Search Results - "Delgado, Fernando S."
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Supramolecular Networks in Copper(II) Malonate Complexes
Published in Crystal growth & design (03-09-2008)“…Six new copper(II)-malonate containing complexes [Cu(dpydiol)(mal)(H2O)]·2H2O (1) (dpydiol = bis(2-pyridyl)methanediol), [Cu(dpa)(mal)(H2O)]·H2O (2) (dpa =…”
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Malonate-Containing Manganese(III) Complexes: Synthesis, Crystal Structure, and Magnetic Properties of AsPh4[Mn(mal)2(H2O)2]
Published in Inorganic chemistry (06-02-2006)“…The novel manganese(III) complexes PPh4[Mn(mal)2(H2O)2] (1) and AsPh4[Mn(mal)2(H2O)2] (2) (PPh4 + = tetraphenylphosphonium cation, AsPh4 + =…”
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3
1,2,4,5-Benzenetetracarboxylic Acid and 4,4′-Bipyridine as Ligands in Designing Low-Dimensional Coordination Polymers
Published in European journal of inorganic chemistry (01-10-2004)“…The combined use of 1,2,4,5‐benzenetetracarboxylic acid (H4bta) and 4,4′‐bipyridine (bpy) as ligands with MnII and CoII ions afforded two polymeric compounds…”
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4
Study of the Influence of the Bridge on the Magnetic Coupling in Cobalt(II) Complexes
Published in Inorganic chemistry (07-12-2009)“…Two new cobalt(II) complexes of formula [Co2(bta)(H2O)6] n ·2nH2O (1) and [Co(phda)(H2O)] n ·nH2O (2) [H4bta = 1,2,4,5-benzenetetracarboxylic acid, H2phda =…”
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5
Crystal Structure and Magnetic Properties of Two Isomeric Three-Dimensional Pyromellitate-Containing Cobalt(II) Complexes
Published in Inorganic chemistry (15-09-2008)“…The hydrothermal preparation, crystal structure determination, and magnetic study of two isomers made up of 1,2,4,5-benzenetetracarboxylate and high-spin CoII…”
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6
Unusual (μ-aqua)bis(μ-carboxylate) Bridge in Homometallic M(II) (M = Mn, Co and Ni) Two-Dimensional Compounds Based on the 1,2,3,4-Butanetetracarboxylic Acid: Synthesis, Structure, and Magnetic Properties
Published in Inorganic chemistry (03-09-2007)“…The first coordination compounds of 1,2,3,4-butanetetracarboxylate anion (butca4-) of the formula [M2(butca)(H2O)5] n ·2nH2O [M = Mn(II) (1), Co(II) (2), and…”
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7
The construction of open Gd(III) metal-organic frameworks based on methanetriacetic acid: new objects with an old ligand
Published in Chemistry : a European journal (06-04-2010)“…The preparation, X-ray crystallography and magnetic investigation of the first examples of methanetriacetate (mta)-containing lanthanide(III) complexes of…”
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8
Insertion of a spin crossover Fe(III) complex into an oxalate-based layered material: coexistence of spin canting and spin crossover in a hybrid magnet
Published in Inorganic chemistry (06-10-2008)“…The syntheses, structures, and magnetic properties of the compounds of formula [Fe (III)(sal 2trien)] 2[Mn (II) 2(ox) 3].4H 2O.C 3H 7NO ( 1) and [In (III)(sal…”
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Cobalt(II) Sheet-Like Systems Based on Diacetic Ligands: from Subtle Structural Variances to Different Magnetic Behaviors
Published in Inorganic chemistry (06-07-2009)“…The preparation, X-ray crystallography, and magnetic investigation of the compounds [Co(H2O)2(phda)] n (1), [Co(phda)] n (2), and [Co(chda)] n (3) [H2phda =…”
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10
Design of High-Dimensional Copper(II) Malonate Complexes with Exo-Polydentate N-Donor Ligands
Published in Inorganic chemistry (22-09-2003)“…Two polymeric malonato-bridged copper(II) complexes of formulas {(H2bpe)[Cu(mal)2]} n ·4nH2O (1) and [Cu4(mal)4(bpe)3] n ·6nH2O (2) [mal = malonate dianion;…”
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11
The Construction of Open Gd III Metal–Organic Frameworks Based on Methanetriacetic Acid: New Objects with an Old Ligand
Published in Chemistry : a European journal (06-04-2010)“…The preparation, X‐ray crystallography and magnetic investigation of the first examples of methanetriacetate (mta)‐containing lanthanide(III) complexes of…”
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12
(4,4) Rectangular Lattices of Cobalt(II) with 1,2,4,5-Benzenetetracarboxylic Acid: Influence of the Packing in the Crystal Structure
Published in Crystal growth & design (05-11-2008)“…The preparation, structural characterization and magnetic investigation of three new cobalt(II) complexes of formula [Co2(bta)(H2O)8] n ·4nH2O (1 and 2) and…”
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13
Novel Malonate-Containing Coordination Compounds with Ligands Having N- and NO-Donors: Synthesis, Structures, and Magnetic Properties
Published in Crystal growth & design (01-02-2012)“…In our efforts to tune the structures of mixed-ligands malonate-containing coordination compounds, four copper(II) and two high-spin cobalt(II) complexes of…”
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14
Low-Dimensional Copper(II) Complexes with the Trinucleating Ligand 2,4,6-Tris(di-2-pyridylamine)-1,3,5-triazine: Synthesis, Crystal Structures, and Magnetic Properties
Published in Inorganic chemistry (20-07-2009)“…The preparation and structural characterization of three new copper(II) complexes of formula [Cu3(dipyatriz)2(H2O)3](ClO4)6·2H2O (1),…”
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Nuclearity Controlled Cyanide-Bridged Bimetallic CrIII-MnII Compounds: Synthesis, Crystal Structures, Magnetic Properties and Theoretical Calculations
Published in Chemistry : a European journal (03-12-2004)“…The preparation, X‐ray crystallography and magnetic investigation of the compounds PPh4[Cr(bipy)(CN)4]⋅2 CH3CN⋅H2O (1) (mononuclear),…”
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16
Hydrogen Bond-Directed Frameworks Based on 1,2,4,5-Benzene-Tetracarboxylate
Published in Crystal growth & design (01-05-2005)“…The deprotonated forms of 1,2,4,5-benzenetetracarboxylic acid H4bta can act not only as hydrogen-bond acceptors but also as hydrogen-bond donors, depending on…”
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17
Zeolite-like Nanoporous Gadolinium Complexes Incorporating Alkaline Cations
Published in Crystal growth & design (01-01-2006)“…In this article, we describe the synthesis and single-crystal X-ray structural studies of two new lanthanide complexes of formula [MILnIII(bta)(H2O)3]·nH2O, (M…”
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18
Crystal Engineering of Complexes of Propane-1,2,3-tricarboxylic Acid (H3tca) with Lanthanide(III) Cations
Published in Crystal growth & design (01-04-2008)“…The knowledge of the one-synthon based supramolecular network of the propane-1,2,3-tricarboxylic acid (H3tca), commonly referred to as tricarballylic acid (1),…”
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19
Insertion of a Spin Crossover FeIII Complex into an Oxalate-Based Layered Material: Coexistence of Spin Canting and Spin Crossover in a Hybrid Magnet
Published in Inorganic chemistry (06-10-2008)“…The syntheses, structures, and magnetic properties of the compounds of formula [FeIII(sal2trien)]2[MnII 2(ox)3]·4H2O·C3H7NO (1) and [InIII(sal2trien)]2[MnII…”
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20
Spin Control in Ladderlike Hexanuclear Copper(II) Complexes with Metallacyclophane Cores
Published in Inorganic chemistry (03-05-2004)“…Two new hexanuclear oxamatocopper(II) complexes 3 and 4 have been synthesized from the binuclear copper(II) complexes of the meta- and…”
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