Search Results - "Deckers, Kristina"
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1
Squaramide‐Catalyzed Asymmetric aza‐Friedel–Crafts/N,O‐Acetalization Domino Reactions Between 2‐Naphthols and Pyrazolinone Ketimines
Published in Angewandte Chemie International Edition (27-11-2017)“…N‐Boc ketimines derived from pyrazolin‐5‐ones were explored to develop an unprecedented domino aza‐Friedel–Crafts/N,O‐acetalization reaction with 2‐naphthols…”
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2
Combining Silver Catalysis and Organocatalysis: A Sequential Michael Addition/Hydroalkoxylation One-Pot Approach to Annulated Coumarins
Published in Organic letters (03-10-2014)“…A highly stereoselective one-pot procedure for the synthesis of five-membered annulated hydroxycoumarins has been developed. By merging primary amine catalysis…”
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3
Orthogonal Stability and Reactivity of Aryl Germanes Enables Rapid and Selective (Multi)Halogenations
Published in Angewandte Chemie (12-10-2020)“…While halogenation is of key importance in synthesis and radioimaging, the currently available repertoire is largely designed to introduce a single halogen per…”
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4
Orthogonal Stability and Reactivity of Aryl Germanes Enables Rapid and Selective (Multi)Halogenations
Published in Angewandte Chemie International Edition (12-10-2020)“…While halogenation is of key importance in synthesis and radioimaging, the currently available repertoire is largely designed to introduce a single halogen per…”
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5
Direct Synthesis of Acyl Fluorides from Carboxylic Acids with the Bench-Stable Solid Reagent (Me4N)SCF3
Published in Organic letters (03-11-2017)“…A convenient, highly efficient, and selective transformation of aliphatic and aromatic carboxylic acids to acyl fluorides is reported. In contrast to…”
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6
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench‐Stable Precursor (Me4N)SCF3
Published in Angewandte Chemie International Edition (02-01-2017)“…Reported herein is the one‐pot synthesis of trifluoromethylated amines at room temperature using the bench‐stable (Me4N)SCF3 reagent and AgF. The method is…”
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7
Organocatalytic Asymmetric Synthesis of Tetracyclic Pyridocarbazole Derivatives by Using a Diels-Alder/aza-Michael/Aldol Condensation Domino Reaction
Published in Chemistry : a European journal (12-08-2013)“…Triple domino: An organocatalytic asymmetric triple cascade reaction to form tetracyclic pyridocarbazole derivatives is described. The new protocol includes a…”
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8
Electrochemistry-Enabled C‑Heteroatom Bond Formation of Alkyl Germanes
Published in Journal of the American Chemical Society (07-08-2024)“…Because of their robustness and orthogonal reactivity features, alkyl germanes bear significant potential as functional handles for the construction of…”
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9
Quadruple Domino Organocatalysis: An Asymmetric Aza-Michael/Michael/Michael/Aldol Reaction Sequence Leading to Tetracyclic Indole Structures with Six Stereocenters
Published in Chemistry : a European journal (13-08-2012)“…Quadruple domino/Wittig–one pot: An organocatalytic, asymmetric, three‐component quadruple cascade, which leads to tetracyclic double‐annulated indole…”
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10
Combining silver- and organocatalysis: an enantioselective sequential catalytic approach towards pyrano-annulated pyrazoles
Published in Chemical communications (Cambridge, England) (11-02-2015)“…A one-pot asymmetric Michael addition/hydroalkoxylation sequence, catalyzed by a sequential catalytic system consisting of a squaramide and a silver salt,…”
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11
Modular Generation of (Iodinated) Polyarenes Using Triethylgermane as Orthogonal Masking Group
Published in Angewandte Chemie International Edition (09-05-2022)“…While the modular construction of molecules from suitable building blocks is a powerful means to more rapidly generate a diversity of molecules than through…”
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12
Direct Synthesis of Acyl Fluorides from Carboxylic Acids with the Bench-Stable Solid Reagent (Me 4 N)SCF 3
Published in Organic letters (03-11-2017)“…A convenient, highly efficient, and selective transformation of aliphatic and aromatic carboxylic acids to acyl fluorides is reported. In contrast to…”
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Journal Article -
13
Asymmetric Synthesis of Spiropyrazolones by Sequential Organo- and Silver Catalysis
Published in Angewandte Chemie International Edition (26-01-2016)“…A stereoselective one‐pot synthesis of spiropyrazolones through an organocatalytic asymmetric Michael addition and a formal Conia‐ene reaction has been…”
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14
Selective ortho‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer
Published in Angewandte Chemie International Edition (11-05-2020)“…Contrary to the general belief that Pd‐catalyzed cross‐coupling at sites of severe steric hindrance are disfavored, we herein show that the oxidative addition…”
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15
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me 4 N)SCF 3
Published in Angewandte Chemie International Edition (02-01-2017)“…Reported herein is the one-pot synthesis of trifluoromethylated amines at room temperature using the bench-stable (Me N)SCF reagent and AgF. The method is…”
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16
Access to Cyclic N‑Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides
Published in Journal of the American Chemical Society (06-04-2022)“…We report the mild activation of carbamoyl azides to the corresponding nitrenes using a blue light/[Ir]-catalyzed strategy, which enables stereospecific access…”
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17
Modular Generation of (Iodinated) Polyarenes Using Triethylgermane as Orthogonal Masking Group
Published in Angewandte Chemie (09-05-2022)“…While the modular construction of molecules from suitable building blocks is a powerful means to more rapidly generate a diversity of molecules than through…”
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Journal Article -
18
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me4N)SCF3
Published in Angewandte Chemie (02-01-2017)“…Reported herein is the one-pot synthesis of trifluoromethylated amines at room temperature using the bench-stable (Me4N)SCF3 reagent and AgF. The method is…”
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Journal Article -
19
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench‐Stable Precursor (Me 4 N)SCF 3
Published in Angewandte Chemie (02-01-2017)“…Reported herein is the one‐pot synthesis of trifluoromethylated amines at room temperature using the bench‐stable (Me 4 N)SCF 3 reagent and AgF. The method is…”
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Journal Article -
20
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me sub(4)N)SCF sub(3)
Published in Angewandte Chemie (01-01-2017)“…Reported herein is the one-pot synthesis of trifluoromethylated amines at room temperature using the bench-stable (Me sub(4)N)SCF sub(3) reagent and AgF. The…”
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