Search Results - "Deetz, Alexander M"

Chloride Oxidation by One- or Two-Photon Excitation of N‑Phenylphenothiazine by Li, Pengju, Deetz, Alexander M., Hu, Jiaming, Meyer, Gerald J., Hu, Ke

“…Chloride oxidation has tremendous utility in the burgeoning field of chlorine-mediated C–H activation, yet it remains a challenging process to initiate with…”
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Formation of Chlorosilyl Pincer-Type Rhodium Complexes by Multiple Si–H Activations of Bis(phosphine)/Dihydrosilyl Ligands by Whited, Matthew T, Deetz, Alexander M, Boerma, Joseph W, DeRosha, Daniel E, Janzen, Daron E

“…The synthesis and metalation of two bis(phosphine)/dihydrosilyl ligands at rhodium(I) sources is reported. Irrespective of the substitution at silicon (diaryl…”
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Nanosecond Intra-Ionic Chloride Photo-Oxidation by Deetz, Alexander M., Goodwin, Matthew J., Kober, Erin A., Meyer, Gerald J.

“…Transition-metal photocatalysts capable of oxidizing chloride are rare yet serve as an attractive means to controllably generate chlorine atoms, which have…”
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Periodic Trends in Intra-ionic Excited State Quenching by Halide by Goodwin, Matthew J., Deetz, Alexander M., Griffin, Paul J., Meyer, Gerald J.

“…The preassociation of reactants in a photoinitiated redox reaction through the use of noncovalent interactions can have a significant impact on excited state…”
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Factors that Impact Photochemical Cage Escape Yields by Goodwin, Matthew J., Dickenson, John C., Ripak, Alexia, Deetz, Alexander M., McCarthy, Jackson S., Meyer, Gerald J., Troian-Gautier, Ludovic

“…The utilization of visible light to mediate chemical reactions in fluid solutions has applications that range from solar fuel production to medicine and…”
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On the Determination of Halogen Atom Reduction Potentials with Photoredox Catalysts by Deetz, Alexander M, Troian-Gautier, Ludovic, Wehlin, Sara A. M, Piechota, Eric J, Meyer, Gerald J

“…The standard one-electron reduction potentials of halogen atoms, E°′(X•/–), and many other radical or unstable species, are not accessible through standard…”
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Resolving Halide Ion Stabilization through Kinetically Competitive Electron Transfers by Deetz, Alexander M, Meyer, Gerald J

“…Stabilization of ions and radicals often determines reaction kinetics and thermodynamics, but experimental determination of the stabilization magnitude remains…”
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Photocatalyst assemblies with two halide ions by Turlington, Michael D., Deetz, Alexander M., Vitt, Dylan, Meyer, Gerald J.

“…A series of ruthenium polypyridyl photocatalysts bearing amide functional groups were designed that successfully promoted halide assembly in CH2Cl2 and CH3CN…”
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Fundamental Insights Into Photo-Initiated Halide Oxidation and the Influence of Noncovalent Interactions by Deetz, Alexander M

“…In just one and a half hours, the sunlight that strikes earth provides enough energy to meet the world’s energy consumption for an entire year. Developing…”
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