Search Results - "Deutman, Alexander B C"
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Porphyrin Macrocyclic Catalysts for the Processive Oxidation of Polymer Substrates
Published in Journal of the American Chemical Society (10-02-2010)“…A novel cavity-containing porphyrin catalyst based on a previously reported clip architecture, substituted on the outer face with urea terminated tails, has…”
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Mechanism of Threading a Polymer Through a Macrocyclic Ring
Published in Science (American Association for the Advancement of Science) (12-12-2008)“…The translocation of biopolymers through pores and channels plays a fundamental role in numerous biological processes. We describe here the mechanism of the…”
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Slippage of a Porphyrin Macrocycle over Threads of Varying Bulkiness: Implications for the Mechanism of Threading Polymers through a Macrocyclic Ring
Published in Chemistry : a European journal (02-01-2015)“…Threading of a polymer through a macrocyclic ring may occur directly, that is, by finding the end of the polymer chain, or by a process in which the polymer…”
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Strong Induced-Fit Binding of Viologen and Pyridine Derivatives in Adjustable Porphyrin Cavities
Published in Chemistry : a European journal (01-09-2014)“…The synthesis and binding properties of new porphyrin cage compounds consisting of a rigid diphenylglycoluril part, which is connected via flexible…”
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Designing Processive Catalytic Systems. Threading Polymers through a Flexible Macrocycle Ring
Published in Journal of the American Chemical Society (25-06-2014)“…The translocation of polymers through pores is widely observed in nature and studying their mechanism may help understand the fundamental features of these…”
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Thermodynamics and kinetics of guest-induced switching between "basket handle" porphyrin isomers
Published in Molecules (Basel, Switzerland) (23-04-2014)“…The synthesis and switching properties of two "basket handle" porphyrin isomers is described. The cis-oriented meso-phenyl groups of these porphyrins are…”
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Squaring cooperative binding circles
Published in Proceedings of the National Academy of Sciences - PNAS (30-06-2009)“…The cooperative binding effects of viologens and pyridines to a synthetic bivalent porphyrin receptor are used as a model system to study how the magnitudes of…”
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Processive Rotaxane Systems. Studies on the Mechanism and Control of the Threading Process
Published in Journal of the American Chemical Society (02-05-2007)“…The threading behavior of a zinc analogue of a previously reported processive manganese porphyrin catalyst onto a series of polymers of different lengths is…”
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Molecular recognition and self-assembly special feature: Squaring cooperative binding circles
Published in Proceedings of the National Academy of Sciences - PNAS (30-06-2009)“…The cooperative binding effects of viologens and pyridines to a synthetic bivalent porphyrin receptor are used as a model system to study how the magnitudes of…”
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