Search Results - "Della Sala, Paolo"
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Deep-Cavity Calix[4]naphth[4]arene Macrocycles: Synthesis, Conformational Features, and Solid-State Structures
Published in Molecules (Basel, Switzerland) (31-08-2024)“…We recently introduced calix[ ]naphth[ ]arenes as a novel class of deep-cavity hybrid macrocycles constituted by phenol (n) and naphthalene (m) units. In this…”
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2
Synthesis and Glycosidase Inhibition Properties of Calix[8]arene-Based Iminosugar Click Clusters
Published in Pharmaceuticals (Basel, Switzerland) (01-11-2020)“…A set of 6- to 24-valent clusters was constructed with terminal deoxynojirimycin (DNJ) inhibitory heads through C6 or C9 linkers by way of Cu(I)-catalyzed…”
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3
Poly(Ethylene Glycol)/β-Cyclodextrin Pseudorotaxane Complexes as Sustainable Dispersing and Retarding Materials in a Cement-Based Mortar
Published in ACS omega (11-05-2021)“…Pseudorotaxane complexes between β-CD and mPEG derivatives bearing a carboxylic acid function (mPEG–COOH) were synthesized and investigated for their…”
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4
Dispersing and Retarding Properties of Water-Soluble Tetrasulfonate Resorcin[4]arene and Pyrogallol[4]arene Macrocycles in Cement-Based Mortar
Published in ACS omega (28-07-2020)“…Water-soluble tetrasulfonate resorcin[4]arene (1a and 1c) and pyrogallol[4]arene (1b) macrocycles were synthesized and investigated for their dispersing…”
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Prismarenes: A New Class of Macrocyclic Hosts Obtained by Templation in a Thermodynamically Controlled Synthesis
Published in Journal of the American Chemical Society (29-01-2020)“…The novel title macrocycles, based on methylene-bridged 1,5-naphthalene units, have been obtained by template effect in a thermodynamically controlled…”
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The Resorcinarene Hexameric Capsule as a Supramolecular Photoacid to Trigger Olefin Hydroarylation in Confined Space
Published in Chemistry : a European journal (16-04-2024)“…The self‐assembled resorcinarene capsule C6 shows remarkable photoacidity upon light irradiation, which is here exploited to catalyze olefin hydroarylation…”
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Under the Influence of Water: Molecular Recognition of Organic Hydrophilic Molecules in Water with a Prismarene Host Driven by Hydration Effects
Published in Chemistry : a European journal (06-08-2024)“…A water‐soluble prism[5]arene host can form endo‐cavity complexes with hydrophilic organic substances in water by displacing frustrated water molecules from…”
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Kinetic and Thermodynamic Modulation of Dynamic Imine Libraries Driven by the Hexameric Resorcinarene Capsule
Published in Journal of the American Chemical Society (02-09-2020)“…The composition of dynamic covalent imine libraries (DCL) adapts to the presence of the hexameric resorcinarene capsule. In the presence of the self-assembled…”
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9
Carbocation catalysis in confined space: activation of trityl chloride inside the hexameric resorcinarene capsule
Published in Chemical science (Cambridge) (29-07-2022)“…Carbocation catalysis can be performed inside the confined space of the hexameric resorcinarene capsule. The inner cavity of the capsule can host the trityl…”
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10
An intramolecularly self-templated synthesis of macrocycles: self-filling effects on the formation of prismarenes
Published in Chemical science (Cambridge) (28-07-2021)“…Ethyl- and propyl-prism[6]arenes are obtained in high yields and in short reaction times, independent of the nature and size of the solvent, in the cyclization…”
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11
Hexahexyloxycalix[6]arene, a Conformationally Adaptive Host for the Complexation of Linear and Branched Alkylammonium Guests
Published in Molecules (Basel, Switzerland) (13-06-2023)“…Hexahexyloxycalix[6]arene leads to the -cavity complexation of linear and branched alkylammonium guests showing a conformational adaptive behavior in CDCl…”
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12
An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion
Published in Journal of organic chemistry (05-01-2018)“…The anthracene-incorporated [8]cycloparaphenylene 2 has been synthesized and its optoelectronic properties studied by UV–vis spectroscopy, cyclic…”
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13
Vicia faba L. Pod Valves: A By-Product with High Potential as an Adjuvant in the Treatment of Parkinson's Disease
Published in Molecules (Basel, Switzerland) (01-08-2024)“…L. is a leguminous plant with seeds rich in nutritional compounds, such as polyphenols and L-dopa, a dopamine precursor and first-line treatment for…”
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14
Study on the Influence of Chirality in the Threading of Calix[6]arene Hosts with Dialkylammonium Axles
Published in Molecules (Basel, Switzerland) (15-11-2020)“…The influence of chirality in calixarene threading has been studied by exploiting the "superweak anion approach". In particular, the formation of chiral…”
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15
Selective recognition of bisphenol S isomers in water by β-cyclodextrin
Published in Supramolecular chemistry (03-06-2021)“…The two isomers 4,4´-dihydroxydiphenyl sulphone and 2,4´-dihydroxydiphenyl sulphone (bisphenol S, BPS) form inclusion complexes with β-CD in solution, in the…”
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16
Supramolecular Catalysis with Chiral Mono- and Bis-(Thio)Urea-Derivatives
Published in Organics (Basel) (01-06-2024)“…Chiral mono- and bis-(thio)urea supramolecular organocatalysts were studied in the enantioselective vinylogous addition reaction of 2-trimethylsilyloxyfuran…”
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Chirality Transfer in a Calixarene-Based Directional Pseudorotaxane Complex
Published in Chemistry an international journal (01-09-2021)“…Hexamethoxycalix[6]arene 3 forms a directional pseudorotaxane complex with the chiral axle (S)-(α-methyl-benzyl)benzylammonium 2+. Between the two…”
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18
per-Hydroxylated Prism[n]arenes: Supramolecularly Assisted Demethylation of Methoxy-Prism[5]arene
Published in Organic letters (05-11-2021)“…Methoxy-prism[5]arene PrS[5] Me is demethylated by a supramolecularly assisted reaction. In the presence of a tetramethylammonium cation, PrS[5] Me is…”
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Insights into the Self‐Filling Effects of Branched Isopropyl Groups on the Conformational and Supramolecular Properties of Isopropoxyprism[6]arene
Published in European journal of organic chemistry (16-10-2023)“…Abstract In this work, the direct macrocyclization of a prism[6]arene macrocycle bearing branched alkyl chains on the rims is reported. Isopropoxyprism[6]arene…”
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Supramolecular control on reactivity and selectivity inside the confined space of H-bonded hexameric capsules
Published in Current opinion in colloid & interface science (01-06-2023)“…The confinement of substrates inside the cavity of self-assembled capsules makes it possible to effectively catalyze organic reactions in a way that is…”
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