Search Results - "Dean Toste, F"

Modern Approaches for Asymmetric Construction of Carbon–Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs by Zhu, Yi, Han, Jianlin, Wang, Jiandong, Shibata, Norio, Sodeoka, Mikiko, Soloshonok, Vadim A, Coelho, Jaime A. S, Toste, F. Dean

“…New methods for preparation of tailor-made fluorine-containing compounds are in extremely high demand in nearly every sector of chemical industry. The…”
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Advances in Catalytic Enantioselective Fluorination, Mono‑, Di‑, and Trifluoromethylation, and Trifluoromethylthiolation Reactions by Yang, Xiaoyu, Wu, Tao, Phipps, Robert J., Toste, F. Dean

“…Recent advances related to catalytic enantioselectice fluorination are examined. Catalytic enantioselective monofluoromethylation and catalytic…”
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Non-Oxidative Vanadium-Catalyzed C----O Bond Cleavage: Application to Degradation of Lignin Model Compounds by Son, Sunghee, Toste, F. Dean

“…New direction: Changes in the ligand structure divert the reactivity of vanadium(V) oxo complexes from alcohol oxidation to a novel non‐oxidative CO bond…”
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Palladium-Catalyzed Defluorinative Coupling of 1-Aryl-2,2-Difluoroalkenes and Boronic Acids: Stereoselective Synthesis of Monofluorostilbenes by Thornbury, Richard T., Toste, F. Dean

“…The palladium‐catalyzed defluorinative coupling of 1‐aryl‐2,2‐difluoroalkenes with boronic acids is described. Broad functional‐group tolerance arises from a…”
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Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes by Bohan, Patrick T, Toste, F. Dean

“…The development of a gold­(III) catalyzed direct enantioconvergent 1,5-enyne cycloisomerization and kinetic resolution reaction is described. The…”
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Expanding the Scope of Biomass-Derived Chemicals through Tandem Reactions Based on Oxorhenium-Catalyzed Deoxydehydration by Shiramizu, Mika, Toste, F. Dean

“…New modes of DODH: Oxorhenium compounds act as deoxydehydration(DODH)/acid dual‐purpose catalysts to transform biomass‐derived diol substrates into a variety…”
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Enantioselective Oxidative Homocoupling and Cross-Coupling of 2‑Naphthols Catalyzed by Chiral Iron Phosphate Complexes by Narute, Sachin, Parnes, Regev, Toste, F. Dean, Pappo, Doron

“…Novel chiral iron phosphate complexes were prepared as catalysts for asymmetric oxidative coupling reactions. These catalysts were applied for the synthesis of…”
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A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis by He, Ying, Wu, Hongmiao, Toste, F Dean

“…A new method for the P-arylation of aryldiazonium salts with H-phosphonates dual gold and photoredox catalysis is described. The reaction proceeds smoothly at…”
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The progression of chiral anions from concepts to applications in asymmetric catalysis by Phipps, Robert J., Hamilton, Gregory L., Toste, F. Dean

“…Novel concepts in asymmetric catalysis have the potential to open up previously inaccessible reaction space. This Review reflects on the origins of an area…”
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Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles by Zi, Weiwei, Wu, Hongmiao, Toste, F. Dean

“…A highly enantioselective dearomative Rautenstrauch rearrangement catalyzed by cationic (S)-DTBM-Segphosgold­(I) is reported. This reaction provides a…”
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A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length by Bender, Trandon A, Bergman, Robert G, Raymond, Kenneth N, Toste, F. Dean

“…Performing selective transformations on complex substrates remains a challenge in synthetic chemistry. These difficulties often arise due to cross-reactivity,…”
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Chiral Anion Phase-Transfer Catalysis Applied to the Direct Enantioselective Fluorinative Dearomatization of Phenols by Phipps, Robert J, Toste, F. Dean

“…Chiral anion phase-transfer catalysis has enabled the direct and highly enantioselective fluorinative dearomatization of phenols catalyzed by a BINOL-derived…”
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Relativistic effects in homogeneous gold catalysis by GORIN, David J, TOSTE, F. Dean

“…Transition-metal catalysts containing gold present new opportunities for chemical synthesis, and it is therefore not surprising that these complexes are…”
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Development of Catalysts and Ligands for Enantioselective Gold Catalysis by Wang, Yi-Ming, Lackner, Aaron D, Toste, F. Dean

“…During the past decade, the use of Au(I) complexes for the catalytic activation of C–C π-bonds has been investigated intensely. Over this time period, the…”
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Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion by Shu, Xing-zhong, Zhang, Miao, He, Ying, Frei, Heinz, Toste, F. Dean

“…A combination of visible light photocatalysis and gold catalysis is applied to a ring expansion–oxidative arylation reaction. The reaction provides an entry…”
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Enantioselective construction of remote tertiary carbon–fluorine bonds by Liu, Jianbo, Yuan, Qianjia, Toste, F. Dean, Sigman, Matthew S.

“…The carbon–fluorine bond engenders distinctive physicochemical properties and significant changes to general reactivity. The development of catalytic,…”
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Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces by Amit, Einav, Dery, Linoy, Dery, Shahar, Kim, Suhong, Roy, Anirban, Hu, Qichi, Gutkin, Vitaly, Eisenberg, Helen, Stein, Tamar, Mandler, Daniel, Dean Toste, F., Gross, Elad

“…N -heterocyclic carbenes (NHCs) have been widely utilized for the formation of self-assembled monolayers (SAMs) on various surfaces. The main methodologies for…”
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Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond by Wu, Chung-Yeh, Horibe, Takahiro, Jacobsen, Christian Borch, Toste, F. Dean

“…Low-valent late transition-metal catalysis has become indispensable to chemical synthesis, but homogeneous high-valent transition-metal catalysis is…”
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A supramolecular microenvironment strategy for transition metal catalysis by Kaphan, David M., Levin, Mark D., Bergman, Robert G., Raymond, Kenneth N., Toste, F. Dean

“…A self-assembled supramolecular complex is reported to catalyze alkyl-alkyl reductive elimination from high-valent transition metal complexes [such as…”
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Data Science Meets Physical Organic Chemistry by Crawford, Jennifer M, Kingston, Cian, Toste, F. Dean, Sigman, Matthew S

“…Conspectus At the heart of synthetic chemistry is the holy grail of predictable catalyst design. In particular, researchers involved in reaction development in…”
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