Search Results - "De Bruycker, Kevin"
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Full and Partial Amidation of Poly(methyl acrylate) as Basis for Functional Polyacrylamide (Co)Polymers
Published in Macromolecules (23-07-2019)“…The direct modification of poly(methyl acrylate) (PMA) to obtain functional poly(acrylate ester)s or poly(N-alkyl acrylamide)s is generally considered to…”
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Rewritable Polymer Brush Micropatterns Grafted by Triazolinedione Click Chemistry
Published in Angewandte Chemie International Edition (26-10-2015)“…Triazolinedione (TAD) click reactions were combined with microcontact chemistry to print, erase, and reprint polymer brushes on surfaces. By patterning…”
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Mass spectrometry as a tool to advance polymer science
Published in Nature reviews. Chemistry (01-05-2020)“…In contrast to natural polymers, which have existed for billions of years, the first well-understood synthetic polymers date back to just over one century ago…”
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Triazolinediones enable ultrafast and reversible click chemistry for the design of dynamic polymer systems
Published in Nature chemistry (01-09-2014)“…With its focus on synthetic reactions that are highly specific and reliable, ‘click’ chemistry has become a valuable tool for many scientific research areas…”
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Use of Triazolinedione Click Chemistry for Tuning the Mechanical Properties of Electrospun SBS-Fibers
Published in Macromolecules (22-09-2015)Get full text
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Tunable Blocking Agents for Temperature-Controlled Triazolinedione-Based Cross-Linking Reactions
Published in Macromolecules (24-04-2018)“…The remarkable reactivity of triazolinediones (TADs) toward olefin-type substrates marks them as highly attractive click reagents, in particular for polymer…”
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Mapping the Compaction of Discrete Polymer Chains by Size Exclusion Chromatography Coupled to High-Resolution Mass Spectrometry
Published in Macromolecules (26-03-2019)“…We introduce a powerful approach based on the combination of size exclusion chromatography with high-resolution mass spectrometry to selectively follow the…”
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Design of a thermally controlled sequence of triazolinedione-based click and transclick reactions
Published in Chemical science (Cambridge) (01-04-2017)“…The reaction of triazolinediones (TADs) and indoles is of particular interest for polymer chemistry applications, as it is a very fast and irreversible…”
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Scalable Synthesis of Sequence‐Defined Oligomers via Photoflow Chemistry
Published in ChemPhotoChem (01-05-2019)“…The development of practical routes that enable the synthesis of unimolecular non‐natural macromolecules on multi‐gram scales remains a key challenge in…”
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Ultrafast Layer-by-Layer Assembly of Thin Organic Films Based on Triazolinedione Click Chemistry
Published in ACS macro letters (17-03-2015)“…Layer-by-layer deposition is a widely used method for surface functionalization. It is shown here that up to 58 covalently linked molecular layers could be…”
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Thiolactone chemistry for the synthesis of functional silicone‐based amphiphilic co‐networks
Published in Journal of polymer science. Part A, Polymer chemistry (01-02-2019)“…A series of amphiphilic co‐networks (ACNs) is prepared in a straightforward way via thiolactone chemistry by crosslinking a multivalent thiolactone‐functional…”
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Suppressing Creep and Promoting Fast Reprocessing of Vitrimers with Reversibly Trapped Amines
Published in Angewandte Chemie International Edition (21-02-2022)“…We report a straightforward chemical strategy to tackle current challenges of irreversible deformation in low Tg vitrimers at operating temperature. In…”
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13
Rewritable Macromolecular Data Storage with Automated Read‐out
Published in Angewandte Chemie International Edition (21-03-2022)“…Rewriting data stored on synthetic macromolecules is an interesting feature, even though it is considered as being quite challenging within the area of digital…”
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Triazolinediones as Highly Enabling Synthetic Tools
Published in Chemical reviews (23-03-2016)“…Triazolinediones (TADs) are unique reagents in organic synthesis that have also found wide applications in different research disciplines, in spite of their…”
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15
Characterising different molecular landscapes in dynamic covalent networks
Published in Chemical science (Cambridge) (09-11-2022)“…Dynamic covalent networks present a unique opportunity to exert molecular-level control on macroscopic material properties, by linking their thermal behaviour…”
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Masked Primary Amines for a Controlled Plastic Flow of Vitrimers
Published in ACS macro letters (19-07-2022)“…We present a simple method for increasing the reprocessability of vinylogous urethane (VU) vitrimers while decreasing the possibility of creep deformation at…”
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High Performance Quantification of Complex High Resolution Polymer Mass Spectra
Published in ACS macro letters (18-12-2018)“…Modern soft ionization mass spectrometry provides chemical information on various polymers with unparalleled resolution and sensitivity. However, the…”
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Two Colour Photoflow Chemistry for Macromolecular Design
Published in Angewandte Chemie International Edition (10-08-2020)“…We report a photochemical flow setup that exploits λ‐orthogonal reactions using two different colours of light (λ1=350 nm and λ2=410 nm) in sequential on‐line…”
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Novel composite materials with tunable delamination resistance using functionalizable electrospun SBS fibers
Published in Composite structures (01-01-2017)“…[Display omitted] Electrospun fibers have shown great potential for the interlaminar toughening. In this work, electrospun SBS fibers were incorporated into…”
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Recyclable cross-linked hydroxythioether particles with tunable structures via robust and efficient thiol-epoxy dispersion polymerizations
Published in RSC advances (2017)“…The highly efficient base-catalyzed thiol-epoxy reactions were exploited in dispersion polymerizations as a simple method for the preparation of uniform and…”
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