In situ observation of chrysotile decomposition in the presence of NaCl-bearing aqueous fluid up to 5 GPa and 400 °C

Natural occurrence of chrysotile, a rock-forming serpentine mineral, is largely associated with fluid-rich environments, thus making the fluid chemistry an important factor governing chrysotile growth and stability. Paper examines the effect of alkali chlorides, lowering the H 2 O activity in fluid,...

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Bibliographic Details
Published in:	Mineralogy and petrology Vol. 115; no. 2; pp. 213 - 222
Main Authors:	Likhacheva, Anna Yu, Goryainov, Sergey V., Rashchenko, Sergey V., Dementiev, Sergey N., Safonov, Oleg G.
Format:	Journal Article
Language:	English
Published:	Vienna Springer Vienna 01-04-2021 Springer Nature B.V
Subjects:	Amorphization Analytical methods Chlorides Chrysotile Dehydration Diamond anvil cells Diamonds Earth and Environmental Science Earth Sciences Fluids Forsterite Geochemistry High pressure Inorganic Chemistry Low temperature Mineralogy Minerals Original Paper Raman spectroscopy Saline environments Salts Serpentine Sodium chloride Stability Subduction Subduction (geology) Subduction zones Talc Temperature X-ray diffraction NaCl aqueous fluid O activity Amorphization H Chrysotile High temperature In situ Raman spectroscopy High pressure
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Summary:	Natural occurrence of chrysotile, a rock-forming serpentine mineral, is largely associated with fluid-rich environments, thus making the fluid chemistry an important factor governing chrysotile growth and stability. Paper examines the effect of alkali chlorides, lowering the H 2 O activity in fluid, on chrysotile stability at high pressure. The behavior of natural chrysotile (Thetford) in the presence of concentrated NaCl-H 2 O fluids was studied up to 5 GPa and 400 °C using in-situ Raman spectroscopy and X-ray diffraction combined with resistively heated diamond anvil cell. Reference experiments were also performed on salt-free samples. In salt-free H 2 O-saturated conditions, chrysotile is stable within the whole temperature range at 1.5–5 GPa. The presence of NaCl in the fluid at X NaCl = mole NaCl/(NaCl+H 2 O) ≈ 0.1–0.15 strongly suppresses the temperature of chrysotile dehydration at 2–4 GPa to 380 °C, which is about 170 °C lower compared to the equilibrium data for H 2 O-saturated salt-free system. Talc/talc-like phase only crystallizes at H P -H T conditions as product of the reaction “chrysotile → forsterite + talc”, whereas forsterite appears after the P , T release. This indicates an enhanced solubility of forsterite in supercritical NaCl-H 2 O fluid at H P -H T conditions. Chrysotile shows disordering/amorphization at unusually low temperature of 150 °C. The shift of the chrysotile dehydration to lower temperatures in saline environment makes this process more operable in natural metamorphic processes in serpentinites. This effect can be extended to other serpentine minerals, including antigorite, a common participant of H P -H T metamorphic reactions in subduction zones.
ISSN:	0930-0708 1438-1168
DOI:	10.1007/s00710-020-00731-x