precious…”
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Tuning Oxygen Reduction Reaction Activity via Controllable Dealloying: A Model Study of Ordered Cu3Pt/C Intermetallic Nanocatalysts
Published in Nano letters (10-10-2012)“…A promising electrocatalyst prototype of low Pt mole fraction, intermetallic nanoparticles of Cu3Pt, has been prepared using a simple impregnation-reduction…”
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