Search Results - "Deutsch, Todd G."
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Direct solar-to-hydrogen conversion via inverted metamorphic multi-junction semiconductor architectures
Published in Nature energy (13-03-2017)“…Solar water splitting via multi-junction semiconductor photoelectrochemical cells provides direct conversion of solar energy to stored chemical energy as…”
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Integrated halide perovskite photoelectrochemical cells with solar-driven water-splitting efficiency of 20.8
Published in Nature communications (26-06-2023)“…Achieving high solar-to-hydrogen (STH) efficiency concomitant with long-term durability using low-cost, scalable photo-absorbers is a long-standing challenge…”
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High performance III-V photoelectrodes for solar water splitting via synergistically tailored structure and stoichiometry
Published in Nature communications (29-07-2019)“…Catalytic interface of semiconductor photoelectrodes is critical for high-performance photoelectrochemical solar water splitting because of its multiple roles…”
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Accelerating materials development for photoelectrochemical hydrogen production: Standards for methods, definitions, and reporting protocols
Published in Journal of Materials Research (01-01-2010)“…Photoelectrochemical (PEC) water splitting for hydrogen production is a promising technology that uses sunlight and water to produce renewable hydrogen with…”
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Book Review Journal Article -
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Molybdenum Disulfide as a Protection Layer and Catalyst for Gallium Indium Phosphide Solar Water Splitting Photocathodes
Published in The journal of physical chemistry letters (02-06-2016)“…Gallium indium phosphide (GaInP2) is a semiconductor with promising optical and electronic properties for solar water splitting, but its surface stability is…”
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Employing Overlayers To Improve the Performance of Cu2BaSnS4 Thin Film based Photoelectrochemical Water Reduction Devices
Published in Chemistry of materials (14-02-2017)“…Earth-abundant copper-barium-thiostannate Cu2BaSnS4 (CBTS)-based thin films have recently been reported to exhibit the optoelectronic and defect properties…”
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Addressing the Stability Gap in Photoelectrochemistry: Molybdenum Disulfide Protective Catalysts for Tandem III–V Unassisted Solar Water Splitting
Published in ACS energy letters (14-08-2020)“…While photoelectrochemical (PEC) solar-to-hydrogen efficiencies have greatly improved over the past few decades, advances in PEC durability have lagged behind…”
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Best Practices in PEC Water Splitting: How to Reliably Measure Solar-to-Hydrogen Efficiency of Photoelectrodes
Published in Frontiers in energy research (27-10-2022)“…Photoelectrochemical (PEC) water splitting, which utilizes sunlight and water to produce hydrogen fuel, is potentially one of the most sustainable routes to…”
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III−V Nitride Epilayers for Photoelectrochemical Water Splitting: GaPN and GaAsPN
Published in The journal of physical chemistry. B (21-12-2006)“…Epilayers of single-crystal GaAsPN and GaPN semiconductor samples with varying nitrogen compositions were photoelectrochemically characterized to determine…”
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Concentrating on solar for hydrogen
Published in Nature energy (01-06-2023)“…Hydrogen generated by sunlight could play a major role in a low-carbon future, but high-efficiency demonstrations have been limited mostly to very small…”
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Understanding the Stability of Etched or Platinized p‑GaInP Photocathodes for Solar-Driven H2 Evolution
Published in ACS applied materials & interfaces (08-12-2021)“…The long-term stability in acidic or alkaline aqueous electrolytes of p-Ga0.52In0.48P photocathodes, with a band gap of ∼1.8 eV, for the solar-driven…”
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A Robust, Scalable Platform for the Electrochemical Conversion of CO2 to Formate: Identifying Pathways to Higher Energy Efficiencies
Published in ACS energy letters (11-05-2020)“…This work demonstrated a robust, scalable cell architecture for electroreduction of CO2 (CO2R). An up to 90% faradaic efficiency for the conversion of CO2R to…”
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Phosphonic Acid Modification of GaInP2 Photocathodes Toward Unbiased Photoelectrochemical Water Splitting
Published in ACS applied materials & interfaces (03-06-2015)“…The p-type semiconductor GaInP2 has a nearly ideal bandgap (∼1.83 eV) for hydrogen fuel generation by photoelectrochemical water splitting but is unable to…”
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Printed assemblies of GaAs photoelectrodes with decoupled optical and reactive interfaces for unassisted solar water splitting
Published in Nature energy (27-03-2017)“…Despite their excellent photophysical properties and record-high solar-to-hydrogen conversion efficiency, the high cost and limited stability of III–V compound…”
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Engineering Surface Architectures for Improved Durability in III–V Photocathodes
Published in ACS applied materials & interfaces (11-05-2022)“…GaInP2 has shown promise as the wide bandgap top junction in tandem absorber photoelectrochemical (PEC) water splitting devices. Among previously reported…”
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Failure Modes of Platinized pn + -GaInP Photocathodes for Solar-Driven H 2 Evolution
Published in ACS applied materials & interfaces (15-06-2022)“…The long-term stability for the hydrogen-evolution reaction (HER) of homojunction pn -Ga In P photocathodes (band gap = 1.8 eV) with an electrodeposited Pt…”
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Failure Modes of Platinized pn+‑GaInP Photocathodes for Solar-Driven H2 Evolution
Published in ACS applied materials & interfaces (15-06-2022)“…The long-term stability for the hydrogen-evolution reaction (HER) of homojunction pn+-Ga0.52In0.48P photocathodes (band gap = 1.8 eV) with an electrodeposited…”
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Protection of GaInP2 Photocathodes by Direct Photoelectrodeposition of MoSx Thin Films
Published in ACS applied materials & interfaces (17-07-2019)“…Catalytic MoSx thin films have been directly photoelectrodeposited on GaInP2 photocathodes for stable photoelectrochemical hydrogen generation. Specifically,…”
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Protection of GaInP2 Photocathodes by Direct Photoelectrodeposition of MoS x Thin Films
Published in ACS applied materials & interfaces (17-07-2019)“…Catalytic MoS x thin films have been directly photoelectrodeposited on GaInP2 photocathodes for stable photoelectrochemical hydrogen generation. Specifically,…”
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High-Performance Bipolar Membrane Development for Improved Water Dissociation
Published in ACS applied polymer materials (13-11-2020)“…Bipolar membranes (BPMs) are the enabling component of many promising electrochemical devices used for separation and energy conversion. Here, we describe the…”
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