Search Results - "De Luna, Phil"
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What would it take for renewably powered electrosynthesis to displace petrochemical processes?
Published in Science (American Association for the Advancement of Science) (26-04-2019)“…Electrocatalytic transformation of carbon dioxide (CO ) and water into chemical feedstocks offers the potential to reduce carbon emissions by shifting the…”
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CO2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Published in Science (American Association for the Advancement of Science) (18-05-2018)“…A very basic pathway from CO2 to ethyleneEthylene is an important commodity chemical for plastics. It is considered a tractable target for synthesizing…”
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Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Published in Nature (London) (15-09-2016)“…Gold and palladium nanoneedle electrocatalysts benefit from field-induced reagent concentration to improve the efficiency of carbon dioxide reduction in the…”
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Homogeneously dispersed multimetal oxygen-evolving catalysts
Published in Science (American Association for the Advancement of Science) (15-04-2016)“…Earth-abundant first-row (3d) transition metal–based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at…”
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Copper adparticle enabled selective electrosynthesis of n-propanol
Published in Nature communications (05-11-2018)“…The electrochemical reduction of carbon monoxide is a promising approach for the renewable production of carbon-based fuels and chemicals. Copper shows…”
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Three-Dimensional Cathodes for Electrochemical Reduction of CO2: From Macro- to Nano-Engineering
Published in Nanomaterials (Basel, Switzerland) (20-09-2020)“…Rising anthropogenic CO2 emissions and their climate warming effects have triggered a global response in research and development to reduce the emissions of…”
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Publisher Correction: Copper adparticle enabled selective electrosynthesis of n-propanol
Published in Nature communications (20-02-2020)“…An amendment to this paper has been published and can be accessed via a link at the top of the paper…”
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Molecular enhancement of heterogeneous CO2 reduction
Published in Nature materials (01-03-2020)“…The electrocatalytic carbon dioxide reduction reaction (CO 2 RR) addresses the need for storage of renewable energy in valuable carbon-based fuels and…”
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Tunable Cu Enrichment Enables Designer Syngas Electrosynthesis from CO2
Published in Journal of the American Chemical Society (12-07-2017)“…Using renewable energy to recycle CO2 provides an opportunity to both reduce net CO2 emissions and synthesize fuels and chemical feedstocks. It is of central…”
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Accelerated discovery of CO2 electrocatalysts using active machine learning
Published in Nature (London) (14-05-2020)“…The rapid increase in global energy demand and the need to replace carbon dioxide (CO 2 )-emitting fossil fuels with renewable sources have driven interest in…”
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Stabilizing Highly Active Ru Sites by Suppressing Lattice Oxygen Participation in Acidic Water Oxidation
Published in Journal of the American Chemical Society (05-05-2021)“…In hydrogen production, the anodic oxygen evolution reaction (OER) limits the energy conversion efficiency and also impacts stability in proton-exchange…”
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Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Published in Nature chemistry (01-09-2018)“…The electrochemical reduction of CO 2 to multi-carbon products has attracted much attention because it provides an avenue to the synthesis of value-added…”
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Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate
Published in ACS catalysis (02-12-2016)“…The electrochemical reduction of CO2 into renewable chemical products such as formic acid is an important and challenging goal. Traditional Pd catalysts suffer…”
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2D Metal Oxyhalide‐Derived Catalysts for Efficient CO2 Electroreduction
Published in Advanced materials (Weinheim) (20-09-2018)“…Electrochemical reduction of CO2 is a compelling route to store renewable electricity in the form of carbon‐based fuels. Efficient electrochemical reduction of…”
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A Surface Reconstruction Route to High Productivity and Selectivity in CO2 Electroreduction toward C2+ Hydrocarbons
Published in Advanced materials (Weinheim) (06-12-2018)“…Electrochemical carbon dioxide reduction (CO2) is a promising technology to use renewable electricity to convert CO2 into valuable carbon‐based products. For…”
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Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction
Published in Nature catalysis (15-01-2018)“…The reduction of carbon dioxide to renewable fuels and feedstocks offers opportunities for large-scale, long-term energy storage. The synthesis of efficient CO…”
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Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2
Published in Nature communications (20-09-2018)“…Copper-based materials are promising electrocatalysts for CO 2 reduction. Prior studies show that the mixture of copper (I) and copper (0) at the catalyst…”
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Metal–Organic Frameworks Mediate Cu Coordination for Selective CO2 Electroreduction
Published in Journal of the American Chemical Society (12-09-2018)“…The electrochemical carbon dioxide reduction reaction (CO2RR) produces diverse chemical species. Cu clusters with a judiciously controlled surface coordination…”
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A Molecular Dynamics (MD) and Quantum Mechanics/Molecular Mechanics (QM/MM) study on Ornithine Cyclodeaminase (OCD): a tale of two iminiums
Published in International journal of molecular sciences (11-10-2012)“…Ornithine cyclodeaminase (OCD) is an NAD+-dependent deaminase that is found in bacterial species such as Pseudomonas putida. Importantly, it catalyzes the…”
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Multi-site electrocatalysts for hydrogen evolution in neutral media by destabilization of water molecules
Published in Nature energy (01-02-2019)“…High-performance hydrogen evolution reaction (HER) catalysts are compelling for the conversion of renewable electricity to fuels and feedstocks. The best HER…”
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