Search Results - "Darvasiova, Denisa"
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Coumarin-Based Triapine Derivatives and Their Copper(II) Complexes: Synthesis, Cytotoxicity and mR2 RNR Inhibition Activity
Published in Biomolecules (Basel, Switzerland) (09-06-2021)“…A series of thiosemicarbazone-coumarin hybrids (HL1-HL3 and H2L4) has been synthesised in 12 steps and used for the preparation of mono- and dinuclear…”
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Solvent effect on the anodic oxidation of tannic acids: EPR/UV–Vis spectroelectrochemical and DFT theoretical study
Published in Journal of solid state electrochemistry (01-09-2015)“…Cyclic voltammetry of tannic acid mixture (TAM) in water, dimethylsulfoxide (DMSO), and acetonitrile (ACN) indicates the highest oxidation potential for TAM in…”
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Triapine Derivatives Act as Copper Delivery Vehicles to Induce Deadly Metal Overload in Cancer Cells
Published in Biomolecules (Basel, Switzerland) (19-09-2020)“…Thiosemicarbazones continue to attract the interest of researchers as potential anticancer drugs. For example, 3-aminopyridine-2-carboxaldehyde…”
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Copper(ii) thiosemicarbazone complexes induce marked ROS accumulation and promote nrf2-mediated antioxidant response in highly resistant breast cancer cells
Published in Dalton transactions : an international journal of inorganic chemistry (2017)“…A series of water-soluble sodium salts of 3-formyl-4-hydroxybenzenesulfonic acid thiosemicarbazones (or sodium 5-sulfonate-salicylaldehyde thiosemicarbazones)…”
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Vanadium(V) Complexes with Substituted 1,5-bis(2-hydroxybenzaldehyde)carbohydrazones and Their Use As Catalyst Precursors in Oxidation of Cyclohexane
Published in Inorganic chemistry (19-09-2016)“…Six dinuclear vanadium(V) complexes have been synthesized: NH4[(VO2)2(HLH)] (NH4[1]), NH4[(VO2)2( t‑BuLH)] (NH4[2]), NH4[(VO2)2(ClLH)] (NH4[3]),…”
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Nickel(II) Complexes with Redox Noninnocent Octaazamacrocycles as Catalysts in Oxidation Reactions
Published in Inorganic chemistry (19-08-2019)“…Nickel(II) complexes with 15-membered (1–5) and 14-membered (6) octaazamacrocyclic ligands derived from 1,2- and 1,3-diketones and…”
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Nickel(II), Copper(II) and Palladium(II) Complexes with Bis-Semicarbazide Hexaazamacrocycles: Redox-Noninnocent Behavior and Catalytic Activity in Oxidation and C–C Coupling Reactions
Published in Inorganic chemistry (03-08-2020)“…Nickel(II), copper(II), and palladium(II) complexes ML H , where M = Ni (1), Cu (2), Pd (3), and ML OMe , where M = Ni (4), Cu (5), Pd (6), have been…”
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Novel latonduine derived proligands and their copper(ii) complexes show cytotoxicity in the nanomolar range in human colon adenocarcinoma cells and in vitro cancer selectivity
Published in Dalton transactions : an international journal of inorganic chemistry (16-07-2019)“…Four Schiff bases derived from 7-hydrazin-yl-5,8-dihydroindolo[2,3-d][2]benzazepin-(6H)-one and its bromo-substituted analogue (HL1-HL4) and four copper(ii)…”
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Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors
Published in Molecules (Basel, Switzerland) (11-01-2021)“…The in situ spectroelectrochemical cyclic voltammetric studies of the antimony-monocapped nickel(II) and iron(II) tris-pyridineoximates with a labile…”
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Diastereomeric dinickel(II) complexes with non-innocent bis(octaazamacrocyclic) ligands: isomerization, spectroelectrochemistry, DFT calculations and use in catalytic oxidation of cyclohexane
Published in Dalton transactions : an international journal of inorganic chemistry (29-03-2022)“…Diastereomeric dinickel(II) complexes with bis-octaazamacrocyclic 15-membered ligands [Ni(L1-3-L1-3)Ni] (4-6) have been prepared by oxidative dehydrogenation…”
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Spectroelectrochemical, photochemical and theoretical study of octaazamacrocyclic nickel(II) complexes exhibiting unusual solvent-dependent deprotonation of methylene group
Published in Electrochimica acta (05-12-2019)“…The reduction potentials and the reversibility of corresponding redox processes in a series of nickel(II) complexes, featuring 15-membered (1–5) and…”
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Tuning Redox Properties and Self‐Assembly of Thienoacene‐Extended Tetrathiafulvalenes
Published in ChemPlusChem (Weinheim, Germany) (01-09-2019)“…Turning on and off associations between molecules by a reversible change in their redox states is a convenient way of controlling self‐assembly and hence for…”
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New Water-Soluble Copper(II) Complexes with Morpholine–Thiosemicarbazone Hybrids: Insights into the Anticancer and Antibacterial Mode of Action
Published in Journal of medicinal chemistry (24-01-2019)“…Six morpholine-(iso)thiosemicarbazone hybrids HL 1 –HL 6 and their Cu(II) complexes with good-to-moderate solubility and stability in water were synthesized…”
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Triapine Analogues and Their Copper(II) Complexes: Synthesis, Characterization, Solution Speciation, Redox Activity, Cytotoxicity, and mR2 RNR Inhibition
Published in Inorganic chemistry (02-08-2021)“…Three new thiosemicarbazones (TSCs) HL 1 –HL 3 as triapine analogues bearing a redox-active phenolic moiety at the terminal nitrogen atom were prepared…”
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Copper(II) Complexes with Isomeric Morpholine-Substituted 2‑Formylpyridine Thiosemicarbazone Hybrids as Potential Anticancer Drugs Inhibiting Both Ribonucleotide Reductase and Tubulin Polymerization: The Morpholine Position Matters
Published in Journal of medicinal chemistry (21-05-2024)“…The development of copper(II) thiosemicarbazone complexes as potential anticancer agents, possessing dual functionality as inhibitors of R2 ribonucleotide…”
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Redox-Active Organoruthenium(II)– and Organoosmium(II)–Copper(II) Complexes, with an Amidrazone–Morpholine Hybrid and [CuICl2]− as Counteranion and Their Antiproliferative Activity
Published in Organometallics (28-05-2019)“…A novel proligand HLH has been prepared from 2-pyridinamidrazone and 6-(morpholinomethyl)pyridine-2-carboxaldehyde. Subsequently, starting from HLH and…”
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