Perfluoro-1,2-di-t-butylvinyl radical stable in an inert medium

The perfluoro-1,2-di-t-butylvinyl radical has been generated by direct fluorination of perfluorodi-t-butylacetylene or by the addition of the perfluorodi-t-butyl radical to perfluoro-t-butylacetylene in perfluorodiamyl ether. The radical was identified by its ESR spectrum, and appeared to be quite s...

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Bibliographic Details
Published in:Journal of fluorine chemistry Vol. 79; no. 1; pp. 93 - 95
Main Authors: Cherstkov, V.F., Tumanskii, B.L., Delyagina, N.I., Sterlin, S.R., German, L.S.
Format: Journal Article
Language:English
Published: Elsevier B.V 01-07-1996
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Summary:The perfluoro-1,2-di-t-butylvinyl radical has been generated by direct fluorination of perfluorodi-t-butylacetylene or by the addition of the perfluorodi-t-butyl radical to perfluoro-t-butylacetylene in perfluorodiamyl ether. The radical was identified by its ESR spectrum, and appeared to be quite stable in an inert medium.
ISSN:0022-1139
1873-3328
DOI:10.1016/0022-1139(96)03477-X